摘要:
A novel metallic oxide of a Ln-Ca-Sr-Ba-Cu-B-O type and a process for manufacturing such a metallic oxide. The above metallic oxide has a composition expressed by the following formula (I):
(Ln 1-a Ca a )(Sr 2-b Ba b )(Cu 3-c B c )O d (I)
wherein Ln is one or more kinds of elements selected from the group consisting of Y and lanthanoid elements except for Ce and Tb and wherein the following conditions are met: 0.1≦a≦0.5, 0.7≦b≦1.7, 0.1≦c≦0.5, and 6.5≦d≦7.5. A process for manufacturing the metallic oxide has the following steps. A mixture of materials including H₃BO₃ used as a starting material of B is prepared. The resultant mixture is heated at a rate of 5°C or lower per minute up to 900°C or lower. Then, it is heated in an oxygen atmosphere at a range from 900 - 1050°C.
摘要:
Provided is a metal oxide material represented by the composition formula of Ln a Sr b Cu 3-x M x O c , where 2.7 ≦ a + b ≦ 3.3; 0.8 ≦ a ≦ 1.2; 6 ≦ c ≦ 9; and 0.05 ≦ x ≦ 0.7, Ln is at least one element selected from the group of elements of Y and lanthanoids or an atomic group consisting of said elements, and M is at least one element selected from the group of elements of Ti, V, Ga, Ge, Mo, W and Re or an atomic group consisting of said elements.
摘要:
An oxide superconductor comprising Ln₂BaCuO₅ and PtBaCuO with a mean particle diameter of 0.1 to 10 µm finely dispersed in the crystal of LnBa₂Cu₃O y , wherein Ln represents at least one rare earth element including Y; and a process for producing the same by melting a powdery raw material comprising composite oxides of Ln, Ba and Cu, rapidly cooling the melt to effect solidification, crushing the solid, adding thereto a Pt powder, molding the mixture, heating the molding into a semi-molten state, and cooling the resulting molding.
摘要翻译:一种氧化物超导体,其包含Ln 6 BaCuO psi和PtBaCuO,其平均粒径为0.1至10μm,其细分散在LnBa 6 Cu 7 O y的晶体中,其中Ln表示至少一种稀土元素 包括Y; 以及通过熔化包含Ln,Ba和Cu的复合氧化物的粉末原料,快速冷却熔融物进行固化,粉碎固体,加入Pt粉末,模塑混合物,将模塑物加热成 半熔融状态,并冷却所得模制品。
摘要:
A superconductive material is in composition expressed as (Y 0.33 Ba 0.67 ) a Cu b (OF) c . The usual a , b and c are so selected as to satisfy a relation expression ax (mix valence of A) + bx (mix valence of B) = cx (mix valence of C).