摘要:
New alkyl substituted siloxanes and alkyl substituted polyether fluids are prepared by reacting an unsaturated alkyl, a aralkyl or ether with alkylhydrido siloxanes such as (i) comonomers of the formula RSi(OSiMe 2 H) 3 , (ii) oligomers of the formula (HMe 2 SiO) 2 -Si(R)-O-Si(R)-(OSiMe 2 H) 2 , and (iii) higher molecular weight siloxane species of the formula RSi[(OSiMe 2 ) x OSiMe 2 H] 3 and [HMe 2 SiO(Me 2 SiO) x ] 2 Si(R)O(R)Si[(OSiMe 2 ) x OSiMe 2 H] 2 . R is a C 2 to C 18 straight-chain or branched-chain alkyl substituent; and x has a value of 1-200.
摘要:
This invention pertains to alkylsiloxanes that comprise greater than 99.9% alkylsiloxanes and contain less than 10 ppm -SiH, less than 10 ppm CH 2 =CH- and less than 1 ppm platinum. The pristine alkylsiloxanes of our invention are produced by reacting an -SiH containing polysiloxane with an olefinic compound, under anhydrous conditions, in the presence of a supported platinum catalyst and oxygen.
摘要:
A method is described of producing a mixture of silicone polyethers from a mixture of at least two alkenyl ether terminated organic oxyalkylene compounds having different molecular weights and an organosilicon compound having at least two hydride substituents. In an alternate embodiment, an organocyclosilazane is used and either alkyl or alkenyl ether terminated organic oxyalkylene compounds can be employed. The mixtures have utility in the conditioning of skin.
摘要:
A method of treating human skin to decrease transepidermal water loss. A method of enhancing the substantivity of conditioning compounds applied to the skin. A film forming conditioning formulation which includes as an ingredient thereof an organosilicon compound is applied to the skin. The improvement resides in the utilization of a formulation which includes as the organosilicon compound a cyclic alkylmethyl polysiloxane.
摘要:
A nail lacquer which includes a film forming resin, a plasticizer and a solvent. The improvement relates to the utilization as the film forming resin of the nail lacquer a graft copolymer which has a main backbone chain of acrylic ester monomer units and methacrylic ester monomer units. The main backbone chain has grafted thereto side chain units of carboxyl groups and side chain units of trialkoxysilyl groups. Nail coat compositions containing these film forming resins provide improved wear resistance.
摘要:
An emulsion and a mixture including water, at least one surfactant and a polymethylalkylsiloxane. The polymethylalkylsiloxane has the formula: wherein R is a methyl radical, a is an integer from one to about three thousand and b is an integer from one to about ten. Also disclosed is a method of rendering a surface repellent to water by treating the surface with an effective amount of the foregoing emulsion. The surface being treated is an organic surface and can be a rubber surface such as wires, cables, the sidewall of a pneumatic tire, footwear, molded goods and coated fabrics. The surface can also be a vinyl surface such as flooring, shower curtains, rain coats, automotive seat upholstery, residential siding and piping.
摘要:
A process for the preparation of substantially polycrystalline silicon carbide fibers, and the product produced thereby, are provided. The fibers may be fabricated to have a small diameter and are thermally stable at high temperatures. The process is carried out by initially forming fibers from a preceramic polymeric precursor comprising phenyl-containing polyorganosiloxane resins. The fibers are then infusibilized to render them nonmelting followed by a pyrolysis step in which the fibers are heated to a temperature in excess of 1600°C. in a nonoxidizing atmosphere to form substantially polycrystalline silicon carbide fibers. The substantially polycrystalline silicon carbide fibers which are formed by the process of the present invention have at least 75% crystallinity and have a density of at least about 2.9 gm/cm³. The polymeric precursor or the fibers contain, or have incorporated therein, at least about 0.2% by weight boron. This incorporation of boron may be accomplished either prior to or during formation of the fibers or during at least one of the infusibilizing or pyrolyzing steps of the process.
摘要翻译:提供了制备基本上多晶碳化硅纤维的方法以及由此制备的产品。 纤维可以制造成具有小直径并且在高温下是热稳定的。 该方法通过最初由包含含苯基的聚有机硅氧烷树脂的陶瓷前体聚合物前体形成纤维来进行。 然后将纤维熔融以使其不熔化,随后进行热解步骤,其中将纤维在非氧化气氛中加热至超过1600℃的温度以形成基本上多晶的碳化硅纤维。 通过本发明的方法形成的基本上多晶的碳化硅纤维具有至少75%的结晶度并且具有至少约2.9gm / cm 3的密度。 聚合物前体或纤维含有或并入其中至少约0.2重量%的硼。 这种硼的掺入可以在纤维形成之前或期间或在该方法的至少一个不熔化或热解步骤期间完成。