Abstract:
A lubricant composition having improved non-Newtonian viscometrics includes at least 85 weight percent of a base oil and 1 to 15 weight percent of a lubricant additive. The additive itself includes 10 to 80 weight percent of a diluent oil and 30 to 80 weight percent of a random co-polymeric viscosity index improver. The viscosity index improver is the free-radical polymerization product of at least 5 to 15 weight percent methyl methacrylate and 5 to 95 weight percent of a C8-C10 alkyl (meth)acrylate. The additive is formed using a method that includes the step of providing the diluent oil, the methyl methacrylate, the C8-C10 alkyl (meth)acrylate, and a free-radical initiator. The method also includes the steps of flowing the diluent oil into a reactor, flowing the methyl methacrylate and the C8-C10 alkyl (meth)acrylate into the reactor independently from the free-radical initiator, and flowing the free-radical initiator into the reactor.
Abstract:
A method of recharging the reaction tubes of a tube-bundle reactor with a new catalyst fixed bed in which a heterogeneously catalysed partial gas phase oxidation of an organic compound has been carried out in advance in a precursor catalyst fixed bed having Mo-containing multielement oxidative compositions and with formation of a steam-containing product gas mixture, in which, before the recharging, molybdenum oxide and/or molybdenum oxide hydrate-containing solid coating deposited on the tube interior walls is brushed off using a brush.
Title translation:VERFAHREN DER INBETRIEBNAHME EINER HETEROGEN KATALYSIERTEN PARTIELLEN GASPHASENOXIDATION VON ACRININ ZUACRYLSÄUREODER VON METHACROLEIN ZUMETHACRYLSÄURE
Abstract:
The invention relates to a method for starting a heterogeneously catalyzed partial gas phase oxidation of acrolein into acrylic acid or of methacrolein into methacrylic acid at a fixed catalyst bed that is located in a shell-and-tube reactor cooled with a heat exchanger means, wherein the temperature of the heat exchanger means is ≥ 290°C, and wherein the temperature of the reactor bottom surface facing the reactor gas inlet mixture and the temperature of the reaction gas inlet mixture are ≤ 285°C.
Abstract:
The invention relates to a method for the heterogeneously catalysed partial gas phase oxidation of propylene to form acrylic acid in the presence of propane as an inert diluent gas. According to said method, cyclopropane as an impurity is largely avoided in the reaction gas starting mixture and raw propylene is used as a propylene source.
Abstract:
Disclosed is a method for the heterogeneously catalyzed partial gas phase oxidation of propene into acrolein, according to which the initial reaction gas mixture is oxidized on a fixed catalyst bed that comprises at least two fixed catalyst bed zones and is accommodated in two successive temperature zones A, B, the transition of temperature zone A to temperature zone B not coinciding with a transition from one fixed catalyst bed zone to another.