VERFAHREN ZUR HERSTELLUNG VON SALZEN DER POLYASPARAGINSÄURE
    3.
    发明公开
    VERFAHREN ZUR HERSTELLUNG VON SALZEN DER POLYASPARAGINSÄURE 失效
    用于生产聚天冬氨酸盐

    公开(公告)号:EP0777696A1

    公开(公告)日:1997-06-11

    申请号:EP95929870.0

    申请日:1995-08-16

    IPC分类号: C08G69 C02F5 C08G73 C11D3

    摘要: A process is disclosed for preparing polyaspartic acid salts by treating polycondensates in an aqueous medium with bases. At least 0.7 equivalents of an alkaline metal and/or alkaline earth metal base per mole of the aspartic acid, aspartic acid imide and/or amide units contained in the polycondensates are used. The bases are added during 30 minutes to 20 hours to an aqueous suspension of the polycondensates of aspartic acid heated up to 40 to 140 °C, and the reaction mixture is optionally allowed to continue to react. These alkaline metal and/or alkaline earth metal salts of polyaspartic acids obtained by treating aspartic acid polycondensates in an aqueous medium with more than 1 equivalent of an alkaline metal and/or alkaline earth metal base for reducing the molar mass of polycondensates are used as additives for washing and cleaning agents.

    PHOSPHONIUMSALZE UND IHRE VERWENDUNG ALS GLANZMITTEL FÜR WÄSSRIG-SAURE GALVANISCHE NICKELBÄDER
    8.
    发明公开
    PHOSPHONIUMSALZE UND IHRE VERWENDUNG ALS GLANZMITTEL FÜR WÄSSRIG-SAURE GALVANISCHE NICKELBÄDER 失效
    磷及其作为增白剂用于水,电偶ACID镍浴的。

    公开(公告)号:EP0633888A1

    公开(公告)日:1995-01-18

    申请号:EP93906587.0

    申请日:1993-03-23

    IPC分类号: C07F9 C25D3

    摘要: Phosphonium salts of formula (I) in which: R1 to R3 are C¿1? to C18 alkyl which may be substituted by carboxyl groups or C1 to C4 alkoxycarbonyl groups or cyano groups, C2 to C12 alkenyl, C2 to C12 alkinyl, C5 to C8 cycloalkyl, C7 to C12 phenylalkyl, phenyl which may be substitued by one or two C1 to C4 alkyl radicals, C1 to C4 alkoxy radicals, halogen atoms, hydroxyl groups, phenyl radicals or C1 to C4 alkoxy carbonyl groups, or mono or di(C1 to C4 alkyl)amino; R?4 and R5¿ are hydrogen or C¿1? to C4 alkyl; A is hydrogen or a group of the formula -OCO-H, -CO-R?6¿, -CO-OH, -CO-OR6, -CO-CH2-CO-OR6, -O-CO-H, O-CO-R?6, -OR6, -SO¿2-R6, -SO2-OH, -SO2-OR6, -PO(OH)¿2?, PO(OH)(OR?6¿), -PO(OR6)2, -OPO(OH)2, -OPO(OH)(OR6) or -OPO(OR6)2; where R6 is C1 to C12 alkyl, C2 to C12 alkenyl, C2 to C12 alkinyl, C5 to C8 cycloalkyl, C7 to C12 phenylalkyl or phenyl which may be substituted by one or two C1 to C4 alkyl radicals, C1 to C4 alkoxy radicals, halogen atoms, hydroxyl groups, phenyl radicals or C1 to C4 alkoxy carbonyl groups; Y stands for the group -CH=CH- or -C=C-; m is a number from 0 to 10; n is a number from 1 to 4; p is 0 or 1; and q is a number from 0 to 10; and X- is an n-valent inorganic or organic anion improving water solubility. The phosphonium salts I are suitable as brighteners for aqueous-acid galvanic nickel baths.