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公开(公告)号：EP3792240A1
公开(公告)日：2021-03-17
申请号：EP19800180.2
申请日：2019-05-10
IPC分类号： C07C29/62 , C07C33/46 , C07C45/67 , C07C49/233 , C07C49/697 , C07C49/813 , C07C49/84 , C07C67/333 , C07C69/65 , C07C201/12 , C07C205/45 , C07C231/12 , C07C233/33 , C07D333/22
摘要： An object of the present disclosure is to provide a novel method for producing a fluoromethyl derivative. The object is achieved by a method for producing a fluorinated organic compound represented by formula (1):
wherein
R 1 represents an organic group,
R 2 represents hydrogen, halogen, or an organic group,
R 3 represents hydrogen, halogen, or an organic group,
L represents a single bond, alkanediyl, -CO-, -CONR-, -NRCO-, -O-CO-, or -CO-O- wherein R independently represents, in each occurrence, hydrogen or an organic group,
R 4 represents hydrogen, halogen, hydroxyl, or an organic group,
R 3 and R 4 may be linked to each other, and
R X represents hydrogen or fluoro,
provided that when R 4 represents hydrogen, L represents -CO-, -CONR-, -NRCO-, -O-CO-, or -CO-O-,
the method including step A of reacting an alkene compound represented by formula (2):
wherein the steric configuration of a single bond indicated by a wavy line with respect to a double bond to which the single bond is connected is in E configuration or Z configuration, or a mixture of E configuration and Z configuration in any ratio, and other alphabetical symbols are as defined above,
with a fluorine source that is a fluorine source (3a) represented by formula MF n wherein M represents H, a metal of Group 1 of the periodic table, or a metal of Group 2 of the periodic table; and n is 1 or 2
in the presence of a hypervalent-iodine aromatic compound (1a), or
in the presence of an aromatic iodine compound (1b) and an oxidant (A) to fluorinate the alkene compound.-
公开(公告)号：EP3967673A1
公开(公告)日：2022-03-16
申请号：EP20805493.2
申请日：2020-05-08
IPC分类号： C07B39/00 , C07C17/02 , C07C19/16 , C07C21/18 , C07C22/08 , C07C23/10 , C07C29/62 , C07C31/36 , C07C67/307 , C07C69/63 , C07C69/65
摘要： The present disclosure addresses the problem of providing a novel method for producing a fluorinated iodinated organic compound.
The problem can be solved by a method for producing a fluorinated iodinated organic compound, comprising reacting a compound represented by formula (1):
wherein R 1 and R 2 are each independently a hydrogen atom, a halogen atom, or an organic group, or R 1 and R 2 optionally form a ring together with the two adjacent carbon atoms; and n is 1 or 2, with a fluorine source, an iodine source, and an oxidizing agent or radical generator to add fluorine and iodine to the double bond or triple bond.-
公开(公告)号：EP3778548A1
公开(公告)日：2021-02-17
申请号：EP19777301.3
申请日：2019-03-29
IPC分类号： C07C67/307 , C07C69/757
摘要： An object of the present invention is to provide a method for producing a fluorinated organic compound, whereby an iodosylbenzene derivative can be easily separated and recovered.
The above object can be achieved by a method for producing a fluorinated organic compound, comprising step A of fluorinating an organic compound (1) by reaction with a fluorine source (3)
in the presence of a hypervalent iodine aromatic ring compound (2a), or
in the presence of an iodine aromatic ring compound (2b) and an oxidant (2bo);
wherein the fluorine source (3) is a fluorine source (3a) represented by formula: MF n , wherein M is H, a metal of Group 1 of the periodic table, or a metal of Group 2 of the periodic table; and n is 1 or 2; and
step B of separating the iodine aromatic ring compound from a reaction liquid after step A is started.-
公开(公告)号：EP4265589A1
公开(公告)日：2023-10-25
申请号：EP21906736.0
申请日：2021-12-17
IPC分类号： C07C17/02 , C07C19/10 , C07C22/08 , C07C67/307 , C07C69/63 , C07C69/635 , C07C69/76
摘要： The invention provides a novel method for producing a fluorinated organic compound. The method for producing a fluorinated organic compound comprises reacting a compound represented by formula (1):
(wherein R 1 and R 2 are each independently a hydrogen atom, a halogen atom, or an organic group, or R 1 and R 2 optionally form a ring together with the two adjacent carbon atoms; n is 1 or 2;
and wherein two R 1 s are optionally the same or different, two R 2 s are optionally the same or different, or two R 1 s or two R 2 s optionally form a ring together with their adjacent carbon atom), with (A) at least one fluorine source selected from the group consisting of hydrogen fluoride, hydrogen fluoride salts, and fluoride salts, and (B) a halogen source other than fluorine represented by the formula: R 3 (OX) m (wherein R 3 is a hydrogen atom, a cation, or an organic group, X is a halogen atom other than a fluorine atom, and m is an integer corresponding to the valence of R 3 ), to add fluorine and a halogen other than fluorine to the double bond or triple bond.-
公开(公告)号：EP3778547A1
公开(公告)日：2021-02-17
申请号：EP19774411.3
申请日：2019-03-29
IPC分类号： C07C67/307 , C07C69/757
摘要： An object of the present invention is to provide a method for producing a fluorinated organic compound, whereby an iodosylbenzene derivative can be easily separated and recovered.
The above object can be achieved by a method for producing a fluorinated organic compound, comprising step A of fluorinating an organic compound (1) by reaction with a fluorine source (3)
in the presence of an iodine-containing polymer (2ap) having one or more hypervalent iodine aromatic ring moieties,
in the presence of a combination of an oxidant (2bo) and an iodine-containing polymer (2bp) having one or more iodine aromatic ring moieties, or
in the presence of an iodine-containing polymer (2cp) having one or more IF 2 -substituted aromatic ring moieties;
wherein the fluorine source (3) is
a fluorine source (3a) represented by formula: MF n , wherein M is H, a metal of Group 1 of the periodic table, or a metal of Group 2 of the periodic table; and n is 1 or 2,
the polymer (2cp) having one or more IF 2 -substituted aromatic ring moieties, or
a combination thereof.-
公开(公告)号：EP4417664A1
公开(公告)日：2024-08-21
申请号：EP22892495.7
申请日：2022-10-14
发明人： AKUTA, Ryo , HIGASHI, Masahiro , KISHIKAWA, Yosuke , HSU, Yu-I , UYAMA, Hiroshi
IPC分类号： C09K3/18 , D06M15/507
CPC分类号： D06M23/10 , D06M15/507 , C09K3/18 , C08J3/14
摘要： Provided is a novel water repellent agent in which a biodegradable polyester is used. In the water repellent agent, porous particles having the biodegradable polyester as a main component are contained.
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公开(公告)号：EP4317214A3
公开(公告)日：2024-05-01
申请号：EP23216669.4
申请日：2019-03-01
发明人： NANBA, Yoshinori , ICHIKAWA, Kenji , FUJIMOTO, Yohei , YOSHIDA, Hirotoshi , SATO, Hiroyuki , KATO, Taketo , ITO, Kengo , ISHIHARA, Sumi , HIGASHI, Masahiro , YONEDA, Satoru , AOYAMA, Hirokazu , SUKEGAWA, Masamichi , KISHIKAWA, Yosuke , TAIRA, Takahiro , OKUI, Chiaki , YAMANAKA, Taku
IPC分类号： C08F2/44 , B29C55/00 , C08F2/24 , C08F14/18 , C08F261/06 , C08L27/12 , C08F259/08 , C08F2/26 , C08F214/26 , C08L27/18 , C08F116/14
CPC分类号： C08L27/12 , C08F259/08 , B29C55/16 , B29C55/18 , B29C55/06 , C08L27/18 , C08F261/06 , C08F2/26 , C08F116/14 , C08F114/26 , C08F14/26 , C08F214/26
摘要： An object of the present disclosure is to provide a novel method for producing a fluoropolymer. The present disclosure relates to a method for producing a fluoropolymer, comprising polymerizing a fluoromonomer in an aqueous medium in the presence of a polymer (1) to provide a fluoropolymer, the polymer (1) comprising a polymerized unit (1) derived from a monomer represented by the following general formula (1): CX2=CY(-CZ2-O-Rf-A) (1)
wherein X is the same or different and is -H or -F; Y is -H, -F, an alkyl group, or a fluorine-containing alkyl group; Z is the same or different and is -H, -F, an alkyl group, or a fluoroalkyl group; Rf is a fluorine-containing alkylene group having 1 to 40 carbon atoms or a fluorine-containing alkylene group having 2 to 100 carbon atoms and having an ether bond; and A is -COOM, - SO3M, or -OSO3M, wherein M is -H, a metal atom, -NR74, imidazolium optionally having a substituent, pyridinium optionally having a substituent, or phosphonium optionally having a substituent, wherein R7 is H or an organic group, with the proviso that at least one of X, Y, and Z contains a fluorine atom.-
8.发明公开
公开(公告)号：EP4317308A1
公开(公告)日：2024-02-07
申请号：EP22781302.9
申请日：2022-03-31
发明人： MUKAE, Hirofumi , KISHIKAWA, Yosuke , YAMANAKA, Taku , KATO, Taketo , ITOH, Ryuo , KUBOTA, Hiroki
IPC分类号： C08L27/12 , C08F214/26 , C08J3/12 , C08J3/20 , C08L27/18
摘要： Provided is a method for producing a fluororesin composition suffering less coloring and having excellent tensile properties while containing a fluororesin having a history of being heated to the melting point thereof or higher, the fluororesin composition, and a molded article obtainable from the fluororesin composition. The disclosure provides a method for producing a fluororesin composition, the method including: mixing a powder of a fluororesin A1 having a history of being heated to a melting point thereof or higher and an aqueous dispersion containing particles of a fluororesin B1 and having a solid concentration of 70% by mass or lower to provide a mixture; and drying the mixture to provide a fluororesin composition.
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公开(公告)号：EP4317307A1
公开(公告)日：2024-02-07
申请号：EP22781277.3
申请日：2022-03-31
发明人： MUKAE, Hirofumi , KISHIKAWA, Yosuke , YAMANAKA, Taku , KATO, Taketo , SAKAKURA, Atsushi , ITOH, Ryuo , KUBOTA, Hiroki , NAKAUE, Ayane
IPC分类号： C08L27/12 , C08F214/26 , C08J3/12 , C08J3/20
摘要： Provided is a fluororesin composition having excellent tensile properties while containing a fluororesin having a history of being heated to the melting point thereof or higher, and a molded article obtainable from the fluororesin composition. The disclosure provides a non-melt-flowable fluororesin composition containing: a non-melt-flowable fluororesin A having a history of being heated to a melting point thereof or higher; and a melt-flowable fluororesin B.
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公开(公告)号：EP4317219A1
公开(公告)日：2024-02-07
申请号：EP22781282.3
申请日：2022-03-31
发明人： MUKAE, Hirofumi , KISHIKAWA, Yosuke , YAMANAKA, Taku , KATO, Taketo , ITOH, Ryuo , KUBOTA, Hiroki
IPC分类号： C08F214/26 , C08L27/12 , C08L27/18
摘要： Provided is a fluororesin composition having excellent handleability while containing a fluororesin having a history of being heated to the melting point thereof or higher, and a molded article obtainable from the fluororesin composition. The disclosure provides a fluororesin composition containing: a non-melt-flowable fluororesin A having a history of being heated to a melting point thereof or higher; and a non-melt-flowable fluororesin B having no history of being heated to a melting point thereof or higher and being prepared by suspension polymerization. The fluororesin composition has an apparent density of 0.42 g/ml or higher.
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