摘要:
Disclosed is a lubricant base stock, exhibiting a combination of high flash point, low evaporation loss, high viscosity and unexpectedly exceptionally low pour point and high viscosity index value. Said lubricant base stock comprises at least one ester between 2-propylheptanoic acid and at least one 2,2-substituted 1,3-propanediol and/or at least one dimer, trimer or polymer thereof and/or at least one alkoxylated species of a said 2,2-substituted 1,3-propanediol or a said dimer, trimer or polymer thereof.
摘要:
Ester polyol esters are a unique class of lubricants that have adjustable molecular weights, viscosities, and pour points based on the character of their reaction materials and relative ratios. There is provided a method for preparing at least one ester polyol ester, the method comprising the method comprising preparing a reaction mixture comprising at least one polyol compound; at least one dicarboxylic acid; and at least one monocarboxylic acid, wherein the at least one polyol compound is esterified with the at least one dicarboxylic acid and the at least one monocarboxylic acid, wherein the reaction mixture has a hydroxyl group to carboxyl group ratio (HCR) corresponding to a ratio of moles of hydroxyl groups to moles of carboxyl groups, and the HCR is less than about 1.
摘要:
An object of the present invention is to provide a lubricant having excellent lubrication performance. Further, another object of the present invention is to produce a polyester composition having a small load on an environment and mass productivity. The present invention relates to a production method for a complex polyester composition including a step of obtaining a complex polyester composition by condensing polyhydric alcohol, polycarboxylic acid having at least two carboxyl groups and carbon atoms of greater than or equal to 5, monohydric alcohol having at least one oxyalkylene group in the absence of a solvent, in which a component having a weight average molecular weight of less than or equal to 1300 in a GPC chart of the complex polyester composition is less than or equal to 43 area%. Further, the present invention relates to a complex polyester composition, a lubricant composition, and a lubricant.
摘要:
The present invention provides a working fluid composition for a refrigerating machine, comprising: a refrigerating machine oil comprising, as a base oil, a mixed ester of (A) a complex ester obtainable by synthesis of at least one polyhydric alcohol selected from neopentyl glycol, trimethylolpropane and pentaerythritol, a C6-C12 polybasic acid, and a C4-C18 monohydric alcohol or a C4-C18 monocarboxylic fatty acid, and (B) a polyol ester obtainable by synthesis of at least one polyhydric alcohol selected from neopentyl glycol, trimethylolpropane, pentaerythritol and dipentaerythritol, and a C4-C18 monocarboxylic fatty acid, in a mass ratio of (A) the complex ester/(B) the polyol ester of 5/95 to 95/5; and a hydrocarbon refrigerant having 3 or 4 carbon atoms, wherein a refrigerant dissolved viscosity, at a temperature of 80°C and an absolute pressure of 1.5 MPa, is 1.0 mm 2 /s or more.
摘要:
Ester polyol esters are a unique class of lubricants that have adjustable molecular weights, viscosities, and pour points based on the character of their reaction materials and relative ratios. There is provided a method for preparing at least one ester polyol ester, the method comprising the method comprising preparing a reaction mixture comprising at least one polyol compound; at least one dicarboxylic acid; and at least one monocarboxylic acid, wherein the at least one polyol compound is esterified with the at least one dicarboxylic acid and the at least one monocarboxylic acid, wherein the reaction mixture has a hydroxyl group to carboxyl group ratio (HCR) corresponding to a ratio of moles of hydroxyl groups to moles of carboxyl groups, and the HCR is less than about 1.
摘要:
A method of retaining or decreasing the pour point of an estolide base oil by increasing the EN of the estolide base oil, comprising selecting an estolide base oil having an initial EN and an initial pour point and removing at least a portion of the estolide base oil, said portion exhibiting an EN that is less than the initial EN of the estolide base oil. The resulting estolide base oil exhibits an EN that is greater than the initial EN of the estolide base oil, and a pour point that is equal to or lower than the initial pour point of the estolide base oil.
摘要:
A process to prepare an estolide derivative composition comprises reacting a triglyceride having an unsaturation level of less than 0.1 m Eq/g and an alcohol having from 2 to 22 carbon atoms, under conditions such that a product including an oligomerized ester having residual hydroxyl groups is formed; and reacting the product with a capping agent under conditions such that an estolide derivative composition is formed. The compositions may exhibit desirably low pour point, desirable viscosity and thermoxidative stability, and a high level of renewable carbons, making them suitable for use as biolubricants, process fluids, plasticizers, or starting materials for polyurethane polymers.