公开(公告)号：EP1270649A4

公开(公告)日：2004-06-16

申请号：EP00944428

申请日：2000-07-13

申请人： DAIKIN IND LTD

发明人： MORITA SHIGERU ,  ARASE TAKUYA ,  SHIMIZU TETSUO

IPC分类号： C08J3/24 ,  C08F8/00 ,  C08F14/18 ,  C08F16/24

CPC分类号： C08F8/00 ,  C08F14/18

摘要： A polymer having a structure represented by general formula: (I) (wherein X, Y, and Z each is hydrogen, fluorine, chlorine, bromine, or iodine, provided that at least one of X, Y, and Z is fluorine; R is linear or branched fluoroalkylene optionally containing oxygen; x and y each represents mol% and x is 1 to 100 mol%; A is -CN, -NCO, -COOR' (R' is hydrogen or alkyl), an acid anhydride group, or an unsaturated hydrocarbon group; and M is a repeating unit derived from a copolymerizable monomer) is treated with a crosslinking agent selected among ammonia, a diamine, and a polyol to crosslink the polymer through pendant functional groups of the polymer. This method of crosslinking can be carried out at room temperature and gives a transparent fluororesin having excellent heat resistance as compared with conventional transparent thermoplastic resins.

公开(公告)号：EP0844271A4

公开(公告)日：2000-03-22

申请号：EP96926609

申请日：1996-08-08

申请人： DAIKIN IND LTD

发明人： ASANO MICHIO ,  TANIGAWA SHINGO ,  KAWACHI SHOJI ,  SHIMIZU TETSUO

IPC分类号： C08F16/14 ,  C08F214/26 ,  C08F216/14 ,  C08J3/12 ,  C08J3/16 ,  C08L27/12 ,  C08L27/18

CPC分类号： C08J3/16 ,  C08J3/12 ,  C08J2327/18

摘要： A process for producing a granular powder of modified polytetrafluoroethylene (PTFE) which is excellent in the handleability, i.e., flowability and apparent density of a powder without using an atomized powder and in the properties of moldings made therefrom, can be granulated with only water without using organic liquids, and can provide moldings having a breakdown voltage similar to the case wherein use is made of an atomized powder of an unmodified PTFE. The granular powder is produced by agitating in an aqueous medium a powder of a perfluorovinyl ether-modified PTFE produced by suspension polymerization and having an average grain diameter of 100 to 300 νm.

公开(公告)号：EP0726293A4

公开(公告)日：1998-06-10

申请号：EP94931170

申请日：1994-10-27

申请人： DAIKIN IND LTD

发明人： YAMAMOTO YOSHIHISA ,  YAMATO TAKAFUMI ,  SHIMIZU TETSUO ,  HARADA TAKESHI

IPC分类号： B32B1/08 ,  C08L27/12 ,  C08L27/18 ,  C08L77/00 ,  B32B27/08 ,  B32B27/30 ,  B32B27/34

CPC分类号： B32B1/08 ,  B32B27/08 ,  B32B27/34 ,  B32B2250/03 ,  B32B2307/718 ,  B32B2327/12 ,  B32B2597/00 ,  C08L27/12 ,  C08L27/18 ,  C08L77/00 ,  C08L2205/02 ,  Y10T428/139 ,  C08L2666/02 ,  C08L2666/06

摘要： A thermoplastic resin composition comprising (i) 5-80 wt. % of a polyamide resin, (ii) 15-90 wt. % of a fluororesin, and (iii) 1-80 wt. % of a fluororubber having a tensile modulus of 500 kg/cm2 or less at ordinary temperature. A molding having a layer formed from the above composition has an excellent chemical resistance.

公开(公告)号：EP1462458A4

公开(公告)日：2005-02-23

申请号：EP02786022

申请日：2002-12-04

申请人： DAIKIN IND LTD

发明人： AOYAMA TAKAHISA ,  OHTANI KATSUHIDE ,  IMAMURA HITOSHI ,  SHIMIZU TETSUO

IPC分类号： C08F8/22 ,  C08F214/26

CPC分类号： C08F8/22 ,  C08F214/262

摘要： The invention provides ozone-resistant articles such as pipes and fittings for semiconductor equipment; molding materials suitable for the production of such ozone-resistant articles; ozone-resistant injection-molded articles; and injection molding materials. A molding material for the production of ozone-resistant articles which comprises a copolymer (A) and exhibits a melt flow rate of 0.1 to 50g/10min, characterized in that the copolymer (A) is a copolymer of tetrafluoroethylene and a perfluoro vinyl ether which contains at least 3.5 % by mass of perfluoro vinyl ether units and has a melting point of 295°C or above and a content of unstable terminals of 50 or below per 1 × 106 carbon atoms contained in the copolymer.

公开(公告)号：EP0924537A4

公开(公告)日：2005-01-05

申请号：EP97934770

申请日：1997-08-12

申请人： DAIKIN IND LTD

发明人： AOYAMA TAKAHISA ,  SHIMIZU TETSUO ,  OTSUKI NORIHITO ,  NAGAHAMA NORIO

IPC分类号： B32B27/00 ,  B32B27/30 ,  C08L53/00 ,  C09D153/00 ,  G02B1/11 ,  G02B1/111 ,  G02B1/14 ,  G02B1/16 ,  G02B1/10 ,  C09D133/04 ,  G09F9/00

CPC分类号： G02B1/14 ,  G02B1/105 ,  G02B1/111 ,  Y10T428/24942 ,  Y10T428/265 ,  Y10T428/3154 ,  Y10T428/31935

摘要： An antireflection article, comprising an acrylic resin substrate and a fluoropolymer film provided on the surface of the substrate, wherein the film has a thickness of 0.03 to 0.5 mu m and the fluoropolymer has a refractive index of 1.30 to 1.40 and comprises a block compatible with an acrylic resin and a block of a fluoroelastomer. This article possesses scratch resistance and antireflection effect comparable with the conventional articles and, in addition, can be stably prepared at a low cost, or possesses an antireflection effect superior to that of the conventional antireflection film while maintaining the scratch resistance.

摘要翻译： 作为防反射物品，其包含丙烯酸类树脂基板和设置在基板的表面上的含氟聚合物膜，其中所述膜的厚度为0.03〜0.5微米和含氟聚合物具有1.30的折射率1.40和包括与相容的块 丙烯酸树脂和含氟弹性体的嵌段。 本文具有耐擦伤性和防反射效果与常规制品相媲美，并且此外，可以以低成本稳定地制备，或具有防反射效果优于同时保持耐擦伤性的现有的防反射膜的。

公开(公告)号：EP1422258A4

公开(公告)日：2004-09-15

申请号：EP02758781

申请日：2002-08-01

申请人： DAIKIN IND LTD

发明人： SHIMIZU TETSUO ,  ASANO MICHIO ,  ONO MAKOTO ,  NANBA YOSHINORI ,  KASAI SHUNJI ,  YANO SHINICHI ,  YOSHIMOTO HIROYUKI

IPC分类号： C08J3/12 ,  C08J7/00

CPC分类号： C08J3/12 ,  C08J2327/18 ,  Y10T428/2991 ,  Y10T428/3154

摘要： A polytetrfluoroethylene fine powder which is obtainable by contacting a polytetrfluoroethylene fine powder having a standard specific gravity of 2.180 to 2.225 with a fluorine radical source and exhibits a standard specific gravity of 2.180 to 2.225, wherein a film which is cut from a formed product of the resulting fine powder, fired and then cooled at a rate of 5 to 50˚C/sec exhibits a tan δ at 12 GHz of 2.0 X 10-4 or less. The disclosed polytetrfluoroethylene fine powder exhibits excellent extrudability and can be used for producing a polytetrfluoroethylene formed article excellent in various electrical and mechanical characteristics in a high frequency region of 3 to 30 GHz, in particular, a PTFE formed article for high frequency insulation.

摘要翻译： 一种聚四氟乙烯细粉，其可以通过使标准比重为2.180〜2.225的聚四氟乙烯细粉与氟自由基源接触而显示出标准比重为2.180〜2.225，其特征在于，从该成形品 得到的细粉，烧成，然后以5〜50℃/秒的速度冷却，在12GHz时的tanδ为2.0×10 -4以下。 所公开的聚四氟乙烯细粉表现出优异的可挤出性，并且可用于制造在3至30GHz的高频区域中具有各种电特性和机械特性优异的聚四氟乙烯成形制品，特别是用于高频绝缘的PTFE成形制品。

公开(公告)号：EP1091435A4

公开(公告)日：2001-11-21

申请号：EP99918347

申请日：1999-05-10

申请人： DAIKIN IND LTD

发明人： ARAKI TAKAYUKI ,  OKA NORITOSHI ,  TANAKA YOSHITO ,  NAKAMURA TAKAYUKI ,  SHIMIZU TETSUO

IPC分类号： C08F293/00 ,  C08F228/02 ,  C08J5/22 ,  G02B6/12 ,  G02B6/13 ,  G02F1/025 ,  H01B1/12 ,  H01M8/02 ,  H01M8/10 ,  H01S5/00 ,  H01S5/20 ,  H01S5/22 ,  H02N11/00 ,  C08F14/18 ,  C08F14/20 ,  C08F14/26 ,  H01B1/06

CPC分类号： H01S5/22 ,  C08J5/2237 ,  C08J2327/12 ,  G02B2006/12097 ,  G02B2006/12176 ,  H01B1/122 ,  H01M8/0289 ,  H01M8/1025 ,  H01M8/1039 ,  H01M8/1067 ,  H01S5/0655 ,  H01S5/20 ,  H01S5/2004 ,  H01S5/2213 ,  H01S5/2218 ,  H01S5/2227

摘要： A material for solid polyelectrolytes which comprises a polymer comprising two or more fluoropolymer segments differing in monomer composition, wherein at least one of the fluoropolymer segments has sulfonic acid type functional groups.

公开(公告)号：EP0857747A4

公开(公告)日：1999-06-09

申请号：EP96935439

申请日：1996-10-23

申请人： DAIKIN IND LTD

发明人： ASANO MICHIO ,  SUKEGAWA MASAMICHI ,  YUKAWA HIROKAZU ,  SHIMIZU TETSUO ,  KAWACHI SHOJI ,  TANIGAWA SHINGO ,  TSUJI MASAYUKI

IPC分类号： C08J3/12 ,  C08J3/205 ,  C08J3/21 ,  C08L27/18

CPC分类号： C08J3/21 ,  C08J3/205 ,  C08J2327/18

摘要： A granular powder of filled PTFE which has a high apparent density, a small mean particle diameter and a sharp particle size distribution, is excellent in the fluidity in a powdery state and can give molded articles being excellent in tensile strength and elongation and having low surface roughness; and a process for the production thereof. Powdered PTFE is mixed with a filler in water in the presence of a surfactant in a slurry state, and the resulting mixture is agitated in the presence of an organic liquid forming a liquid-liquid interface together with water to thereby conduct granulation.

公开(公告)号：EP0861865A4

公开(公告)日：1999-05-26

申请号：EP96935535

申请日：1996-11-01

申请人： DAIKIN IND LTD

发明人： ASANO MICHIO ,  SHIMIZU TETSUO ,  KAWACHI SHOJI

IPC分类号： C08J3/205 ,  C08J3/12

CPC分类号： C08J3/205 ,  C08J2327/18

摘要： A granulated powder of filled PTFE for molding which exhibits a high apparent density and a low quantity of electrification, is excellent in the fluidity in a powdery state, and can give molded articles not lowered in tensile strength and elongation and little suffering from discoloration due to surfactants; and a process for the production thereof. 100 parts by weight of a mixture comprising powdered PTFE and a filler is wetted with 30 to 60 parts by weight of an aqueous solution containing an anionic surfactant; in a concentration of 10 or more but less than 40 times the critical micelle concentration, and the resulting wet mixture is granulated by a mechanical force.

公开(公告)号：EP0861856A4

公开(公告)日：1999-05-19

申请号：EP96937550

申请日：1996-11-08

申请人： DAIKIN IND LTD

发明人： KITAHARA TAKAHIRO ,  HOSOKAWA KAZUTAKA ,  SHIMIZU TETSUO

IPC分类号： C08F14/26 ,  C08J3/16 ,  C08L27/18 ,  C08L101/00 ,  C09K3/22 ,  C09K21/14 ,  C08F6/14

CPC分类号： C08J3/16 ,  C08F14/26 ,  C08J2327/12 ,  C08L27/18 ,  C08L101/00 ,  C09K3/22 ,  C09K21/14 ,  C08F2/16 ,  C08L2666/04

摘要： A fine polytetrafluoroethylene powder excellent in fluidity in a powdery state, which is composed of fine particles (primary particles) having a mean particle diameter of 0.05 to 1 νm and has an apparent density of 0.52 to 0.70 g/ml, a standard specific gravity (SSG) of 2.14 to 2.23 and a secondary mean particle diameter of 100 to 1000 νm; an antidripping agent produced from this powder; a flame-retardant resin composition containing the powder; and an antidusting composition containing the powder.