摘要:
Disclosed is a membrane-electrode structure for a solid polymer fuel cell comprising a pair of electrode catalyst layers and a polyeletrolyte membrane sandwiched between the electrode catalyst layers, wherein the electrode catalyst layers contain polyarylene having a sulfonic acid group, said polyarylene comprising a recurring unit represented by the following formula (A) and a recurring unit represented by the following formula (B);
摘要:
A process of producing an electrode paste having excellent storage stability and capable of forming a catalyst layer that has a sufficient pore volume for high generating performance, and an electrode paste composition having such properties are disclosed. The process comprises mixing and agitating carbon black supporting a catalyst metal, a polymer electrolyte, an organic solvent and at least either carbon fiber or water thereby to finely disperse the carbon black to a predetermined mean particle diameter of particles dispersed in the mixed solution, and admixing a dispersant to the mixed solution and agitating the resultant mixture to obtain an electrode paste in which particles having a predetermined mean particle diameter are uniformly dispersed.
摘要:
Disclosed is a membrane-electrode structure for a solid polymer fuel cell comprising a pair of electrode catalyst layers and a polyeletrolyte membrane sandwiched between the electrode catalyst layers, wherein the electrode catalyst layers contain polyarylene having a sulfonic acid group, said polyarylene comprising a recurring unit represented by the following formula (A) and a recurring unit represented by the following formula (B);
摘要:
A process of producing an electrode paste having excellent storage stability and capable of forming a catalyst layer that has a sufficient pore volume for high generating performance, and an electrode paste composition having such properties are disclosed. The process comprises mixing and agitating carbon black supporting a catalyst metal, a polymer electrolyte, an organic solvent and at least either carbon fiber or water thereby to finely disperse the carbon black to a predetermined mean particle diameter of particles dispersed in the mixed solution, and admixing a dispersant to the mixed solution and agitating the resultant mixture to obtain an electrode paste in which particles having a predetermined mean particle diameter are uniformly dispersed.
摘要:
A membrane electrode assembly for a polymer electrolyte fuel cell has superior power generation characteristics under low humidity conditions and superior starting characteristics under low temperature conditions. In the membrane electrode assembly for a polymer electrolyte fuel cell in which a polymer electrolyte membrane is disposed between a pair of electrodes containing a catalyst, the polymer electrolyte membrane has a polymer segment A having an ion conductive component and a polymer segment B not having an ion conductive component. Furthermore, in the case in which the polymer electrolyte membrane is immersed in'water at 90°C for 30 minutes, absorbed water which exhibits a thawing temperature of from -30 to 0°C is in a range from 0.01 to 3.0 g per 1 g of the polymer.
摘要:
In a polymer electrolyte fuel cell in which a cathode diffusion layer (5), a cathode electrode catalyst layer (3), a polymer electrolyte membrane (1), an anode electrode catalyst layer (2), and an anode diffusion layer (4) are laminated in this order, electron conductivity of the cathode electrode catalyst layer at a portion on the side of the cathode diffusion layer is higher than at a portion on the side of the polymer electrolyte membrane and electron conductivity of the cathode electrode catalyst layer at the portion on the side of the polymer electrolyte membrane is lower than at the portion on the side of the cathode diffusion layer, and furthermore, electron conductivity of the anode electrode catalyst layer at a portion on the side of the anode diffusion layer is higher than at a portion on the side of the polymer electrolyte membrane and electron conductivity of the anode electrode catalyst layer at the portion on the side of the polymer electrolyte membrane is lower than at the portion on the side of the anode diffusion layer.
摘要:
A fuel cell (22) having an oxygen-containing gas flow field (34) and a fuel gas flow field (36), an oxygen-containing gas supply apparatus (14) for supplying an oxygen-containing gas to the oxygen-containing gas flow field (34), a fuel gas supply apparatus (16) for supplying a fuel gas to the fuel gas flow field (36), a scavenging gas supply apparatus (18) for supplying air as a scavenging gas to the fuel gas flow field (36), and a controller (20) are provided. The controller (20) includes a voltage detection unit (72) for detecting the voltage of the fuel cell (22) after operation of the fuel cell (22) is stopped and a scavenging control unit (74) for starting scavenging in the fuel gas flow field (36) by the scavenging gas supply apparatus (18) after the detected voltage is decreased temporarily, increased, and decreased again to become a preset voltage or less.
摘要:
A solid polymer electrolyte membrane fuel cell electrode catalyst layer comprises Ptparticles carriedon a carbon carrier and a solid polymer electrolyte, wherein a center-to-center distance dimension (Lpt-pt) between the Pt particles carried on the carbon carrier is made to substantially coincide with the sum of a double of a total dimension resulting by adding the length (Lpes) of a side chain having an ion-exchange group to the diameter (Dpem) of a main chain of the solid polymer electrolyte and the diameter (Dpt) of the Pt particle.