公开(公告)号：EP2121549A1

公开(公告)日：2009-11-25

申请号：EP07726908.2

申请日：2007-03-14

Applicant: BASF SE

Inventor： PINKOS, Rolf ,  LORENZ, Rudolf Erich ,  BESTE, York Alexander

IPC: C07C29/17 ,  C07C31/20

CPC classification number: C07C29/42 ,  C07C29/172 ,  Y02P20/125 ,  C07C33/046 ,  C07C31/207

Abstract: The object of the present invention is an integrated method for the continuous production of 1,4-butanediol, comprising the following steps: (I) reacting formaldehyde with acetylene in the presence of a catalyst comprising copper at a pH value between 5 and 8, and at a molar ratio of formaldehyde to acetylene of a maximum of 2:1, (II) intermediate buffering of the resulting aqueous mixture comprising butanediol for 0.1 to 100 h, (III) hydrating the mixture obtained after intermediate buffering, and (IV) distilling the hydrogenation product obtained in step II for yielding 1,4-butanediol.

公开(公告)号：EP1926696B1

公开(公告)日：2009-04-29

申请号：EP06792973.7

申请日：2006-08-23

Applicant: BASF SE

Inventor： LORENZ, Rudolf Erich ,  PINKOS, Rolf ,  STEINIGER, Michael ,  SCHÄFER, Gerd

IPC: C07C29/17 ,  C07C29/76 ,  C07C31/30 ,  C07C33/035

CPC classification number: C07C29/172 ,  C07C29/17 ,  C07C29/76 ,  C07C33/035 ,  C07C31/207 ,  C07C33/046

Abstract: The invention relates to a method for purifying 1,4-butynediol, in which 1,4-butynediol is processed in a dynamic mixing device in an inert gas atmosphere at 25 to 150 °C at a velocity gradient exceeding 100,000 sec-1 in the radial play between the rotor and the stator, one waits for the phases to separate at temperatures ranging from 25 to 150 °C, and the bottom phase is eliminated. Also disclosed is a method for hydrogenating 1,4-butynediol into 1,4-butenediol and 1,4-butanediol with the aid of the purified 1,4-butynediol.

公开(公告)号：EP4073052A1

公开(公告)日：2022-10-19

申请号：EP20811680.6

申请日：2020-11-30

Applicant: BASF SE

Inventor： PINKOS, Rolf ,  RODEWALD, Dieter ,  LINKE, Stephanie, Sybille ,  HEIDEMANN, Thomas ,  WEIGUNY, Jens

IPC: C07D307/08 ,  C07C29/149 ,  C07C31/20 ,  C07D307/32

公开(公告)号：EP3844138A1

公开(公告)日：2021-07-07

申请号：EP19753103.1

申请日：2019-08-19

Applicant: BASF SE

Inventor： BIENEWALD, Frank ,  VOELKERT, Martin ,  PINKOS, Rolf

IPC: C07C41/08 ,  C07C41/44 ,  C07C43/188 ,  C07C43/16

公开(公告)号：EP3684504A1

公开(公告)日：2020-07-29

申请号：EP18762869.8

申请日：2018-09-10

Applicant: BASF SE

Inventor： SCHROETER, Marie Katrin ,  DE WISPELAERE, Irene ,  SCHWARZ, Michael ,  PINKOS, Rolf ,  SCHWABAUER, Inna

IPC: B01J21/02 ,  B01J23/755 ,  B01J23/883 ,  C22C19/03 ,  C22C19/00 ,  C22C21/00 ,  B01J37/02 ,  B01J37/08 ,  B01J37/18 ,  B01J37/00 ,  B01J35/04 ,  C07C29/17 ,  C07C31/20 ,  C07C29/141 ,  C07C31/12 ,  C23C30/00

公开(公告)号：EP3436420A1

公开(公告)日：2019-02-06

申请号：EP17714694.1

申请日：2017-03-29

Applicant: BASF SE

Inventor： PINKOS, Rolf ,  RITTINGER, Stefan ,  NUEBLING, Christoph ,  ABILLARD, Olivier

IPC: C07C29/149

公开(公告)号：EP3328820A1

公开(公告)日：2018-06-06

申请号：EP16744365.4

申请日：2016-07-26

Applicant: BASF SE

Inventor： DUEFERT, Alexander ,  PINKOS, Rolf ,  REISER, Michael ,  BRUEGGEMANN, Philipp ,  THEIS, Gerhard

IPC: C07C29/149 ,  C07C31/20

Abstract: The invention relates to a method for producing monoethylene glycol (MEG) via the metal-catalysed reaction of an oxalic acid dialkyl ester of formula (I), in which R
1 and R
2 each independently of one another represent methyl, ethyl, n-propyl or iso-propyl groups, with hydrogen (H
2 ), wherein the oxalic acid dialkyl ester (I) is used in the form of a melt or dissolved in a solvent, oxalic acid dialkyl ester (I) and H
2 are used in a molar ratio of H
2 :oxalic acid dialkyl ester (I) in the region of 4.0 to 30, and the reaction is carried out continuously in a reactor at a sectional density of ≥ 10 m/s, a temperature in the region of 150 to 270°C, a pressure in the region of 150 to 390 bar and in the presence of a chrome-free, heterogeneous, copper-containing catalyst.

公开(公告)号：EP2501667B1

公开(公告)日：2016-11-02

申请号：EP10776382.3

申请日：2010-11-16

Applicant: BASF SE

Inventor： TOMPERS, Rolf ,  URTEL, Heiko ,  PINKOS, Rolf ,  TEBBEN, Gerd-Dieter ,  HEIMANN, Jens ,  GUIXA GUARDIA, Maria ,  BORCHERS, Sabine

IPC: C07C29/141 ,  C07C29/149 ,  C07C31/20 ,  C07C31/22 ,  B01J23/58 ,  B01J23/78 ,  B01J23/83 ,  B01J23/72 ,  B01J37/06

CPC classification number: B01J23/78 ,  B01J23/58 ,  B01J23/72 ,  B01J23/80 ,  B01J23/83 ,  B01J37/0063 ,  B01J37/06 ,  C07C29/141 ,  C07C29/149 ,  C07C31/22 ,  C07C31/20

公开(公告)号：EP2614056B1

公开(公告)日：2014-07-23

申请号：EP11749864.2

申请日：2011-09-05

Applicant: BASF SE

Inventor： ABILLARD, Olivier ,  BREUNINGER, Daniel ,  KLEINMANN, Eva ,  PINKOS, Rolf

IPC: C07D313/04 ,  C07C29/149

CPC classification number: C07D313/04 ,  C07C29/149 ,  C07C29/80 ,  C07C29/86 ,  C07C51/316 ,  C07C31/20 ,  C07C55/14

公开(公告)号：EP2417089B1

公开(公告)日：2013-06-05

申请号：EP10711899.4

申请日：2010-03-31

Applicant: BASF SE

Inventor： PINKOS, Rolf ,  BREUNINGER, Daniel ,  Dr. TEBBEN, Gerd-Dieter

IPC: C07C29/149 ,  C07C31/125 ,  C07C29/145 ,  C07C29/80 ,  C07C35/14 ,  C07C51/31 ,  C07C59/185 ,  C07C59/01 ,  C07C55/14 ,  C07C67/08 ,  C07C69/02 ,  C07D313/04 ,  C07D307/33

CPC classification number: C07C29/145 ,  C07C29/149 ,  C07C29/80 ,  C07C51/313 ,  C07C67/08 ,  C07D307/33 ,  C07D313/04 ,  C07C35/14 ,  C07C31/125 ,  C07C59/185 ,  C07C59/01 ,  C07C55/14 ,  C07C69/02