摘要:
The present invention discloses a poly(terephthalate-co-sebacate) resin and a preparation method thereof. A structure of the poly(terephthalate-co-sebacate) resin satisfies a relation as follows: S δ hydrogen on conjugated carbon chain /S δ hydrogen on saturated carbon chain 1.2-2.4 = 0.1 to 0.35; wherein said S δ hydrogen on conjugated carbon chain is a total area of a peak integration of hydrogen on a conjugated carbon chain in a 1 H NMR spectra, and said S δ hydrogen on saturated carbon chain 1.2-2.4 is a total area of a peak integration of hydrogen on a saturated carbon chain and with a chemical shift between 1.2-2.4 ppm in the 1 H NMR spectra. When the poly(terephthalate-co-sebacate) resin according to the present invention is made into a thin film with a thickness of 25±1 µm, a water vapor transmission thereof is 100-1500 g/m 2 /d, and it has a relatively good moisture-penetrability.
摘要:
The present invention discloses a PBAT resin and a preparation method thereof. A structure of the PBAT resin satisfies a relation as follows: S δ hydrogen on conjugated carbon chain /S δ hydrogen on saturated carbon chain 1.2-2.4 = 0.1 to 0.35; wherein said S δ hydrogen on conjugated carbon chain is a total area of a peak integration of hydrogen on a conjugated carbon chain in a 1 H NMR spectra, and said S δ hydrogen on saturated carbon chain 1.2-2.4 is a total area of a peak integration of hydrogen on a saturated carbon chain and with a chemical shift between 1.2-2.4 ppm in the 1 H NMR spectra. When the PBAT resin according to the present invention is made into a thin film with a thickness of 25±1 µm, a water vapor transmission thereof is 100-1500 g/m 2 /d.
摘要:
The present invention discloses a biodegradable polyester composition, wherein based on a total weight of the biodegradable polyester composition, a weight content of a cyclic ester compound having a structure shown as formula (I) is 100ppm-950ppm;
and based on the total weight of the biodegradable polyester composition, a weight content of tetrahydrofuran is 3ppm-200ppm. In the present invention, by adding the cyclic ester compound and tetrahydrofuran into the composition and controlling the content of the cyclic ester compound and the content of tetrahydrofuran in a certain range in the composition, an anti-thermal oxidative aging property of the biodegradable polyester composition can be greatly improved. Besides, after being digested with 95% ethanol at 40°C for 240 hours, a film prepared by blow molding or a part prepared by injection molding has little precipitate separating out of the surface and has an excellent surface appearance property. Also, poor printing of the biodegradable polyester composition during printing process can be greatly improved and the film shows excellent printing performance.
摘要:
The present invention discloses a polyamide resin and its application and polyamide composition thereof. The repeating units of the described polyamide resin comprises the following components: dicarboxylic acid units composed 80-100mol% of polyamide resin; aliphatic diamines units having 2-14 carbon atoms composed 80-100mol% of polyamide resin; lactam or amino acid units having 6-14 carbon atoms composed 0-20mol% of polyamide resin; in the described polyamide resin, the bio-based carbon concentration is more than 45%; the described bio-based carbon mole concentration is calculated according to the formula below: bio-based carbon concentration=(bio-based carbon mole content/total organic carbon mole content)*100%. The described polyamide resin in the present invention has low gas volatile, hence the polyamide composition produced thereof has low gas volatile too, and can be applied to food-contact field. In addition, the surface condition after reflow soldering of the polyamide composition produced is good.
摘要:
The present invention discloses a biodegradable polyester and use thereof, including components: A) containing repeating units of acid components as follows: 50 to 58 mol% of terephthalic acid A1; 30 to 40 mol% of sebacic acid A2; and 2 to 20 mol% of an aliphatic dibasic acid A3 with a carbon chain length of 6 or less;
B) butanediol. In the present invention, in the case of a high content of terephthalic acid, by introducing an aliphatic dibasic acid unit having a carbon chain length of 6 or less, under the circumstance that the prepared biodegradable polyester satisfies the degradation performance and rigidity, the tenacity of the material can be improved simultaneously.
摘要:
The present invention discloses a PBS resin composition and a preparation method thereof. The PBS resin composition comprises the following components: a. PBS resin; b. element titanium; c. element phosphorus, wherein a range of a weight ratio of the element titanium to the element phosphorus is 0.6-10:1, preferably 0.7-4:1, and more preferably 1.25-1.5:1. A weight content of the element titanium is 20-200 ppm, and a weight content of the element phosphorus is 15-70 ppm. By adding a titanium-containing compound and a phosphorus-containing compound and controlling the range of the weight ratio of the element titanium to the element phosphorus in the PBS resin composition to be 0.6-10:1, the present invention obtains a PBS resin composition. After treating in a 95°C-distilled water bath for 12 hours and drying at 90°C for 3 hours, a change of the melt flow index of the PBS resin composition is less than 50.0 g/lOmin, and the PBS resin composition possesses an obviously improved hydrolysis property.
摘要:
The present invention discloses a biodegradable polyester composition, wherein based on a total weight of the biodegradable polyester composition, a weight content of styrene is 0.1ppm-30ppm. When the weight content of styrene which is added into a chosen formula of the biodegradable polyester composition based on the total weight of the biodegradable polyester composition is controlled as 0.1ppm-30ppm, the present invention may guarantee the biodegradable polyester composition with excellent transmittance and haze effect, and meanwhile may guarantee the biodegradable polyester composition with suitable UV resistance function, without reducing a degradation rate of the biodegradable polyester composition.
摘要:
Disclosed is a biodegradable polyester composition, comprising the following components in percentage by weight: i) 58-80 parts of aliphatic-aromatic copolyester; ii) 20-32 parts of starch; and iii) 0-10 parts of processing assistant agents. According to the present invention, it can be unexpectedly found during studies that the aliphatic-aromatic copolyester in which the aromatic carboxylic acid is 44 mol%-48 mol% as the total amount of diacid is used as a base resin, the crystalline peak width D of the aliphatic-aromatic copolyester is 5°C-6°C, and the starch having the particle size D(50) of 2 µm-12 µm is used as another phase; meanwhile, a processing assistant agent having the particular content is added, the polyester composition obtained by preparing has excellent transverse and longitudinal tear strength, meets industrial compost, and has more than 90% of biodegradation rate in a 12-week degradation test process.