公开(公告)号：EP2020407A1

公开(公告)日：2009-02-04

申请号：EP07743582.4

申请日：2007-05-17

申请人： Chisso Corporation ,  Chisso Petrochemical Corporation

发明人： URATA, Yasuo ,  OSHIMA, Shunji ,  NISHIBATA, Ryousuke ,  KODAKI, Keiichi ,  TAKEUCHI, Hiroyuki ,  MATSUI, Shuichi

IPC分类号： C07D305/12 ,  C07D405/10 ,  C07D407/08

CPC分类号： C07D305/12 ,  C07D405/10 ,  C07D407/08

摘要： An aldehyde derivative represented by the general formula (2) is reacted with ketene in the presence of a Lewis acid catalyst to produce a novel 2-oxetanone derivative (1), which is then purified to a 2-oxetanone derivative having a high trans-isomer purity, and then converted to a vinyl derivative (3) through decarboxylation reaction.

摘要翻译： 通式（2）表示的醛衍生物与路易斯酸催化剂存在下的乙烯酮反应生成新的2-氧杂环丁酮衍生物（1），然后将其纯化成具有高反式 - 异构体纯度，然后通过脱羧反应转化成乙烯基衍生物（3）。

公开(公告)号：EP0949231B1

公开(公告)日：2007-05-02

申请号：EP97946802.2

申请日：1997-11-27

申请人： Chisso Corporation

发明人： KONDO, Tomoyuki ,  MIYAZAWA, Kazutoshi ,  TAKEUCHI, Hiroyuki ,  MATSUI, Shuichi ,  HISATSUNE, Yasusuke ,  TAKESHITA, Fusayuki ,  NAKAGAWA, Etsuo

IPC分类号： C07C25/18 ,  C07C43/225 ,  C09K19/10 ,  G02F1/13 ,  C09K19/46 ,  C09K19/44 ,  C09K19/12 ,  C09K19/14 ,  C09K19/20

CPC分类号： C07C17/12 ,  C07C17/263 ,  C07C17/35 ,  C07C25/18 ,  C07C43/225 ,  C07C45/004 ,  C09K19/10 ,  C09K19/44 ,  C09K19/46 ,  C07C49/813

摘要： Liquid-crystalline compounds which have an extremeley high voltage retention, an extremely small temperature dependence of the retention, a low threshold voltage, and a large value of Δn; a liquid-crystal composition containing any of the liquid-crystal compounds; and a liquid-crystal display element containing the liquid-crystal composition. The compounds are represented by general formula (1), wherein R represents C1-20 alkyl, in which arbitrary non adjacent methylene groups (-CH2-) may have been replaced with oxygen atoms (-O-); Y1 to Y16 each independently represents hydrogen or fluorine, provided at least two of them are fluorine atoms and that at least two hydrogen atoms of each 1,4-phenylene group have not been replaced with fluorine atoms; X represents halogeno or C1-20 alkyl in which arbitrary non adjacent methylene groups may have been replaced with oxygen atoms and any hydrogen has optionally been replaced with fluorine; and Z1, Z2, and Z3 each independently represents -(CH2)2-, -(CH2)4-, -CH2O-, -OCH2-, -(CH2)3O-, -O(CH2)3- or a single bond; and each atom contained in this compound may have been replaced with an isotope thereof; provided when X is -OCF2CF2H, Z1 and Z3 are both single bonds, and Z2 is -(CH2)2-, then none of Y6, Y10, and Y12 is F, and none of Y1 to Y5, Y7 to Y9, Y11, and Y13 to Y16 is H; none of Y2, Y10, and Y12 is F, and none of Y1, Y3 to Y9, Y11, and Y13 to Y16 is H; or none of Y2, Y4, Y10, and Y12 is F and none of Y1, Y3, Y5 to Y9, Y11, and Y13 to Y16 is H.

公开(公告)号：EP0949232A1

公开(公告)日：1999-10-13

申请号：EP97947960.7

申请日：1997-12-16

申请人： CHISSO CORPORATION

发明人： KATO, Takashi ,  MATSUI, Shuichi ,  MIYAZAWA, Kazutoshi ,  TAKESHITA, Fusayuki ,  NAKAGAWA, Etsuo

IPC分类号： C07C25/18 ,  C07C25/24 ,  C07C43/192 ,  C07C43/225 ,  C07D239/26 ,  C07F9/54 ,  C09K19/12 ,  C09K19/14 ,  C09K19/20 ,  C09K19/30 ,  C09K19/34 ,  C09K19/42 ,  G02F1/13

CPC分类号： C07C17/16 ,  C07B59/001 ,  C07C17/12 ,  C07C17/263 ,  C07C17/2632 ,  C07C17/269 ,  C07C17/354 ,  C07C25/18 ,  C07C25/24 ,  C07C43/192 ,  C07C43/225 ,  C07C45/513 ,  C07C45/60 ,  C07C2601/14 ,  C07F7/0896 ,  C09K19/0403 ,  C09K19/14 ,  C09K19/20 ,  C09K19/3003 ,  C09K19/3066 ,  C09K19/3402 ,  C09K19/3444 ,  C09K19/3458 ,  C09K19/3491 ,  C09K19/42 ,  C09K2019/0407 ,  C09K2019/3027 ,  C09K2019/3422 ,  Y10T428/10 ,  C07C22/00 ,  C07C47/105

摘要： Disclosed are liquid crystalline compounds which (i) are characterized in that the compounds have a wide temperature range in which the compounds exhibit a liquid crystal phase, are low in viscosity, and have a negative and high Δε, (ii) are readily mixed with other various liquid crystal materials even at low temperatures, and (iii) are useful as component of liquid crystal compositions suitable both for TFT type display mode and IPS mode; and liquid crystal composition comprising the liquid crystalline compound; the compounds are expressed by the general formula (1)
wherein R 1 represents an alkyl group having 1 to 15 carbon atoms; ring A 1 , ring A 2 , and ring A 3 independently represent trans-1,4-cyclohexylene group, trans-1,4-silacyclohexylene group, pyrimidine-2,5-diyl group, pyridine-2,5-diyl group, 1,3-dioxane-2,5-diyl group, tetrahydropyran-2,5-diyl group, 1,3-dithian-2,5-diyl group, or tetrahydrothiopyran-2,5-diyl group, or 1,4-phenylene group in which one or more hydrogen atoms on the six-membered ring may be replaced by a halogen atom; X 1 , X 2 , and X 3 independently represent -(CH 2 ) 4 -, -(CH 2 ) 3 O-, -O(CH 2 ) 3 -, or single bond; Y 1 represents hydrogen atom or an alkyl group having 1 to 15 carbon atoms; m and n are independently 0 or 1; and any atom which constitutes this compound may be replaced by its isotope.

公开(公告)号：EP0947501A1

公开(公告)日：1999-10-06

申请号：EP97913456.6

申请日：1997-11-27

申请人： CHISSO CORPORATION

发明人： FUJITA, Atsuko ,  TAMURA, Norio ,  MATSUI, Shuichi ,  MIYAZAWA, Kazutoshi ,  TAKEUCHI, Hiroyuki ,  KUBO, Yasuhiro ,  TAKESHITA, Husayuki ,  NAKAGAWA, Etsuo

IPC分类号： C07C255/31 ,  C07C255/32 ,  C07D239/24 ,  C07D319/06 ,  C09K19/10 ,  C09K19/30 ,  C09K19/34 ,  G02F1/13

CPC分类号： C07D239/26 ,  C07C255/31 ,  C07C255/34 ,  C07C255/35 ,  C07C255/37 ,  C07C255/38 ,  C07C2601/08 ,  C07C2601/14 ,  C07D319/06 ,  C09K19/04 ,  C09K19/3001 ,  C09K19/3003 ,  C09K19/3028 ,  C09K19/3048 ,  C09K19/3059 ,  C09K19/42 ,  C09K19/44 ,  C09K19/46 ,  C09K2019/0448 ,  C09K2019/0451 ,  C09K2019/0496

摘要： Disclosed are novel liquid crystalline compounds having a wide temperature range of liquid crystal phase, a high dielectric anisotropy, and a high optical anisotropy; liquid crystal compositions comprising the compound; and liquid crystal display devices fabricated by using the liquid crystal composition; and the liquid crystalline compounds are cyclohexane derivatives expressed by the following general formula (1)
wherein R represents an alkyl group having 1 to 10 carbon atoms in which alkyl group, methylene group may be replaced by oxygen atom or ethylene group (-CH=CH-) provided that in no case continued methylene groups are simultaneously replaced by one of these groups; A 1 , A 2 , A 3 , and A 4 represent 1,4-cyclohexylene group, 1,3-pyrimidine-2,5-diyl group, or 1,3-dioxane-2,5-diyl group, or 1,4-phenylene group which may be replaced by fluorine atom; B 1 , B 2 , and B 3 independently represent a covalent bond, 1,2-ethylene group, 1,2-ethenylene group, 1,2-ethynylene group, carbonyloxy group, methylenoxy group, or 1,4-butylene group; m, n, and p are 0 or 1; and G represents the group expressed by the general formula (2), (3), or (4).

摘要翻译： 公开了具有宽的液晶温度范围，高介电各向异性和高光学各向异性的新型液晶化合物; 包含该化合物的液晶组合物; 以及使用该液晶组合物制造的液晶显示装置; 液晶性化合物为下述通式（1）表示的环己烷衍生物，其中，R表示碳原子数1〜10的烷基，可以被氧原子或亚乙基代替亚甲基（ - CH = CH-），条件是在任何情况下，连续的亚甲基同时被这些基团中的一个取代; A1，A2，A3和A4表示1,4-亚环己基，1,3-嘧啶-2,5-二基或1,3-二恶烷-2,5-二基或1,4-亚苯基 其可以被氟原子取代; B1，B2和B3独立地表示共价键，1,2-亚乙基，1,2-亚乙烯基，1,2-亚乙炔基，羰氧基，亚甲氧基或1,4-亚丁基; m，n和p为0或1; G表示通式（2），（3）或（4）表示的基团。

公开(公告)号：EP0926120A1

公开(公告)日：1999-06-30

申请号：EP97924341.7

申请日：1997-06-06

申请人： CHISSO CORPORATION

发明人： KONDO, Tomoyuki ,  MATSUI, Shuichi ,  MIYAZAWA, Kazutoshi ,  TAKEUCHI, Hiroyuki ,  TAKESHITA, Fusayuki ,  NAKAGAWA, Etsuo

IPC分类号： C07C43/225 ,  C07D319/06 ,  C09K19/12 ,  C09K19/14 ,  C09K19/30 ,  C09K19/34 ,  C09K19/42 ,  G02F1/13

CPC分类号： C09K19/3001 ,  C07C43/225 ,  C07C2601/14 ,  C07C2601/16 ,  C09K19/04 ,  C09K19/14 ,  C09K19/3028 ,  C09K19/42 ,  C09K19/46 ,  Y10T428/10

摘要： Liquid-crystal compounds which are excellent in compatibility with other liquid-crystal materials particularly even at low temperatures, have a high voltage retention and a low threshold voltage, are lowered in the temperature dependence of these characteristic values, have a high Δn value, and exhibit liquid-crystal properties over a wide temperature range, the compounds being represented by the general formula: R a -A 1 -Z 1 -A 2 -Z 2 -(-A 3 -Z 3 -) m -A 0 -Rf (wherein m is 0 or 1; A 0 , A 1 , A 2 and A 3 are each a six-membered ring, with A 0 being 1,4-phenylene which may be substituted with one to three fluorine and/or chlorine atoms and A 1 , A 2 and A 3 being selected each independently from among trans-1,4-cyclohexane, optionally halogenated 1,4-phenylene, cyclohexene-1,4-diyl and 1,3-dioxane-2,5-diyl; Z 1 , Z 2 and Z 3 are each independently a bridge between rings and selected from among -(CH 2 ) 2 -, -(CH 2 ) 4 -, -CH 2 O-and -OCH 2 - which may be halogenated, and single bond (-); Rf is -OCF 2 CF 2 H or -OCF 2 CFHCF 3 ; and Ra is a C 1 -C 20 linear or branched monovalent organic group); liquid-crystal compositions comprising at least one of the compounds; and liquid-crystal display devices made by using the compositions.

摘要翻译： 与其他液晶材料的相容性优异，特别是即使在低温下也具有高电压保持和低阈值电压的液晶化合物在这些特性值的温度依赖性方面降低，具有高DELTA n值， 并且在宽的温度范围内具有液晶性能，该化合物由通式表示：Ra-A1-Z1-A2-Z2 - （ - A3-Z3-）m-A0-Rf（其中m为0或1 A 0，A 1，A 2和A 3分别为六元环，A 0为可被1〜3个氟原子和/或氯原子取代的1,4-亚苯基，A1，A2和A3各自独立地选自 反式-1,4-环己烷，任选卤代的1,4-亚苯基，环己烯-1,4-二基和1,3-二恶烷-2,5-二基; Z 1，Z 2和Z 3各自独立地为环之间的桥， 可以被卤化的 - （CH 2）2 - ， - （CH 2）4 - ， - CH 2 O-和-OCH 2 - ，和单键（ - ）; R f是-OCF 2 CF 2 H或-OCF 2 CFHCF 3; Ra为C1-C20直链或支链一价有机基团）; 包含至少一种化合物的液晶组合物; 以及使用该组合物制成的液晶显示装置。

公开(公告)号：EP0893424A1

公开(公告)日：1999-01-27

申请号：EP97915683.3

申请日：1997-04-09

申请人： CHISSO CORPORATION

发明人： MATSUI, Shuichi ,  KOIZUMI, Yasuyuki ,  MIYAZAWA, Kazutoshi ,  SEKIGUCHI, Yasuko ,  NAKAGAWA, Etsuo

IPC分类号： C07C43/225 ,  C07C255/54 ,  C09K19/20 ,  C09K19/30 ,  C09K19/42 ,  G02F1/13

CPC分类号： C07C255/54 ,  C07C43/225 ,  C07C255/50 ,  C07C255/57 ,  C07C2601/14 ,  C09K19/3066

摘要： An object of the invention is to provide novel liquid crystalline compounds which 1) exhibit a low threshold voltage, 2) have a low viscosity, 3) maintain or lower dielectric anisotropy of liquid crystal compositions when added thereto, and further are excellent in miscibility with other known liquid crystalline compounds, particularly excellent in the miscibility at low temperatures; to provide liquid crystal compositions comprising the compound; and to provide liquid crystal display devices comprising the composition; and the liquid crystalline compounds are α, α-difluorobenzyl ether derivatives expressed by the general formula (1)
wherein R 1 represents a straight chain or branched alkyl group having 1 to 15 carbon atoms or an alkenyl group having 2 to 15 carbon atoms one or not-adjacent two or more CH 2 groups in the alkyl or alkenyl group may be replaced by oxygen atom; ring A and ring B independently represent 1,4-cyclohexylene group one or more CH 2 groups on the ring may be replaced by oxygen atom or sulfur atom, or 1,4-phenylene group one or more CH groups on the ring may be replaced by nitrogen atom, and one or more hydrogen atoms on the ring may be replaced by a halogen atom; ring C and ring D independently represent 1,4-phenylene group one or more hydrogen atoms on the ring may be replaced by a halogen atom; Z 1 , Z 2 , and Z 3 independently represent -CH 2 CH 2 -, -CH=CH-, -C≡C-, or single bond; X represents a halogen atom, CF 3 , OCF 3 , OCHF 2 , or CN; Y represents hydrogen atom or a halogen atom; ℓ and m are 0 or 1; ℓ + m ≦ 1 ; and an element which constitutes the compound may be replaced by its isotope.

摘要翻译： 本发明的目的是提供一种新的液晶化合物，其具有低阈值电压，2）具有低粘度，3）当添加时保持或降低液晶组合物的介电各向异性，并且与 其他已知的液晶化合物，在低温下的混溶性特别优异; 以提供包含该化合物的液晶组合物; 并提供包含该组合物的液晶显示装置; 液晶化合物是由通式（1）表示的α，α-二氟苄醚衍生物，其中R 1表示碳原子数1〜15的直链或支链烷基或具有2〜 烷基或烯基中的一个或不相邻的两个或更多个CH 2基团的15个碳原子可被氧原子取代; 环A和环B独立地表示1,4-亚环己基，环上的一个或多个CH 2基可以被氧原子或硫原子代替，或1,4-亚苯基可以被环上的一个或多个CH基取代 氮原子和环上的一个或多个氢原子可以被卤素原子取代; 环C和环D独立地表示1,4-亚苯基，环上的一个或多个氢原子可被卤素原子取代; Z 1，Z 2和Z 3独立地表示-CH 2 CH 2 - ， - CH = CH - ， - C≡C-或C- X表示卤素原子，CF 3，OCF 3，OCHF 2或CN; Y表示氢原子或卤素原子; l和m为0或1; 1 + m <1; 并且构成化合物的元素可以被其同位素代替。

公开(公告)号：EP0881221A1

公开(公告)日：1998-12-02

申请号：EP97928518.6

申请日：1997-06-30

申请人： CHISSO CORPORATION

发明人： HASEBA, Yasuhiro ,  KONDOU, Tomoyuki ,  MATSUI, Shuichi ,  MIYAZAWA, Kazutoshi ,  TAKEUCHI, Hiroyuki ,  HISATSUNE, Yasusuke ,  TAKESHITA, Fusayuki ,  NAKAGAWA, Etsuo

IPC分类号： C07D319/06 ,  C07D239/26 ,  C09K19/34 ,  C09K19/42 ,  G02F1/13

CPC分类号： C09K19/3402 ,  C07D319/06 ,  C09K19/40 ,  C09K19/406 ,  C09K2019/3422 ,  Y10T428/10

摘要： The present invention provides liquid crystalline compounds having a high voltage holding ratio and a remarkably high Δ ε value, electric and chemical stability, and having good compatibility with known liquid crystalline compounds, liquid crystal compositions containing the compound, and liquid crystal display devices constituted by using the compounds.
The liquid crystalline compounds of the present invention are particular dioxane derivatives represented by general formula (1). Further, the present invention relates to liquid crystal compositions characterized in that the compositions comprise at least one of the derivatives, and liquid crystal display devices constituted by using the compositions.

摘要翻译： 本发明提供具有高电压保持率和显着高的DELTA小量值，电和化学稳定性，并且具有与由构成公知的液晶化合物，液晶组合物含有化合物，和液晶显示装置良好的相容性的液晶化合物 使用所述化合物。 本发明的液晶化合物是由通式（1）表示的特殊的二恶烷衍生物。 此外，本发明涉及在管芯DASS组合物为特征的液晶组合物包括衍生物中的至少一个，并且通过使用该组合物构成的液晶显示装置。

公开(公告)号：EP0846670A1

公开(公告)日：1998-06-10

申请号：EP96926607.1

申请日：1996-08-08

申请人： CHISSO CORPORATION

发明人： KATO, Takashi ,  MATSUI, Shuichi ,  MIYAZAWA, Kazutoshi ,  HACHIYA, Norihisa ,  NAKAGAWA, Etsuo

IPC分类号： C07C22/08 ,  C07C25/18 ,  C07C25/24 ,  C07C43/174 ,  C07C43/176 ,  C07C43/192 ,  C07C43/225 ,  C07C69/75 ,  C07C69/773 ,  C07C255/50 ,  C07C255/54

CPC分类号： C07C17/263 ,  C07C17/2632 ,  C07C17/266 ,  C07C17/354 ,  C07C22/08 ,  C07C25/18 ,  C07C25/24 ,  C07C43/225 ,  C07C45/41 ,  C07C45/513 ,  C07C47/238 ,  C07C47/24 ,  C07C69/753 ,  C07C69/76 ,  C07C69/88 ,  C07C69/90 ,  C07C255/50 ,  C07C255/54 ,  C07C255/55 ,  C07C2601/14 ,  C09K19/3003 ,  C09K19/3028 ,  C09K19/3048 ,  C09K19/3068 ,  C09K19/42 ,  C09K19/46

摘要： Novel liquid crystalline compounds and liquid crystal compositions comprising the compound are provided which liquid crystalline compounds have a high dielectric anisotropy, high voltage holding ratio at temperatures in which the compounds are employed, low threshold voltage, and improved solubility with other liquid crystal materials at low temperatures; and the liquid crystalline compounds are cyclohexane derivatives expressed by the following general formula (1)
wherein R 1 represents an alkyl group having 1 to 15 carbon atoms, at least one non-adjacent methylene group (-CH 2 -) in the alkyl group may be replaced by -O-, -S-, -CH=CH-, or -C≡C-; L 1 , L 2 , L 3 , and L 4 independently represent H or F; X represent a halogen atom, CF 3 , OCF 3 , OCHF 2 , CN, or NCS; and Z 1 and Z 2 independently represent -(CH 2 ) 2 -, -CH=CH-, -COO-, or a covalent bond.

公开(公告)号：EP0945418B1

公开(公告)日：2004-04-07

申请号：EP97913458.2

申请日：1997-11-27

申请人： CHISSO CORPORATION

发明人： KONDO, Tomoyuki ,  MATSUI, Shuichi ,  MIYAZAWA, Kazutoshi ,  TAKEUCHI, Hiroyuki ,  TAKESHITA, Fusayuki ,  NAKAGAWA, Etsuo

IPC分类号： C07C25/18 ,  C07C43/225 ,  C07C43/174 ,  C09K19/10 ,  G02F1/13 ,  C09K19/14 ,  C09K19/20

CPC分类号： C09K19/12 ,  C07C25/18 ,  C07C43/225 ,  C09K19/14 ,  C09K19/20 ,  C09K19/42 ,  C09K19/44 ,  C09K19/46 ,  C09K2019/0448 ,  C09K2019/0451 ,  Y10T428/10

公开(公告)号：EP0786509B1

公开(公告)日：2001-09-12

申请号：EP95934294.0

申请日：1995-10-13

申请人： CHISSO CORPORATION

发明人： MATSUI, Shuichi ,  MIYAZAWA, Kazutoshi ,  OHNISHI, Noriyuki ,  HASEBA, Yasuhiro ,  GOTO, Yasuyuki ,  NAKAGAWA, Etsuo ,  SAWADA, Shinichi

IPC分类号： C09K19/42 ,  C09K19/44 ,  C09K19/46 ,  G02F1/13 ,  C09K19/30

CPC分类号： C07C255/54 ,  C07C43/225 ,  C07C255/55 ,  C07C2601/14 ,  C09K19/20 ,  C09K19/3001 ,  C09K19/3066 ,  C09K19/42 ,  C09K19/44 ,  C09K19/46 ,  C09K2019/0466

摘要： A liquid crystal composition which not only satisfies various characteristics required of liquid crystal compositions for AM-LCD, but also particularly has an improved low-temperature compatibility, a suitably increased Δn value, and lowered Vth and viscosity. The composition contains at least one compound represented by general formula (I-1) or (I-2) as a first component and at least one compound represented by any of the general formulae (II-1) to (II-7) as a second component, (wherein n represents an integer of 1 to 10; Z1 represents -CH¿2?CH2- or a single bond; X represents F or OCH3; Y represents H or F; and m represents 0 or 1). The composition is useful as a low-voltage liquid crystal material of various modes including active matrix and STN systems.

摘要翻译： 提供液晶组合物，其在低温下具有特别优异的混溶性，适当大的DELTA n和小的V @ @和粘度，同时满足AM-LCD液晶组合物所需的若干特性。 公开了含有作为第一成分的至少一种由通式（I-1）或（I-2）表示的化合物，并且含有至少一种由下列化合物表示的化合物作为第二成分的液晶组合物： 通式（II-1）〜（II-7） 其中n为1〜10的整数，Z 1表示-CH 2 CH 2 - 或单键，X表示F或OCF 3，Y表示H 或F，m为0或1.本发明的液晶组合物可用作有源矩阵模式和STN模式等多种模式的低电压液晶材料。