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公开(公告)号：EP3212686B1
公开(公告)日：2018-08-29
申请号：EP15793972.9
申请日：2015-10-27
发明人： KUO, Thauming , LIU, Junjia , HALL, Phillip, Bryan
IPC分类号： C08G8/04 , C08G8/08 , C08G8/24 , C08G8/36 , C08L61/14 , C08L67/00 , C08L67/02 , C09D161/14 , C09D161/06 , C08L61/06
摘要： There is now provided a variety of curable polyester resins that cure well with phenolic crosslinking agents. The curable polyester resins include polyester resins that have both carboxyl and hydroxyl functionalities and a high ratio of carboxyl functionalities to hydroxyl functionalities; unsaturated curable polyester having residues of an α,β-unsaturated polycarboxylic acid compound with at least one unsaturation in a position that is α,β relative to a carbonyl group and not located on an aromatic ring; and a curable polyester resin containing beta-ketoacetate moieties without vinyl unsaturation. The curable polyester resin can be dispersed in water or dissolved in a solvent and is suitable for waterborne or solventborne coating compositions. Phenolic based crosslinking coating compositions that contain these curable polyester resins cure well with phenolic resin crosslinking compounds with a wide variety of reactive curable polyester resins or other kinds of polyester resins.
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公开(公告)号：EP3327005A1
公开(公告)日：2018-05-30
申请号：EP16827751.5
申请日：2016-07-15
IPC分类号： C07D233/64 , C07D405/04 , C08G8/36 , C08G16/00 , G03F7/11 , G03F7/26 , H01L21/027
CPC分类号： C08G16/0268 , C07B63/04 , C07D233/64 , C07D405/04 , C08G8/36 , C08G16/00 , C09D161/00 , G03F7/039 , G03F7/11 , G03F7/162 , G03F7/168 , G03F7/2037 , G03F7/26 , G03F7/322 , G03F7/38 , H01L21/027 , H01L21/3081 , H01L21/3086
摘要： A compound or a resin represented by the following formula (1).
(in formula (1), each X independently represents an oxygen atom, a sulfur atom, or an uncrosslinked state, each R 1 is independently selected from the group consisting of a halogen group, a cyano group, a nitro group, an amino group, a hydroxyl group, a thiol group, a heterocyclic group, an alkyl group having 1 to 30 carbon atoms, an alkenyl group having 2 to 30 carbon atoms, an aryl group having 6 to 40 carbon atoms, and combinations thereof, in which the alkyl group, the alkenyl group and the aryl group optionally include an ether bond, a ketone bond or an ester bond, each R 2 independently represents an alkyl group having 1 to 30 carbon atoms, an aryl group having 6 to 40 carbon atoms, an alkenyl group having 2 to 30 carbon atoms, a thiol group or a hydroxyl group, in which at least one R 2 represents a group including a hydroxyl group or a thiol group, each m is independently an integer of 0 to 7 (in which at least one m is an integer of 1 to 7.), each p is independently 0 or 1, q is an integer of 0 to 2, and n is 1 or 2.)-
公开(公告)号：EP3212685A1
公开(公告)日：2017-09-06
申请号：EP15791849.1
申请日：2015-10-27
发明人： KUO, Thauming , LIU, Junjia , HALL, Phillip, Bryan
IPC分类号： C08G8/04 , C08G8/08 , C08G8/24 , C08G8/36 , C08L61/14 , C08L67/00 , C08L67/02 , C09D161/14 , C09D161/06 , C08L61/06
摘要： This invention relates to a resole phenolic resin comprising the residues of (a) from about 50 to 100 mole % of a meta-substituted phenol [phenolic component (a)], (b) from 0 to about 50 mole % of at least one phenolic component [phenolic component (b)] other than said meta-substituted phenol, and (c) from about 150 to about 300 mole % of at least one aldehyde, wherein the mole percentages of said phenolic components (a) and (b) are based on the total moles of phenolic components (a) and (b); wherein the mole percentages of said aldehyde component is based on the total moles of said phenolic components (a) and (b), and wherein said resole phenolic resin is soluble in an organic solvent and curable with a functional polyester.
摘要翻译： 现在提供了各种可与酚醛交联剂良好固化的可固化聚酯树脂。 可固化的聚酯树脂包括既具有羧基又具有羟基官能团且具有高比例的羧基官能度与羟基官能度的聚酯树脂; 在α，β相对于羰基且不位于芳香环上的位置上具有至少一个不饱和度的α，β-不饱和多元羧酸化合物的残基; 和含有无乙烯基不饱和度的β-酮乙酸酯部分的可固化聚酯树脂。 可固化聚酯树脂可以分散在水中或溶解在溶剂中，并且适用于水性或溶剂型涂料组合物。 含有这些可固化聚酯树脂的酚醛基交联涂料组合物与酚醛树脂交联化合物与各种活性可固化聚酯树脂或其它种类的聚酯树脂固化良好。
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公开(公告)号：EP2871197A1
公开(公告)日：2015-05-13
申请号：EP13813463.0
申请日：2013-06-20
CPC分类号： C09K5/14 , C08G8/10 , C08G8/12 , C08G8/20 , C08G8/22 , C08G8/24 , C08G8/36 , C08G59/621 , C08G59/688 , C08L61/06 , C08L61/12 , C08L61/14 , C08L63/00
摘要： Provided is a phenolic resin composition containing: an epoxy resin curing agent that contains a hydroxybenzene derivative represented by the following Formula (I) and a phenol resin having at least one partial structure selected from the group consisting of the following Formulae (IIa), (IIb), (IIc) and (IId); and an epoxy resin. In these Formulae, each of R 1 , R 2 , R 3 , R 4 and R 5 independently represents a hydroxy group, a hydrogen atom or an alkyl group; at least two of R 1 , R 2 , R 3 , R 4 and R 5 are hydroxy groups; each Ar independently represents at least one group selected from the group consisting of the following Formulae (IIIa) and (IIIb); each of R 11 and R 14 independently represents a hydrogen atom or a hydroxy group; and each of R 12 and R 13 independently represents a hydrogen atom or an alkyl group.
摘要翻译： 本发明提供一种酚醛树脂组合物，其含有含有下式（I）表示的羟基苯衍生物的环氧树脂固化剂和具有选自下述式（IIa），（IIa）， IIb），（IIc）和（IId）; 和环氧树脂。 在这些式中，R 1，R 2，R 3，R 4和R 5各自独立地表示羟基，氢原子或烷基; R 1，R 2，R 3，R 4和R 5中的至少两个是羟基; 每个Ar独立地表示选自下列式（IIIa）和（IIIb）中的至少一种： R 11和R 14各自独立地表示氢原子或羟基; R 12和R 13各自独立地表示氢原子或烷基。
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公开(公告)号：EP1364978A1
公开(公告)日：2003-11-26
申请号：EP03009577.2
申请日：2003-04-29
申请人： Bakelite AG
IPC分类号： C08G59/14 , C08F290/06 , C08F290/14 , C08G8/28 , C08F220/32 , C08G8/32 , C08G8/36 , C08F299/02
CPC分类号： C08F290/144 , C08F299/026 , C08G59/1461 , C08G59/1494 , C08G59/628
摘要： Die Erfindung betrifft neue Epoxyacrylate, die dadurch hergestellt werden, daß epoxidierte Novolake mit einer aromatischen Hydroxycarbonsäure im molaren Verhältnis epoxidierter Novolak zu Hydroxycarbonsäure von 2 : 0,5 bis 2 : 1,5 umgesetzt werden und die resultierenden Produkte mit mindestens 10 Mol% einer ethylenisch ungesättigten Monocarbonsäure umgesetzt werden. In einem weiteren Reaktionsschritt können diese Epoxyacrylate mit einem Säuranhydrid einer mehrwertigen Carbonsäure verestert werden, wobei die Menge an Carbonsäureanhydrid 50 bis 100% der stöchiometrischen Menge beträgt, die der Summe aller Hydroxylgruppen entspricht.
摘要翻译： 环氧丙烯酸酯基于与芳族羟基羧酸反应，然后与烯键式不饱和一元羧酸反应的环氧化酚醛清漆。 环氧丙烯酸酯具有式（I）R =式（II）的基团; R = = 1-4C烷基或卤素; x = 0-3; R // =羟基; m = 0-4; n = 0-300的整数; M =式（III）的缩水甘油基或OH-取代的基团; R1 = H或甲基; 并且R2 = H，甲基或苯基还包括（i）式（I）的环氧丙烯酸酯的独立权利要求，其中至少10摩尔。 M的％是式（III）的OH取代基; （ii）式（I）的环氧丙烯酸酯，其中50-100％的所有OH基用多元羧酸的酸酐酯化; 和（iii）环氧丙烯酸酯的制备。
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公开(公告)号：EP0209020B1
公开(公告)日：1992-03-04
申请号：EP86109179.1
申请日：1986-07-04
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公开(公告)号：EP0261679A3
公开(公告)日：1991-03-13
申请号：EP87113969.7
申请日：1987-09-24
发明人： Tsuchiya, Yasuyuki , Tobinaga, Kenshiro , Obika, Toshimi , Sakamoto, Hiroyuki , Morita, Kengi , Tsushima, Hiroshi
CPC分类号： C08G18/546 , C08G8/36 , C08G18/4027 , C08G18/4045 , C08G18/8064 , C08G59/621 , C09D5/448 , C09D5/4496 , C09D163/00
摘要： Disclosed is a phenol ether characterized by a beta-hydroxyl group and has the following formula:
wherein R¹ is a residue of an initial reaction product of a resol type phenol resin from which a phenolic hydroxyl group is removed, R², R³, R⁴ and R⁵ are respectively a saturated or unsaturated alkyl group having 1 to 30 carbon atoms, a saturated or unsaturated cycloalkyl group having 1 to 30 carbon atoms, or a substituted or unsubstituted aryl group having 6 to 20 carbon atoms (R³ and R⁴ may constitute a ring together). Also, the present invention is to provide a process for preparing the phenol ether mentioned above. Further, the present invention is to provide a cationic or anionic electrocoating composition containing the phenol ether containing a beta-hydroxyl group.摘要翻译： 公开了以β-羟基为特征的苯酚醚，具有下式：
其中R 1是去除酚羟基的甲阶型酚醛树脂的初始反应产物的残基，R R 3，R 4和R 5分别是碳原子数1〜30的饱和或不饱和的烷基，碳原子数1〜30的饱和或不饱和的环烷基，取代或 具有6至20个碳原子的未取代的芳基（R 3和R 4可以一起构成环）。 另外，本发明提供一种上述制备苯酚醚的方法。 此外，本发明提供一种含有含有β-羟基的苯酚醚的阳离子或阴离子电涂组合物。 -
29.发明公开Phenol ether compound production and usage thereof 失效Phenolätherverbindung，ihre Herstellung und ihre Verwendung。
公开(公告)号：EP0261679A2
公开(公告)日：1988-03-30
申请号：EP87113969.7
申请日：1987-09-24
发明人： Tsuchiya, Yasuyuki , Tobinaga, Kenshiro , Obika, Toshimi , Sakamoto, Hiroyuki , Morita, Kengi , Tsushima, Hiroshi
CPC分类号： C08G18/546 , C08G8/36 , C08G18/4027 , C08G18/4045 , C08G18/8064 , C08G59/621 , C09D5/448 , C09D5/4496 , C09D163/00
摘要： Disclosed is a phenol ether characterized by a beta-hydroxyl group and has the following formula:
wherein R¹ is a residue of an initial reaction product of a resol type phenol resin from which a phenolic hydroxyl group is removed, R², R³, R⁴ and R⁵ are respectively a saturated or unsaturated alkyl group having 1 to 30 carbon atoms, a saturated or unsaturated cycloalkyl group having 1 to 30 carbon atoms, or a substituted or unsubstituted aryl group having 6 to 20 carbon atoms (R³ and R⁴ may constitute a ring together).
Also, the present invention is to provide a process for preparing the phenol ether mentioned above.
Further, the present invention is to provide a cationic or anionic electrocoating composition containing the phenol ether containing a beta-hydroxyl group.摘要翻译： 公开了以β-羟基为特征的苯酚醚，具有下式：
其中R 1是去除酚羟基的甲阶型酚醛树脂的初始反应产物的残基，R R 3，R 4和R 5分别是碳原子数1〜30的饱和或不饱和的烷基，碳原子数1〜30的饱和或不饱和的环烷基，取代或 具有6至20个碳原子的未取代的芳基（R 3和R 4可以一起构成环）。 另外，本发明提供一种上述制备苯酚醚的方法。 此外，本发明提供一种含有含有β-羟基的苯酚醚的阳离子或阴离子电涂组合物。 -
公开(公告)号：EP0243318A2
公开(公告)日：1987-10-28
申请号：EP87810247.4
申请日：1987-04-21
申请人： CIBA-GEIGY AG
CPC分类号： H01B3/40 , C08G59/02 , C08G59/3218 , C08G59/38
摘要： Beschrieben werden neue epoxidgruppenhaltige Phenolether der Formel I
worin R 1 Ci-C 2 oAlkyl, C 5 -C 9 Cycloalkyl oder C 7 -C 14 Aralkyl ist, R 2 die gleiche Bedeutung wie R 1 besitzt oder zusätzlich Wasserstoff oder ein Rest der Formel II ist
R 3 C 1 -C 6 Alkyl oder Halogen bedeutet, R 4 und R 5 Wasserstoff oder C 1 -C 6 Alkyl sind, R 6 Wasserstoff oder Methyl bedeutet, m 0, 1 oder 2 ist und n eine ganze Zahl von 0 bis 30 darstellt mit der Massgabe, dass mindestens zwei Reste R 2 Epoxidgruppen II sein müssen. Die Verbindungen eignen sich insbesondere zur Umhüllung elektronischer Komponenten.摘要翻译： 描述的是式I
其中，R C1 -C 20 - 烷基，C 5 C9Cycloalkyl或C7-C14Aralkyl，R 2是相同的含义R 1，或额外地，氢或式Ⅱ基团的新的环氧化物苯酚醚的 R 3 C1-C6烷基 或卤素，R <4>和R <5>是氢或C1-C6烷基，R <6>是氢或甲基，m是0，1或2，n是从0到30的整数，条件表示 至少两个基团R 2必须是环氧II。 所述化合物特别适合用于涂覆电子元件。
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