Chlorine gas supply
    11.
    发明公开
    Chlorine gas supply 失效
    Chlorgasversorgung

    公开(公告)号:EP0730902A1

    公开(公告)日:1996-09-11

    申请号:EP96301601.9

    申请日:1996-03-08

    发明人: Okabe, Itaru

    摘要: A method for supplying a chlorine gas to a reactor (7) which comprises the steps of cooling the chlorine gas to convert it into liquefied chlorine, transferring the liquefied chlorine to a location near the reactor by pressure and heating the liquefied chlorine to convert it into a chlorine gas, and supplying the chlorine gas to the reactor (7). Using this method, a chlorine gas can be stably supplied to a reactor (7) under a small load and the amount of impurities contained in the chlorine gas and undesired for a chlorination reactor (7) can be reduced in this process.

    摘要翻译: 一种向反应器(7)供应氯气的方法,包括以下步骤:冷却氯气以将其转化为液化氯,通过压力将液化氯转移到靠近反应器的位置,并加热液化氯以将其转化成 氯气,并将氯气供应到反应器(7)。 使用这种方法,可以在小负载下将氯气稳定地供应到反应器(7),并且在该过程中可以减少氯气反应器(7)中所含的杂质的含量。

    METHOD FOR PURIFYING A CHLORINE SUPPLY
    14.
    发明授权
    METHOD FOR PURIFYING A CHLORINE SUPPLY 有权
    清理方法氯气原料的

    公开(公告)号:EP2499090B1

    公开(公告)日:2016-10-26

    申请号:EP10774238.9

    申请日:2010-11-10

    申请人: BASF SE

    摘要: This invention provides a method for purifying a chlorine supply that includes a chlorine component, a bromine component, and nitrogen trichloride. The method includes the steps of introducing the chlorine supply into a vaporizer, heating the chlorine supply in the vaporizer to form a vapor, and introducing the vapor into a distillation system to provide purified chlorine gas, a distillate that includes liquid chlorine and the bromine component, and a bottoms component including the nitrogen trichloride. The method also includes the steps of condensing the vapor in a reflux condenser, heating the condensate in a reboiler, removing the purified chlorine gas from the distillation system, and removing the distillate from the distillation system.

    METHOD OF PRODUCING CHLORINE GAS, AQUEOUS SODIUM HYPOCHLORITE SOLUTION AND LIQUID CHLORINE
    15.
    发明公开
    METHOD OF PRODUCING CHLORINE GAS, AQUEOUS SODIUM HYPOCHLORITE SOLUTION AND LIQUID CHLORINE 有权
    VERFAHREN ZUR HERSTELLUNG VON CHLORGAS,WÄSSRIGERNATRIUMHYPOCHLORITLÖSUNGUNDFLÜSSIGEMCHLOR

    公开(公告)号:EP1947054A1

    公开(公告)日:2008-07-23

    申请号:EP06731861.8

    申请日:2006-04-14

    IPC分类号: C01B7/07 C01B7/075 C01B11/06

    摘要: It is intended to provide methods of producing a chlorine gas having a small bromine content, an aqueous sodium hypochlorite solution having a small bromic acid content, and liquid chlorine having a small bromine content. More specifically, a chlorine gas is produced by a method comprising the steps of: (A) washing a chlorine gas that contains bromine, in a gas washing unit composed of a packed column or a tray tower, wherein the chlorine gas introduced via a lower part of the gas washing unit is brought into counterflow gas/liquid contact with a liquid chlorine introduced via an upper part of the gas washing unit; and (B) taking out a purified chlorine gas thus washed, via the upper part of the gas washing unit, wherein a weight ratio of the chlorine gas and the liquid chlorine introduced in the step (A) is 1/1.0 to 1/0.3.

    摘要翻译: 旨在提供具有溴含量少的氯气,溴酸含量低的次氯酸钠水溶液和溴含量低的液氯的方法。 更具体地说,通过包括以下步骤的方法制备氯气:(A)在由填充塔或塔塔塔构成的气体洗涤单元中洗涤含有溴的氯气,其中经由下层 气体洗涤单元的一部分与通过气体洗涤单元的上部引入的液态氯反向气体/液体接触; 和(B)通过气体洗涤单元的上部取出经过洗涤的净化氯气,其中在步骤(A)中引入的氯气和液态氯的重量比为1 / 1.0〜1 / 0.3 。

    VERFAHREN ZUR HERSTELLUNG VON CHLOR

    公开(公告)号:EP1866239A1

    公开(公告)日:2007-12-19

    申请号:EP06743192.4

    申请日:2006-02-20

    IPC分类号: C01B7/04

    CPC分类号: C01B7/075 C01B7/04 C01B7/0743

    摘要: The invention concerns a method for producing chlorine and a hydrochloric gas including the following steps: a) supplying via a stream containing hydrochloric gas (a1) and a stream containing oxygen (a2) an oxidation zone and a hydrochloric gas catalytic oxidation with chlorine, a stream of gaseous product (a3) containing chlorine, water, oxygen, carbon dioxide, and the inert gases obtained; b) cooling the stream of gaseous products (a3) and separating the water from the hydrochloric gas in the form of hydrochloric acid, a gas stream (b) containing chlorine, water, oxygen, carbon dioxide, and the inert gases still remaining; c) optionally drying the gas stream (b), and obtaining a gas stream (c) substantially water-free, containing chlorine, oxygen, carbon dioxide and inert gases; d) liquefying at least partly the gas stream (c) and a return stream (f1) rich in chlorine, containing chlorine, oxygen, carbon dioxide through thickening and cooling, a partly liquefied stream (d) being preserved; e) gas-liquid separation of the stream (d) into a gas stream (e1) containing chlorine, oxygen, carbon dioxide, and inert gases and into a liquid stream (e2) containing chlorine, oxygen, and carbon dioxide; f) introducing at least part of the gas stream (e1) into a unit with membrane and separating a return stream (f1) rich in chlorine and a gas flow (f2) poor in chlorine, containing chlorine, oxygen, carbon dioxide, via a separation by the membrane and reintroducing the return flux (f1) rich in chlorine in step d); g) separating the liquid stream (e2) by distillation into a stream of chlorine (g1) and a stream (g2) comprising substantially oxygen and carbon dioxide.

    摘要翻译: 本发明涉及一种生产氯气和盐酸气体的方法,包括以下步骤:a)通过含有盐酸气体(a1)和含氧气流体(a2),氧化区域和盐酸气体催化氧化的气流与氯气, 含有氯气,水,氧气,二氧化碳和惰性气体的气体产物(a3)的气流; b)冷却气态产物流(a3)并从盐酸形式的盐酸中分离出水,含有氯气,水,氧气,二氧化碳和剩余的惰性气体的气流(b); c)任选地干燥气流(b),并获得基本上无水的含有氯气,氧气,二氧化碳和惰性气体的气流(c); d)通过增稠和冷却至少部分地液化气体物流(c)和富含氯的返回物流(f1),部分液化物流(d)被保留; e)将气流(d)气 - 液分离成含有氯气,氧气,二氧化碳和惰性气体的气流(e1)并进入含有氯气,氧气和二氧化碳的液体流(e2)中; f)将至少一部分气流(e1)引入具有膜的单元中,并通过一个分离器将富含氯的返回流(f1)和贫含氯的气流(f2)分离,所述氯气包含氯气,氧气,二氧化碳 在步骤d)中通过膜分离并重新引入富含氯的返回通量(f1); g)通过蒸馏将液体流(e2)分离成氯气流(g1)和基本上包含氧气和二氧化碳的气流(g2)。

    Distillative freezing process for separating close boiling mixtures
    17.
    发明公开
    Distillative freezing process for separating close boiling mixtures 失效
    破坏者Ausfrierverfahren zum Trennen von Stoffen mit dicht beieinanderliegenden Siedepunkten。

    公开(公告)号:EP0044366A1

    公开(公告)日:1982-01-27

    申请号:EP80302490.0

    申请日:1980-07-23

    IPC分类号: B01D9/04

    摘要: A crystallization separation process for separating an at least partially liquid mixture containing two volatile components (A and B) the two components forming a binary system in which the vapor pressure ratio of A:B is 0.1 to 10 at the B-triple point and is less than the ratio of the heat of sublimation to the heat of melting of the B-component at the B-triple point, the constant pressure phase diagram having a B-enriched solid-vapor two phase region covering a substantial concentration range above the three phase state temperature and a B-enriched solid and liquid region below such temperature wherein a first vapor mixture and first condensed mass are formed by vaporizing the two components in a first zone at a temperature and pressure lower than the triple point temperature and pressure, the first condensed mass comprising a mother liquor and a solid phase which is B-enriched, the heat released in the formation of the solid being utilized to vaporize the volatile components.
    Such process can be extended to a gas mixture containing two volatile and condensable components (A and B) into substantially pure B and a B-lean component, in which heat is removed from the gas to cause part of the B to desublime, the A remaining in the vapor stream, the vapor stream then having heat removed therefrom while the vapor is at a temperature and pressure below the B-triple point values thereby causing formation of a further condensed mass.

    摘要翻译: 一种用于分离含有两种挥发性组分(A和B)的至少部分液体混合物的结晶分离方法,所述两种组分形成二元体系,其中A:B的蒸气压比在B三重点为0.1至10,并且为 小于B-三重点的B成分的升华热量与熔融热的比例,具有覆盖三分之一以上的实质浓度范围的富含B的固体蒸气两相区域的恒压相图 相状态温度和低于这种温度的富含B的固体和液体区域,其中通过在低于三重点温度和压力的温度和压力下将第一区域中的两种组分蒸发而形成第一蒸气混合物和第一冷凝物质, 包含母液和富含B的固相的第一浓缩物质,在形成固体中释放的热量用于蒸发挥发性组分。 这种方法可以扩展到含有两种挥发性和可冷凝组分(A和B)的气体混合物,成为基本上纯的B和贫B组分,其中热量从气体中除去以使B的一部分发生沉淀,A 保留在蒸汽流中,然后蒸汽流从其中除去热量,同时蒸汽处于低于B-三重点值的温度和压力下,从而形成另外的冷凝物质。

    VERFAHREN ZUR HERSTELLUNG VON CHLOR
    18.
    发明授权
    VERFAHREN ZUR HERSTELLUNG VON CHLOR 有权
    用于生产氯

    公开(公告)号:EP1866239B1

    公开(公告)日:2012-01-18

    申请号:EP06743192.4

    申请日:2006-02-20

    申请人: BASF SE

    IPC分类号: C01B7/04

    CPC分类号: C01B7/075 C01B7/04 C01B7/0743

    摘要: The invention concerns a method for producing chlorine and a hydrochloric gas including the following steps: a) supplying via a stream containing hydrochloric gas (a1) and a stream containing oxygen (a2) an oxidation zone and a hydrochloric gas catalytic oxidation with chlorine, a stream of gaseous product (a3) containing chlorine, water, oxygen, carbon dioxide, and the inert gases obtained; b) cooling the stream of gaseous products (a3) and separating the water from the hydrochloric gas in the form of hydrochloric acid, a gas stream (b) containing chlorine, water, oxygen, carbon dioxide, and the inert gases still remaining; c) optionally drying the gas stream (b), and obtaining a gas stream (c) substantially water-free, containing chlorine, oxygen, carbon dioxide and inert gases; d) liquefying at least partly the gas stream (c) and a return stream (f1) rich in chlorine, containing chlorine, oxygen, carbon dioxide through thickening and cooling, a partly liquefied stream (d) being preserved; e) gas-liquid separation of the stream (d) into a gas stream (e1) containing chlorine, oxygen, carbon dioxide, and inert gases and into a liquid stream (e2) containing chlorine, oxygen, and carbon dioxide; f) introducing at least part of the gas stream (e1) into a unit with membrane and separating a return stream (f1) rich in chlorine and a gas flow (f2) poor in chlorine, containing chlorine, oxygen, carbon dioxide, via a separation by the membrane and reintroducing the return flux (f1) rich in chlorine in step d); g) separating the liquid stream (e2) by distillation into a stream of chlorine (g1) and a stream (g2) comprising substantially oxygen and carbon dioxide.