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公开(公告)号：EP3406646A1
公开(公告)日：2018-11-28
申请号：EP17848103.2
申请日：2017-09-04
申请人： Zhuhai Wango Chemical Co., Ltd. , Kingfa Sci. & Tech. Co., Ltd. , Shanghai Kingfa Sci.&Tech.Co., Ltd.
发明人： WANG, Weiwei , YUAN, Zhimin , CAI, Tongmin , HUANG, Xianbo , ZENG, Xiangbin , RUAN, Renxu , GUO, Zhilong , TANG, Meijun
IPC分类号： C08G63/183 , C08G63/58 , C08G63/52 , C08G63/85
CPC分类号： C08G63/183 , C08G63/52 , C08G63/58 , C08G63/85
摘要： The present invention discloses a polyester resin and a preparation method thereof. A structure of the polyester resin satisfies a relation as follows: Sδ hydrogen on conjugated carbon chain/Sδ hydrogen on saturated carbon chain 1.2-2.4 = 0.1 to 0.35; wherein said Sδ hydrogen on conjugated carbon chain is a total area of a peak integration of hydrogen on a conjugated carbon chain in a 1H NMR spectra, and said Sδ hydrogen on saturated carbon chain 1.2-2.4 is a total area of a peak integration of hydrogen on a saturated carbon chain and with a chemical shift between 1.2-2.4 ppm in the 1H NMR spectra. When the polyester resin according to the present invention is made into a thin film with a thickness of 25±1 µm, a water vapor transmission thereof is 100-1500 g/m2/d, and it has a relatively good moisture-penetrability.
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公开(公告)号：EP3511358A1
公开(公告)日：2019-07-17
申请号：EP17848102.4
申请日：2017-09-04
申请人： Zhuhai Wango Chemical Co., Ltd. , Kingfa Sci. & Tech. Co., Ltd. , Shanghai Kingfa Sci.&Tech.Co., Ltd.
发明人： WANG, Weiwei , YUAN, Zhimin , CAI, Tongmin , HUANG, Xianbo , ZENG, Xiangbin , YUAN, Renxu , GUO, Zhilong , TANG, Meijun
IPC分类号： C08G63/183 , C08G63/78
摘要： The present invention discloses a poly(terephthalate-co-sebacate) resin and a preparation method thereof. A structure of the poly(terephthalate-co-sebacate) resin satisfies a relation as follows: S δ hydrogen on conjugated carbon chain /S δ hydrogen on saturated carbon chain 1.2-2.4 = 0.1 to 0.35; wherein said S δ hydrogen on conjugated carbon chain is a total area of a peak integration of hydrogen on a conjugated carbon chain in a 1 H NMR spectra, and said S δ hydrogen on saturated carbon chain 1.2-2.4 is a total area of a peak integration of hydrogen on a saturated carbon chain and with a chemical shift between 1.2-2.4 ppm in the 1 H NMR spectra. When the poly(terephthalate-co-sebacate) resin according to the present invention is made into a thin film with a thickness of 25±1 µm, a water vapor transmission thereof is 100-1500 g/m 2 /d, and it has a relatively good moisture-penetrability.
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公开(公告)号：EP3406647A1
公开(公告)日：2018-11-28
申请号：EP17848104.0
申请日：2017-09-04
申请人： Zhuhai Wango Chemical Co., Ltd. , Kingfa Sci. & Tech. Co., Ltd. , Shanghai Kingfa Sci.&Tech.Co., Ltd.
发明人： WANG, Weiwei , YUAN, Zhimin , CAI, Tongmin , HUANG, Xianbo , ZENG, Xiangbin , YUAN, Renxu , GUO, Zhilong , TANG, Meijun
IPC分类号： C08G63/183 , C08G63/78
CPC分类号： C08G63/183 , C08G63/78
摘要： The present invention discloses a PBAT resin and a preparation method thereof. A structure of the PBAT resin satisfies a relation as follows: S δ hydrogen on conjugated carbon chain /S δ hydrogen on saturated carbon chain 1.2-2.4 = 0.1 to 0.35; wherein said S δ hydrogen on conjugated carbon chain is a total area of a peak integration of hydrogen on a conjugated carbon chain in a 1 H NMR spectra, and said S δ hydrogen on saturated carbon chain 1.2-2.4 is a total area of a peak integration of hydrogen on a saturated carbon chain and with a chemical shift between 1.2-2.4 ppm in the 1 H NMR spectra. When the PBAT resin according to the present invention is made into a thin film with a thickness of 25±1 µm, a water vapor transmission thereof is 100-1500 g/m 2 /d.
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公开(公告)号：EP4400530A1
公开(公告)日：2024-07-17
申请号：EP22869137.4
申请日：2022-09-09
发明人： ZHANG, Chuanhui , CHEN, Pingxu , YE, Nanbiao , OUYANG, Chunping , MAI, Kaijin , DONG, Xueteng , ZENG, Xiangbin , LU, Changli , CAI, Tongmin
CPC分类号： C05F17/00 , C08L67/04 , C08G63/02 , C08G63/78 , C08G63/00 , C08L67/02 , C08G63/672 , C08G63/20 , C08L67/00
摘要： The present invention discloses a polyester, a preparation method therefor and use thereof. The polyester includes repeating units derived from the following components: a first component A, based on the total molar weight of the first component A, including: a1) 81-100 mol% of succinic acid, or an ester derivative thereof or an anhydride derivative thereof, and a2) 0-19 mol% of a dicarboxylic acid other than succinic acid, or an ester derivative thereof or an anhydride derivative thereof; a second component B: 1,4-butanediol; and a third component C: a dimer(1,4-butanediol); based on the total molar weight of the first component A, the molar content of the repeating unit -CH2CH2CH2CH2-O- in the third component C is 0.05-3.0 mol%. In the present invention, the molar content of the repeating unit -CH2CH2CH2CH2-O- in dimer(1,4-butanediol) is controlled to 0.05-3.0 mol%, and thus, the resin color of the polyester can be effectively improved.
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公开(公告)号：EP3553109A1
公开(公告)日：2019-10-16
申请号：EP17878750.3
申请日：2017-11-30
发明人： WANG, Weiwei , YUAN, Zhimin , CAI, Tongmin , HUANG, Xianbo , ZENG, Xiangbin , YUAN, Renxu , GUO, Zhilong , TANG, Meijun
IPC分类号： C08G63/183 , C08G63/185 , C08G63/78
摘要： The present invention discloses a poly(terephthalate-co-sebacate) resin and a preparation method thereof, wherein the poly(terephthalate-co-sebacate) resin is formed by polymerization of a diacid and a diol, the diacid consists of 45mol%-55mol% of terephthalic acid and 45mol%-55mol% of sebacic acid, the diol is 1,4-butanediol, and thermal performance parameters of the poly(terephthalate-co-sebacate) resin meet the following relational expression: T crystallization peak width at half height / T melting point − T crystallization temperature = 0.05 to 0.26 ; and a film made of the poly(terephthalate-co-sebacate) resin with a thickness of 25±1µm has a static friction coefficient of 0.2-0.3 and a light transmittance of 90% or above, and has balanced light transmittance and static friction coefficient, having a relatively low static friction coefficient whilst maintaining a relatively high light transmittance performance, and the resin can be smoothly processed without adding an antiblocking agent or a compatilizer, so that the obtained poly(terephthalate-co-sebacate) resin has good transparency and processing performance.
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公开(公告)号：EP4400529A1
公开(公告)日：2024-07-17
申请号：EP22869138.2
申请日：2022-09-09
发明人： ZHANG, Chuanhui , CHEN, Pingxu , YE, Nanbiao , OUYANG, Chunping , MAI, Kaijin , DONG, Xueteng , ZENG, Xiangbin , LU, Changli , CAI, Tongmin
IPC分类号： C08G63/672 , C08G63/183 , C08G63/85 , C08L67/02
CPC分类号： C08G63/183 , C08L67/02 , C08G63/672 , C08G63/85 , C08J5/18
摘要： The present invention relates to a semi-aromatic polyether ester, a preparation method therefor and use thereof. The semi-aromatic polyether ester includes repeating units derived from the following components: a first component A, based on the total molar amount of the first component A, including: a1) 35-65 mol%, and preferably 40-60 mol% of at least one aliphatic dicarboxylic acid or an ester derivative thereof, or an anhydride derivative thereof, and a2) 35-65 mol%, and preferably 40-60 mol% of at least one aromatic dicarboxylic acid or an ester derivative thereof, or an anhydride derivative thereof; a second component B: 1,4-butanediol; and a third component C: poly(1,4-butanediol) having a molecular formula of HO-(CH2CH2CH2CH2-O)n-H, where n is an integer from 2 to 200; based on the total molar weight of the first component A, the molar content of the repeating unit -CH2CH2CH2CH2-O- in the third component C is 1.5-5.5 mol%.
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公开(公告)号：EP4400527A1
公开(公告)日：2024-07-17
申请号：EP21957198.1
申请日：2021-09-23
发明人： ZHANG, Chuanhui , CHEN, Pingxu , YE, Nanbiao , OUYANG, Chunping , MAI, Kaijin , DONG, Xueteng , ZENG, Xiangbin , LU, Changli , CAI, Tongmin
IPC分类号： C08G63/183 , C08G63/672 , C08L67/02 , C08G63/78
摘要： Disclosed are a semi-aromatic polyester, and a preparation method therefor and a use thereof. In the present invention, on the basis of the total molar amount of diacid, the molar content of a repeating unit -CH2CH2CH2CH2-O- in dimer(1,4-butanediol) is controlled to be 0.05-0.35 mol%, which can effectively improve the resin color of the semi-aromatic polyester.
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公开(公告)号：EP3260498A1
公开(公告)日：2017-12-27
申请号：EP17762460.8
申请日：2017-02-24
申请人： Kingfa Sci. & Tech. Co., Ltd. , Zhuhai Wango Chemical Co., Ltd. , Tianjin Kingsky Material Co., Ltd.
发明人： LU, Changli , YUAN, Zhimin , CAI, Tongmin , HUANG, Xianbo , ZENG, Xiangbin , JIAO, Jian , YUAN, Renxu , ZHONG, Yuke , XIONG, Kai , YANG, Hui , MAI, Kaijin , DONG, Xueteng
CPC分类号： C08L67/02 , C08G59/1466 , C08J5/18 , C08J2367/02 , C08K5/0016 , C08K5/0075 , C08K5/07 , C08K5/156 , C08K13/02 , C08L3/02 , C08L67/04 , C08L2201/06 , C08L2201/08 , C08L25/14
摘要： The present invention discloses a biodegradable polyester composition, wherein based on a total weight of the biodegradable polyester composition, a weight content of a cyclic ester compound having a structure shown as formula (I) is 100ppm-950ppm;
and based on the total weight of the biodegradable polyester composition, a weight content of cyclopentanone is 0.5ppm-85ppm. In the present invention, by adding the cyclic ester compound and cyclopentanone into the composition and controlling the content of the cyclic ester compound and the content of cyclopentanone in a certain range in the composition, an anti-thermal oxidative aging property of the biodegradable polyester composition can be greatly improved. Besides, after being digested with 95% ethanol at 40°C for 240 hours, a film prepared by blow molding or a part prepared by injection molding has little precipitate separating out of the surface and has an excellent surface appearance property. In addition, the lubrication degree of film during the blow molding process of the biodegradable polyester can be improved. When the velocity of film blowing is 176 Kg/h, a range of a film thickness is less than 0.2µm and a relative deviation of the film thickness is less than 1%. Bubble stability and continuity of film blowing are guaranteed.摘要翻译： 本发明公开了一种生物可降解聚酯组合物，其中基于生物可降解聚酯组合物的总重量，具有式（I）所示结构的环状酯化合物的重量含量为100ppm-950ppm; 基于生物可降解聚酯组合物的总重量，环戊酮的重量含量为0.5ppm-85ppm。 在本发明中，通过将环状酯化合物和环戊酮添加到组合物中，并且在组合物中控制环酯化合物的含量和环戊酮的含量在一定范围内，可生物降解的聚酯组合物的抗热氧化老化性能 可以大大提高。 此外，用95％乙醇在40℃下消化240小时后，通过吹塑或通过注塑制备的部件制备的膜具有很少的从表面析出的沉淀，并具有优异的表面外观性能。 另外，可生物降解聚酯的吹塑成型过程中膜的润滑度可以得到改善。 当吹膜速度为176Kg / h时，膜厚范围小于0.2μm，膜厚相对偏差小于1％。 泡沫稳定性和吹膜连续性得到保证。
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公开(公告)号：EP4174105A1
公开(公告)日：2023-05-03
申请号：EP22203601.4
申请日：2022-10-25
申请人： Jiangsu Kingfa Sci. & Tech. Advanced Materials Co., Ltd. , Zhuhai Wango Chemical Co., Ltd. , KINGFA SCI. & TECH. CO., LTD.
发明人： ZHANG, Chuanhui , CHEN, Pingxu , YE, Nanbiao , OUYANG, Chunping , MAI, Kaijin , DONG, Xueteng , ZENG, Xiangbin , LU, Changli , CAI, Tongmin
摘要： The present invention discloses a semi-aromatic polyester and a preparation method and an application thereof. The semi-aromatic polyester has a specific scope of double bond content. Compared with the existing semi-aromatic polyester, the semi-aromatic polyester of the present invention has better melting heat retention stability and fine color.
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公开(公告)号：EP3260493A1
公开(公告)日：2017-12-27
申请号：EP16884775.4
申请日：2016-12-15
申请人： Zhuhai Wango Chemical Co., Ltd. , Kingfa Sci. & Tech. Co., Ltd. , Tianjin Kingsky Material Co., Ltd.
发明人： ZHAO, Wei , YUAN, Renxu , TANG, Meijun , JIAO, Jian , XIONG, Kai , ZHONG, Yuke , YANG, Hui , MAI, Kaijin , GUO, Zhilong , DONG, Xueteng , ZENG, Xiangbin
IPC分类号： C08L67/02 , C08G63/183 , C08K3/08
摘要： The present invention discloses a PBAT resin composition comprising following components: (a) poly(butyleneadipate-co-terephthalate); (b) iron element; wherein, based on a total weight of the PBAT resin composition, a weight content of the iron element is 1ppm-500ppm. By adding iron-containing compounds into the composition and controlling the content of the iron element in a range of 1ppm-500ppm in the composition, a speed of reaction of aromatic structure in the PBAT resin under a hot and humid condition can be postponed, so that after the prepared PBAT resin composition is aged in boiling water for 24 hours and 48 hours, a variation of b-value is less than 2. The PBAT resin composition has obviously improved color stability in resistance to boiling water aging.
摘要翻译： 本发明公开了一种PBAT树脂组合物，其包含以下组分：（a）聚（亚丁基己二酸酯 - 共 - 对苯二甲酸酯）; （b）铁元素; 其中，基于PBAT树脂组合物的总重量，铁元素的重量含量为1ppm-500ppm。 通过向组合物中添加含铁化合物，并且在组合物中将铁元素的含量控制在1ppm〜500ppm的范围内，可以推迟PBAT树脂在炎热和潮湿条件下的芳香族结构的反应速度，所以 在制备的PBAT树脂组合物在沸水中老化24小时和48小时后，b值的变化小于2.PBAT树脂组合物具有明显改进的耐沸水老化的颜色稳定性。
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