Abstract:
The invention concerns a process for preparing nitrobiphenylene of formula (I) wherein m stands for 1 or 2, R means halogen, R' or OR', R' being a C-organic group which can carry groups which are inert in the reaction conditions, n stands for 0, 1, 2 or 3 and, if n is 2 or 3, the R groups can also be different. According to the invention, a chloronitrobenzene of formula (II) is reacted in the presence of a palladium catalyst and a base in a solvent with a phenyl boric acid (IIIa), one of its alkyl esters of formula (IIIb), R1 meaning C¿1?-C6 alkyl, or one of its anhydrides. The compounds (I) are suitable as initial products for biphenylamines which are in turn intermediate products for fungicidal plant-growth substances.
Abstract:
The invention concerns phenylacetic acid derivatives of formula (I) in which the substituents and the indices have the following meanings: X denotes NOCH3, CHOCH3 and CHCH3; Y denotes oxygen or NRa; Ra denotes hydrogen or alkyl; R denotes cyano, nitro, trifluoromethyl, halogen, alkyl and alkoxy; m stands for 0, 1 or 2, wherein the rests R can be different if m is 2; R1 denotes hydrogen or alkyl; R?2 and R3¿, independently of each other, denote hydrogen, cyano, nitro, hydroxy, amino, halogen, optionally substituted alkyl, alkoxy, alkylthio, alkylamino, dialkylamino, alkenyl, alkenyloxy, alkenylthio, alkenylamino, N-alkenyl-N-alkylamino, alkinyl, alkinyloxy, alkinylthio, alkinylamino, N-alkinyl-N-alkylamino, cycloalkyl, cycloalkyloxy, cycloalkylthio, cycloalkylamino, N-cycloalkyl-N-alkylamino, cycloalkenyl, cycloalkenyloxy, cycloalkenylthio, cycloalkenylamino, N-cycloalkenyl-N-alkylamino, heterocyclyl, heterocyclyloxy, heterocyclylthio, heterocyclylamino, N-heterocyclyl-N-alkylamino, aryl, aryloxy, arylthio, arylamino, N-aryl-N-alkylamino, hetaryl, hetaryloxy, hetarylthio, hetarylamino and N-hetaryl-N-alkylamino; R4 denotes one of the groups mentioned in the case of R2 or a CRd=NORe group; Rd denotes one of the groups mentioned in the case of R?2; and Re¿ denotes hydrogen, optionally substituted alkyl, cycloalkyl, alkenyl, alkinyl, alkylcarbonyl, alkenylcarbonyl, alkinylcarbonyl, alkylsulphonyl, aryl, arylcarbonyl, arylsulphonyl, hetaryl, hetarylcarbonyl or hetarylsulphonyl. The invention also concerns their salts, a process for the preparation of these substances and their use.
Abstract:
The invention concerns pyridylacetic acid derivatives of formula (I) in which the substituents and the index have the following meanings: X is NOCH3, CHOCH3 and CHCH3; Y is oxygen or NRa; Ra is hydrogen or alkyl; R is cyano, nitro, trifluoromethyl, halogen, alkyl and alkoxy; m is 0, 1 or 2; R1 is hydrogen or alkyl; R?2 and R3¿, independently of each other, stand for hydrogen, cyano, nitro, hydroxy, amino, halogen, optionally substituted alkyl, alkoxy, alkylthio, alkylamino, dialkylamino, alkenyl, alkenyloxy, alkenylthio, alkenylamino, N-alkenyl-N-alkylamino, alkinyl, alkinyloxy, alkinylthio, alkinylamino, N-alkinyl-N-alkylamino, cycloalkyl, cycloalkyloxy, cycloalkylthio, cycloalkylamino, N-cycloalkyl-N-alkylamino, cycloalkenyl, cycloalkenyloxy, cycloalkenylthio, cycloalkenylamino, N-cycloalkenyl-N-alkylamino, heterocyclyl, heterocyclyloxy, heterocyclylthio, heterocyclylamino, N-heterocyclyl-N-alkylamino, aryl, aryloxy, arylthio, arylamino, N-aryl-N-alkylamino, hetaryl, hetaryloxy, hetarylthio, hetarylamino or N-hetaryl-N-alkylamino; R4 is one of the groups mentioned under R2 or a CRd =NORe group. The invention further concerns their salts, a process and intermediate products for their preparation and their use.
Abstract:
The invention relates to phenylacetic acid derivatives of the formula (I), in which the substituents and the index have the following meaning: X is NOCH3, CHOCH3, CHCH3 and CHCH2CH3; Y is NRa and O; Ra, R1 are hydrogen and alkyl; R2 is cyano, nitro, halogen, alkyl, alkyl halide and alkoxy; m is 0, 1 or 2; R3 is hydrogen, hydroxy, amino, cyano, halogen, alkyl, alkyl halide, cycloalkyl, alkoxy, alkylthio, alkylamino and dialkylamino; A is a 5 or 6 membered hetero-aromatic ring; R4 is a substituted aryl; R5 is hydrogen, optionally substituted alkyl, alkenyl, alkinyl, cycloalkyl, cycloalkenyl, heterocyclyl, aryl and hetaryl. The invention also relates to the salts of said derivatives, a process and intermediates for the preparation and use thereof.
Abstract:
Compounds of the general formula (I) in which n is 0, 1, 2, 3 or 4; R is nitro, cyano, halogen, possibly substituted alkyl, alkenyl, alkinyl, alkoxy, alkenyloxy, alkinyloxy or, if n is greater than 1, additionally a possibly substituted bridge bonded to two adjacent ring atoms; R1, R2 is alkyl; R3 is a substituted pyrazole or triazole radical of the formulae (A.1) to (A.3), in which the bond marked . is the bond to oxygen, process for their production and their use.
Abstract:
The present invention relates to new pyridine compounds which are useful for combating animal pests, in particular insects, arachnids and nematodes. The invention also relates to a method for combating insects, nematodes and arachnids. The pyridine compounds have the formula I as defined below. Likewise, compounds of the formula Il are suitable for combating pests. In formulae I and Il n is 1 or 2, and R1, R2, R3, R4 and R5 are as defined in the claims and in the specification.
Abstract:
Method for the production of 1,3,5-trifluoro-2,4,6-trichlorobenzene from fluorobenzene, comprising steps A) and B): A) chlorination of fluorobenzene derivatives of formula (II), in which X = fluorine or H, Z = nitro, bromo or chloro and n = 0 or 1-4 and B) fluorination of the distillation residue and separation by distillation of the 1,3,5-trifluoro-2,4,6-trichlorobenzene thus produced.
Abstract:
The invention relates to heteroaroyl-substituted serine amides of formula (I), wherein the variables A, Het, and R1 to R5 have the meanings indicated in the description, the agriculturally useful salts thereof, methods and intermediate products for manufacturing the same, and the use of said compounds or agents containing said compounds for controlling unwanted plants.
Abstract:
Triazolopyrimidines of formula (I), wherein the index and substituents have the following meaning: n = 0 or a whole number of 1 - 5; R = halogen, cyano, hydroxy, cyanate, alkyl, alkenyl, alkinyl, halogenalkyl, halogenalkenyl, alkoxy, alkenyloxy, alkinyloxy, halogenalkoxy, cycloalkyl, cycloalkenyl, cycloalkoxy, alkoxycarbonyl, alkenyloxycarbonyl, alkinyloxycarbonyl, aminocarbonyl, alkylaminocarbonyl, dialkylaminocarbonyl, alkoximinoalkyl, alkenyloximinocarbonyl, alkinyloximinoalkyl, alkylcarbonyl, alkenylcarbonyl, alkinylcarbonyl, cycloalkylcarbonyl or a five to ten membered saturated, partially unsaturated or aromatic heterocycle, containing one to four heteroatoms from the group O, N or S; R1 = alkyl, alkenyl, alkinyl, cycloalkyl, cycloalkenyl, phenyl, naphthyl or a five to ten membered saturated, partially unsaturated or aromatic heterocycle, containing one to four heteroatoms from the group O, N or S, R and/or R1 being able to be substituted according to the description; R2 = alkyl, alkenyl or alkinyl which can be substituted by halogen, cyano, nitro, alkoxy or alkoxycarbonyl. The invention also relates to a method for the production of said compounds, agents containing same, and the use thereof in controlling noxious fungi.
Abstract:
The invention relates to heteroaroyl-substituted phenylalanine amides of formula (I), in which A represents a C-bonded heteroaryl, in addition to their salts that can be used for agricultural applications. The invention also relates to methods and intermediate products for the production of said compounds and to the use of said compounds or agents containing said compounds for controlling undesirable plants.