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133 条记录 (耗时 0.013 秒)

    CATALYST RECYCLE METHODS
    73.
    发明公开
    CATALYST RECYCLE METHODS 审中-公开

    公开(公告)号：EP3140292A4

    公开(公告)日：2017-12-06

    申请号：EP15789639

    申请日：2015-04-29

    申请人： NOVOMER INC

    发明人： SOOKRAJ SADESH H

    IPC分类号： C07D305/12 ,  C07C51/09 ,  C07C67/30

    CPC分类号： C07D305/12 ,  B01J31/20 ,  B01J31/2217 ,  B01J31/403 ,  B01J38/74 ,  C07D307/60 ,  Y02P20/584

    摘要： The present invention provides novel solutions to the problem of recycling carbonylation catalysts in epoxide carbonylation processes. The inventive methods are characterized in that the catalyst is recovered in a form other than as active catalyst. In some embodiments, catalyst components are removed selectively from the carbonylation product stream in two or more processing steps. One or more of these separated catalyst components are then utilized to regenerate active catalyst which is utilized during another time interval to feed a continuous carbonylation reactor.

    Methods for generating and recycling metal halide catalyst compositions for aromatic ring halogenation
    75.
    发明公开
    Methods for generating and recycling metal halide catalyst compositions for aromatic ring halogenation 有权
    一种用于生产和氯化铜的催化剂组合物的回收为芳族化合物的核氯化过程

    公开(公告)号：EP2305380A1

    公开(公告)日：2011-04-06

    申请号：EP10169484.2

    申请日：2005-06-13

    申请人： SABIC Innovative Plastics IP B.V.

    发明人： Ganesan, Balakrishnan ,  Nadkarni, Pradeep Jeevaji ,  Colborn, Robert, Edgar ,  Hancu, Dan

    IPC分类号： B01J31/02 ,  B01J31/04 ,  B01J31/22 ,  B01J31/26 ,  B01J31/30 ,  B01J31/40 ,  B01J37/03 ,  B01J38/50 ,  C07C17/12

    CPC分类号： B01J27/32 ,  B01J31/02 ,  B01J31/0218 ,  B01J31/022 ,  B01J31/0244 ,  B01J31/0271 ,  B01J31/04 ,  B01J31/2226 ,  B01J31/2234 ,  B01J31/226 ,  B01J31/26 ,  B01J31/30 ,  B01J31/4015 ,  B01J31/403 ,  B01J38/50 ,  B01J2531/16 ,  B01J2531/48 ,  B01J2531/842 ,  C07C17/12 ,  Y02P20/584 ,  C07C25/125

    摘要： A method for recovering and reusing a ring-halogenation catalyst comprises:
    (A) Contacting an aromatic compound with chlorine or bromine in the presence of a catalyst composition, where the catalyst composition comprises at least one salt comprising a Group 4-13 metal, a lanthanide metal, or an actinide metal; and at least one organic counterion derived from an organic acid having a pKa relative to water of 0 or greater; and at least one organic sulfur compound; to form a first product mixture comprising a monochloro or a monobromo aromatic compound and a Group 4-13 metal halide, a lanthanide metal halide or an actinide metal halide;
    (B) Separating the metal halide from the first product mixture; and
    (C) Contacting at least a portion of the metal halide and an aromatic compound with chlorine or bromine, and at least one organic sulfur compound; to form a second product mixture comprising a monochloro or a monobromo aromatic compound and a Group 4-13 metal halide, a lanthanide metal halide or an actinide metal halide having a pKa relative to water of 0 or greater; and at least one organic sulfur compound.

    摘要翻译： 一种回收和再使用环卤化催化剂的方法包括：与氯或溴的催化剂组合物，其中催化剂组合物包括至少一种盐包括一组4-13金属的存在，一个芳族化合物（a）使 镧系金属，或锕系金属; 和至少一种有机反离子从具有pKa相对于0或更大的水的有机酸衍生的; 和至少一种有机硫化合物; 以形成第一产物混合物，其包括一氯或Monobromona芳族化合物和一种第4-13金属卤化物，镧系金属卤化物或锕系金属卤化物; （b）分离从第一产物混合物中的金属卤化物; 和（C）至少接触金属卤化物和与氯或溴，以及至少一种有机硫化合物的芳族化合物的一部分; 以形成第二产物混合物，其包括一氯或一Monobromona芳族化合物和一种第4-13金属卤化物，镧系金属卤化物或锕系的pKa相对于0或更大的水的金属卤化物; 和至少一种有机硫化合物。

    METHOD OF REACTION WITH SOLUBLE METALLIC CATALYST AND ANION-EXCHANGE RESIN, METHOD OF RECOVERING THE SOLUBLE METALLIC CATALYST, AND METHOD OF RECYCLING
    80.
    发明公开
    METHOD OF REACTION WITH SOLUBLE METALLIC CATALYST AND ANION-EXCHANGE RESIN, METHOD OF RECOVERING THE SOLUBLE METALLIC CATALYST, AND METHOD OF RECYCLING 审中-公开
    法进行回收可溶性金属催化剂与RECYCLEVERFAHREN的可溶性金属催化剂和阴离子交换树脂，流程实现的

    公开(公告)号：EP1382594A1

    公开(公告)日：2004-01-21

    申请号：EP02705352.9

    申请日：2002-03-19

    申请人： Nippon Shokubai Co., Ltd.

    发明人： KUBO, Takafumi

    IPC分类号： C07C67/26 ,  C07C69/54 ,  C07C69/16 ,  C07C69/28 ,  C07B41/12 ,  C07B61/00 ,  B01J38/74

    CPC分类号： C07C67/26 ,  B01J31/04 ,  B01J31/08 ,  B01J31/4015 ,  B01J31/403 ,  B01J38/74 ,  C07B61/00 ,  Y02P20/584 ,  C07C69/16 ,  C07C69/26 ,  C07C69/54 ,  C07C69/28

    摘要： The subject for the invention is to efficiently use, recover, and reuse a soluble metallic catalyst with great ease at low cost in various liquid-phase reactions using the soluble metallic catalyst.
    The invention provides a method of liquid-phase reaction using a soluble metallic catalyst in which the soluble metallic catalyst is caused to coexist with an anion-exchange resin during the reaction and the reaction is conducted under such conditions that 50% or more of the soluble metallic catalyst is adsorbed onto the anion-exchange resin. The anion-exchange resin having the soluble metallic catalyst adsorbed thereon is separated from the liquid reaction mixture to thereby recover the soluble metallic catalyst and reuse it in a liquid-phase reaction.

    摘要翻译： 对于本发明的主题是为了有效地使用，回收，并且在使用可溶性金属催化剂的各种液相反应成本低重用非常方便的可溶性金属催化剂。 本发明提供了使用可溶性的金属催化剂，其中所述可溶性金属催化剂引起与阴离子交换树脂在反应过程中共存的液相反应的方法，并且该反应是调查条件下进行那样的50％或 更可溶性金属催化剂的被吸附到阴离子交换树脂。 其上具有可溶性金属催化剂吸附在阴离子交换树脂从液体反应混合物中分离，从而回收可溶性金属催化剂和在液相反应重复使用它。