USE OF 4-CYANO-NAPHTHALENE-1, 8-DICARBOXIMIDE DERIVATIVES AND RELATED COMPOUNDS TO PROTECT ORGANIC MATERIAL FROM THE DAMAGING EFFECTS OF LIGHT
    3.
    发明公开
    USE OF 4-CYANO-NAPHTHALENE-1, 8-DICARBOXIMIDE DERIVATIVES AND RELATED COMPOUNDS TO PROTECT ORGANIC MATERIAL FROM THE DAMAGING EFFECTS OF LIGHT 有权
    作者4-氰基萘-1,8-DICARBONSÄUREIMIDDERIVATEN及相关化合物用于保护有机材料对光的有害影响USE

    公开(公告)号:EP1687278A1

    公开(公告)日:2006-08-09

    申请号:EP04818398.2

    申请日:2004-11-12

    IPC分类号: C07D221/14

    CPC分类号: C07D221/14

    摘要: A description is given of the use of naphthalene-1,8-dicarboxylic monoimides of the formula (I), in which R1 is hydrogen, alkyl, alkenyl, cycloalkyl, cycloalkenyl, heterocycloalkyl, aryl or heteroaryl and R2 is a radical containing at least one π electron system containing a carbon atom and at least one further atom selected from carbon, oxygen, and nitrogen, with the proviso that the radical contains at least one atom other than carbon; to protect organic material from the damaging effects of light, of compositions which comprise at least one naphthalene-1,8-dicarboxylic monoimide of the formula (I) in an amount which provides protection from the damaging effects of light, and at least one organic material, and of new naphthalene-1,8-dicarboxylic monoimides (I).

    VERFAHREN ZUR UEBERFUEHRUNG VON PERYLEN-3,4:9, 10-TETRACARBONSAEUREDIIMIDEN IN EINE FUER DIE ANWENDUNG ALS FLUORESZENZFARBMITTEL GEEIGNETE FORM
    8.
    发明授权
    VERFAHREN ZUR UEBERFUEHRUNG VON PERYLEN-3,4:9, 10-TETRACARBONSAEUREDIIMIDEN IN EINE FUER DIE ANWENDUNG ALS FLUORESZENZFARBMITTEL GEEIGNETE FORM 有权
    VERFAHREN ZUR UEBERFUEHRUNG VON PERYLEN-3,4:9,10-TETRACARBONSAEEDIIMIDEN IN EINE FUER DIE ANWENDUNG ALS FLUORESZENZFARBMITTEL GEEIGNETE FORM

    公开(公告)号:EP1516018B1

    公开(公告)日:2005-11-23

    申请号:EP03735563.3

    申请日:2003-06-06

    IPC分类号: C09B5/62

    CPC分类号: C09B67/0014 C09B67/0025

    摘要: Disclosed is a method for converting perylen-3,4:9,10-tetracarboxylic acid diimides of general formula I in which R and R represent unbranched, branched, or cyclical C1-C8-alkyl, into a form that is suitable for use as a fluorescent dye by a) solving or suspending the perylen-3,4:9,10-tetracarboxylic acid diimides in an organic or inorganic solvent, the molecules of which have a molecular volume of = 230 ANGSTROM , at 0 to 250 DEG C; b1) cooling the solution obtained in step a) to or below the crystallization temperature and at the same time optionally removing excess solvent until crystals start forming in case an organic solvent is used or adding water or diluted aqueous solutions of the solvent until crystals start forming in case an inorganic solvent is used, and maintaining said solution at said temperature for further crystallization; or b2) cooling the suspension obtained in step a) to or below the crystallization temperature if the temperature in step a) was above the crystallization temperature and maintaining the suspension at said temperature for further crystallization; c) isolating the solvate crystals formed in step b); and d) then removing the solvent from the solvate crystals. Also disclosed are novel crystalline forms of perylen-3,4:9,10-tetracarboxylic acid diimides.

    摘要翻译: 公开了用于将通式I的苝-3,4:9,10-四甲酸二酰亚胺(其中R 1和R 2代表无支链,支链或环状C 1 -C 8烷基)转化成 其适合用作荧光染料:a)将苝-3,4:9,10-四甲酸二酰亚胺溶解或悬浮在有机或无机溶剂中,其分子的分子量为230Å<3 在0至250℃下; b1)将步骤a)中获得的溶液冷却至结晶温度或低于结晶温度,并且同时任选地除去过量的溶剂直至在使用有机溶剂的情况下开始形成晶体或者加入水或稀释的溶剂水溶液直至晶体开始形成 在使用无机溶剂的情况下,并且将所述溶液保持在所述温度以进一步结晶; 或b2)如果步骤a)中的温度高于结晶温度并将悬浮液保持在所述温度以进一步结晶,则将步骤a)中获得的悬浮液冷却至或低于结晶温度; c)分离步骤b)中形成的溶剂合物晶体; 和d)然后从溶剂合物晶体中除去溶剂。 还公开了苝-3,4:9,10-四甲酸二酰亚胺的新颖结晶形式。

    TERT.-ALKYLPHENOXYSUBSTITUIERTE POLYCYCLISCHE VERBINDUNGEN
    9.
    发明授权
    TERT.-ALKYLPHENOXYSUBSTITUIERTE POLYCYCLISCHE VERBINDUNGEN 有权
    叔丁基苯氧基缩水甘油聚环酯VERBINDUNGEN

    公开(公告)号:EP1373272B1

    公开(公告)日:2005-06-29

    申请号:EP02735166.7

    申请日:2002-03-20

    摘要: Tert. alkylphenoxy substituted polycyclic compounds of general formula (I), in which the variables have the following meanings: P = a conjugated polycyclic group, optionally aryl substituted, stable to base and acid and not containing residues from the group -CO-NH-CO-, -COOH and -CO-O-CO-; R = C1-C8 alkyl, the carbon chain of which may be interrupted by one or several groups of -O-, -S-, -NR1-, -CO- and/or -SO¿2?- and which may be mono- or serially-substituted by C1-C6 alkoxy or a 5- to 7-membered heterocyclic group, bonded by means of a nitrogen atom, which can contain further heteroatoms and can be aromatic, C5-C8 cycloalkyl, the carbon skeleton of which may be interrupted by one or several groups of -O-, -S-, -NR?1¿-, -CO- and/or -SO¿2?- and may optionally be substituted with C1-C6 alkyl; R?1¿ = H or C¿1?-C6 alkyl; Hal = chlorine and/or bromine; m = a number from 0 to 15; n = a number from 1 to 16, whereby the sum m + n ≤ 16, production and use thereof.

    摘要翻译: 叔。 (I)的烷基苯氧基取代的多环化合物,其中变量具有以下含义:P =共轭多环基团,任选被芳基取代,对碱和酸稳定并且不含来自基团-CO-NH-CO- ,-COOH和-CO-O-CO-; R = C 1 -C 8烷基,其碳链可以被-O - , - S - , - NR 1 - , - CO-和/或-SO 2 - 的一个或几个基团间隔,并且可以是单 - 或通过可含有其他杂原子且可为芳族的氮原子键合的C1-C6烷氧基或5至7元杂环基连续取代的C 5 -C 8环烷基,其碳骨架可以是 被-O - , - S-,-NR 1 - , - CO-和/或-SO 2 - 的一个或几个基团中断,并且可以任选地被C 1 -C 6烷基取代; R 1 = H或C 1 -C 6烷基; Hal =氯和/或溴; m =从0到15的数字; n =从1到16的数字,由此总和m +n≤16,其生产和使用。