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1.发明授权STABLE FREE NITROXYL RADICALS AS OXIDATION CATALYSTS AND PROCESS FOR OXIDATION 有权稳定硝酰自由基氧化催化剂和氧化法处理
公开(公告)号：EP1353750B1
公开(公告)日：2004-08-25
申请号：EP02715433.5
申请日：2002-01-15
IPC分类号： B01J31/02 , C07C45/29 , C07C45/30 , C07C51/16 , C07C51/29 , C08F2/38 , C07C7/20 , C08K5/3492 , C07D211/94
CPC分类号： B01J31/40 , B01J31/006 , B01J31/0237 , B01J31/0244 , B01J2231/70 , C07C45/29 , C07C45/294 , C07C45/30 , C07C45/38 , C07C45/39 , C07C51/29 , C07D471/18 , C07D487/18 , C08K5/34926 , Y02P20/584 , C07C49/04 , C07C47/19 , C07C59/305
摘要： The instant invention relates to stable free nitroxyl radicals of formula (I) at least one of the substituents R is -O. and the others are hydrogen or OH; X is -NR1R2, wherein R1 and R2 are independently hydrogen, C1-C18alkyl or together with the nitrogen atom to which they are bound from a 5 or 6 membered ring which may be further interrupted by an O atom. Further subjects of the invention are an oxidation process for alcohols to aldehydes or ketones or to carboxylic acids in the presence of a compound of formula (I) and the use of stable free nitroxyl radicals of formula (I) as oxidation catalysts.
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2.发明公开STABLE FREE NITROXYL RADICALS AS OXIDATION CATALYSTS AND PROCESS FOR OXIDATION 有权稳定硝酰自由基氧化催化剂和氧化法处理
公开(公告)号：EP1353750A1
公开(公告)日：2003-10-22
申请号：EP02715433.5
申请日：2002-01-15
IPC分类号： B01J31/02 , C07C45/29 , C07C45/30 , C07C51/16 , C07C51/29 , C08F2/38 , C07C7/20 , C08K5/3492 , C07D211/94
CPC分类号： B01J31/40 , B01J31/006 , B01J31/0237 , B01J31/0244 , B01J2231/70 , C07C45/29 , C07C45/294 , C07C45/30 , C07C45/38 , C07C45/39 , C07C51/29 , C07D471/18 , C07D487/18 , C08K5/34926 , Y02P20/584 , C07C49/04 , C07C47/19 , C07C59/305
摘要： The instant invention relates to stable free nitroxyl radicals of formula (I) at least one of the substituents R is -O. and the others are hydrogen or OH; X is -NR1R2, wherein R1 and R2 are independently hydrogen, C1-C18alkyl or together with the nitrogen atom to which they are bound from a 5 or 6 membered ring which may be further interrupted by an O atom. Further subjects of the invention are an oxidation process for alcohols to aldehydes or ketones or to carboxylic acids in the presence of a compound of formula (I) and the use of stable free nitroxyl radicals of formula (I) as oxidation catalysts.
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公开(公告)号：EP1781732A1
公开(公告)日：2007-05-09
申请号：EP05779283.0
申请日：2005-08-15
摘要： The invention describes a composition comprising a) an organic material which is susceptible to oxidative, thermal or light-induced degradation, and b) at least one melt additive of a compound of the formula (I) wherein the general symbols are as defined in claim 1. The compounds of the formula (I) are useful as reducers of surface energy for organic materials, for example, for increasing the oil and water repellency of organic materials.
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4.发明公开FILM COMPOSITIONS WITH PERMANENT ANTI-FOG, ANTI-MIST AND ANTI-CLOUD PROPERTIES 审中-公开对恒起雾，防雾和防云层特性薄膜组合物
公开(公告)号：EP1534776A1
公开(公告)日：2005-06-01
申请号：EP03793765.3
申请日：2003-08-28
摘要： The instant invention discloses a film composition with anti-fog, anti-mist and anti-cloud properties comprising (a) a polyolefin, a polyvinylalcohol, a polyvinylester or mixtures thereof, (b) an effective amount of at least one linear ethoxylated alcohol; and (c) an effective amount of at least one fluorine-containing surfactant. The films are useful as a greenhouse film for agricultural applications.
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5.发明公开FUNCTIONALIZED ESTERS, AMIDES OR URETHANES OF PERFLUORINATED ALCOHOLS OR AMINES AS SURFACE MODIFIERS 有权官能的酯，酰胺或氨基甲酸乙酯全氟化醇或胺作为表面物质
公开(公告)号：EP1846356A1
公开(公告)日：2007-10-24
申请号：EP06707887.3
申请日：2006-01-30
IPC分类号： C07C205/57 , C07C229/62 , C07C237/30 , C08K5/12 , C08K5/20 , C08K5/29 , C08K5/32
CPC分类号： C08K5/0008 , C07C205/57 , C07C229/62 , C07C233/54 , C07C233/81 , C07C237/30 , C07C237/40 , C07C275/42 , C08K5/12 , C08K5/20 , C08K5/29 , D01F1/10 , D06M10/08 , D06M13/236 , D06M13/402 , D06M13/428 , D06M2200/11 , D06M2200/12
摘要： The invention describes a composition comprising a) an organic material which is susceptible to oxidative, thermal or light-induced degra- dation, and b) at least one melt additive of a compound of the formula I R1 (I) R3 X R2 wherein the general symbols are as defined in claim 1. The compounds of the formula I are useful as reducers of surface energy for organic mate- rials, for example, for increasing the oil and water repellency of organic materials.
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6.发明公开FLUOROCARBON TERMINATED OLIGO- AND POLY-CARBONATES AS SURFACE MODIFIERS 有权FLUOR烃TERMINATED低聚糖和聚碳酸酯AS表面改性剂
公开(公告)号：EP1697440A1
公开(公告)日：2006-09-06
申请号：EP04817567.3
申请日：2004-12-08
发明人： BRUNNER, Martin , DESAI, Archana K., Plot 63, B-6, Premier Society , HINDALEKAR, Shrirang, Bhikaji, 9/55, B.D.D. Colony , SAHASRABUDHE, Suhas, D., 8, Om Abhiram Society , SCHNEIDER, Armin , THANKI, P., N., A-302, Shri Panchamrut HC Society , TINKL, Michael , ZEDDA, Alessandro , GERSTER, Michèle , BRAND, Fabien, Jean
摘要： The instant invention relates to new compounds of the formula (I), wherein Ro is (formula II), R1 and R2 are each independently of the other a fluorine containing group, R3 and R4 are each independently of the other hydrogen, a fluorine containing group, C1-C12alkyl, phenyl or (formula III), or R3 and R4, together with the carbon atom to which they are bonded, form a C5-C8-cycloalkylidene ring that is unsubstituted or substituted by from 1 to 3 C1-C4alkyl groups; R5, R6, R7 and R8 are each independently of the other hydrogen, C1-C12alkyl or C3-C12alkenyl, X1 and X2 are each independently of the other a direct bond or C1-C12alkylene, m is 1 to 10'000, and n is 0 to 10'000. These new compounds of the formula (I) are useful as reducers of surface energy for organic materials such as polycarbonates, polyesters or polyketones or their mixtures, blends or alloys. Polymers with such a reduced surface energy possess an 'easy to clean', 'self-cleaning' 'antisoiling', 'soil-release' 'antigraffiti', 'oil resistance', 'solvent resistance', 'chemical resistance', 'self lubricating', 'scratch resistance', 'low moisture absorption' and 'hydrophobic' surface.
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