公开(公告)号：EP2478580A1

公开(公告)日：2012-07-25

申请号：EP10816510.1

申请日：2010-09-15

申请人： Hydro-Quebec

发明人： GUERFI, Abdelbast ,  LABRECQUE, Jean-François ,  DONTIGNY, Martin ,  CHAREST, Patrick ,  ZAGHIB, Karim

IPC分类号： H01M4/485 ,  H01M4/131 ,  H01M4/505 ,  H01M4/525 ,  H01M4/58 ,  H01M4/54 ,  H01M10/052 ,  H01M4/04 ,  H01M4/66

CPC分类号： H01M10/052 ,  H01M4/366 ,  H01M4/5825 ,  H01M4/625 ,  Y02E60/122 ,  Y02P70/54

摘要： The invention relates to a positive electrode material, consisting of particles having a complex oxide OC1 core, an at least partial complex oxide OC2 coating, and an adhesive carbon surface deposit. The material is characterized in that the complex oxide OC1 is an oxide having a high energy density and in that the oxide OC2 is an oxide of a metal having a catalytic effect on the reaction of the carbon deposit, the oxide having good electronic conductivity. The presence of the OC2 layer facilitates the deposit of a carbon adhesive layer at the surface of the oxide particles, and improves the conductivity of the material when the latter is used as an electrode material. The electrode material can particularly be used in the manufacture of a lithium battery.

公开(公告)号：EP1933966A1

公开(公告)日：2008-06-25

申请号：EP06775050.5

申请日：2006-07-28

申请人： HYDRO-QUEBEC

发明人： ZAGHIB, Karim ,  JALBERT, Jocelyn ,  GUERFI, Abdelbast ,  MICHOT, Christophe ,  GAUTHIER, Michel ,  DONTIGNY, Martin ,  CHAREST, Patrick

IPC分类号： B01D15/00 ,  C01D15/00 ,  H01M10/26 ,  H01M4/36 ,  H01M4/40 ,  B01J20/04 ,  C99Z99/00

CPC分类号： H01M10/4242 ,  B01D15/00 ,  H01M10/0565 ,  H01M10/0566 ,  H01M2300/0085

摘要： The invention relates to a method of purifying an ionic electrolyte containing at least one alkaline earth salt, said method comprising at least one contact step involving particles of at least one calcium salt. The inventive method can be used to obtain novel electrolytes which are especially characterised by the particularly-low water content thereof. The corresponding electrochemical generators that contain the electrolyte as a component are characterised by excellent stability and are very secure.

公开(公告)号：EP1520309A2

公开(公告)日：2005-04-06

申请号：EP03763538.0

申请日：2003-07-10

申请人： HYDRO QUEBEC

发明人： ZAGHIB, Karim ,  CHAREST, Patrick ,  GUERFI, Abdelbast ,  PERRIER, Michel ,  KINOSHITA, Kimio

IPC分类号： H01M4/48 ,  H01M4/58 ,  H01M4/62 ,  H01M4/04

CPC分类号： H01G11/46 ,  B02C17/1815 ,  H01G11/06 ,  H01G11/30 ,  H01G11/32 ,  H01M4/131 ,  H01M4/136 ,  H01M4/366 ,  H01M4/485 ,  H01M4/505 ,  H01M4/525 ,  H01M4/5825 ,  H01M4/625 ,  H01M4/661 ,  H01M10/052 ,  H01M10/0525 ,  H01M10/0565 ,  Y02E60/13

摘要： The invention relates to a mixture of particles comprising a non-conducting or semi-conducting core which is covered with a conducting hybrid coating and hybrid conducting chains which are located between the particles of the mixture and which form a conductivity network, said mixture being prepared by means of mechanical crushing. The incorporation of said particle mixtures in the anodes and cathodes of electrochemical generators is advantageous owing to the very high conductivity of the network, the low resistivity, the excellent high current capacity and/or the good energy density thereof. In this way, the inventive particle mixture can be used to produce highly-performing electrochemical systems.

摘要翻译： 颗粒混合物（I）包含具有不导电或半导电芯和混合导体的包覆颗粒，所述颗粒被具有混合导体链相互连接以形成导电性的网络。 因此独立权利要求中包括了以下内容：（1）生产的（I）通过制备非传导的混合物，或者用导电材料的半导体材料和添加的第二导电材料，制备非传导的混合物或用半导体材料至少 两种导电材料，或制备导电材料的混合物，并用不导电或半导电材料混合它; （2）电池的阴极和阳极，其包含（I）; （3）锂电池，其包含金属锂阳极和阴极，其包含（I）; （4）混合超级电容器在阳极包括向电解质，其包含（I），以及高表面积的碳或石墨阴极。

公开(公告)号：EP1802707B1

公开(公告)日：2016-09-07

申请号：EP05794996.8

申请日：2005-10-11

申请人： HYDRO-QUEBEC

发明人： ZAGHIG, Karim ,  CHAREST, Patrick ,  GUERFI, Abdelbast ,  DONTIGNY, Martin ,  PETICLERC, Michel

IPC分类号： C08L101/12 ,  C08J5/22 ,  C08J5/20 ,  H01M2/16 ,  C08J3/09

CPC分类号： C08J5/2268 ,  C08J3/095 ,  C08J2327/16 ,  C08J2333/12 ,  G02F1/1525 ,  H01B1/122 ,  H01M10/052 ,  H01M10/0565 ,  H01M2300/0022 ,  H01M2300/0091 ,  Y02P20/542 ,  Y10T29/4911

公开(公告)号：EP1573834B1

公开(公告)日：2009-04-15

申请号：EP03775013.0

申请日：2003-11-13

申请人： HYDRO-QUEBEC

发明人： ZAGHIB, Karim ,  ARMAND, Michel ,  GUERFI, Abdelbast ,  PERRIER, Michel ,  DUPUIS, Elisabeth ,  CHAREST, Patrick

IPC分类号： H01M4/04

CPC分类号： H01M4/0404 ,  H01G11/06 ,  H01G11/24 ,  H01G11/28 ,  H01G11/30 ,  H01G11/32 ,  H01G11/42 ,  H01G11/46 ,  H01G11/86 ,  H01M2/145 ,  H01M2/1653 ,  H01M4/04 ,  H01M4/0409 ,  H01M4/0471 ,  H01M4/133 ,  H01M4/136 ,  H01M4/139 ,  H01M4/1391 ,  H01M4/1393 ,  H01M4/1397 ,  H01M4/366 ,  H01M4/5825 ,  H01M4/587 ,  H01M4/621 ,  H01M4/622 ,  H01M4/623 ,  H01M4/625 ,  H01M4/66 ,  H01M4/661 ,  H01M10/0525 ,  H01M10/0565 ,  H01M10/0568 ,  H01M10/0569 ,  H01M2004/027 ,  H01M2004/028 ,  H01M2300/0028 ,  H01M2300/0037 ,  H01M2300/004 ,  H01M2300/0042 ,  H01M2300/0082 ,  Y02E60/122 ,  Y02E60/13 ,  Y02P70/54

摘要： The invention relates to a method of preparing an electrochemical electrode which is partially or totally covered with a film that is obtained by spreading an aqueous solution comprising a water-soluble binder over the electrode and subsequently drying same. The production cost of the electrodes thus obtained is reduced and the surface porosity thereof is associated with desirable resistance values.

公开(公告)号：EP1649530A2

公开(公告)日：2006-04-26

申请号：EP04737895.5

申请日：2004-06-25

申请人： HYDRO-QUEBEC

发明人： ZAGHIB, Karim ,  GUERFI, Abdelbast ,  CHAREST, Patrick ,  KOSTECKI, Robert ,  KINOSHITA, Kimio ,  ARMAND, Michel

IPC分类号： H01M4/02 ,  H01M4/04

CPC分类号： H01M4/0438 ,  C01B33/02 ,  H01M4/044 ,  H01M4/0461 ,  H01M4/0495 ,  H01M4/134 ,  H01M4/1395 ,  H01M4/366 ,  H01M4/38 ,  H01M4/386 ,  H01M4/387 ,  H01M4/405 ,  H01M4/505 ,  H01M4/525 ,  H01M4/624 ,  H01M4/625 ,  H01M10/052 ,  Y10T29/49108

摘要： The invention concerns a method for preparing electrodes from a porous material to obtain electrodes useful in electrochemical systems and which exhibit at least one of the following properties: high mAh/gram capacity, high mAh/litre capacity, good cyclability, low self-discharge rate, and good environmental tolerance.

摘要翻译： 一种用于电极的制备方法包括使用多孔材料。 独立权利要求中包括了; （A）一种电化学系统; （b）阳极电池; 和（C）一种锂离子电池。

公开(公告)号：EP1466379B1

公开(公告)日：2020-01-08

申请号：EP03700260.7

申请日：2003-01-15

申请人： HYDRO-QUEBEC

发明人： ZAGHIB, Karim ,  PERRIER, Michel ,  GUERFI, Abdelbast ,  DUPUIS, lisabeth ,  CHAREST, Patrick ,  ALLAIRE, François ,  ARMAND, Michel

IPC分类号： H01G9/022 ,  H01G11/56 ,  H01M10/0525 ,  C08F283/00 ,  C09D133/12 ,  C08G65/26 ,  C08G65/333 ,  C08L33/12 ,  C08L71/02 ,  H01M10/0565 ,  C08F290/06 ,  H01M4/587 ,  H01M4/525 ,  H01M4/505

公开(公告)号：EP1933966B1

公开(公告)日：2012-05-30

申请号：EP06775050.5

申请日：2006-07-28

申请人： HYDRO-QUEBEC

发明人： ZAGHIB, Karim ,  JALBERT, Jocelyn ,  GUERFI, Abdelbast ,  MICHOT, Christophe ,  GAUTHIER, Michel ,  DONTIGNY, Martin ,  CHAREST, Patrick

IPC分类号： B01D15/00 ,  C01D15/00 ,  H01M10/26 ,  H01M4/36 ,  H01M4/40 ,  B01J20/04 ,  C99Z99/00

CPC分类号： H01M10/4242 ,  B01D15/00 ,  H01M10/0565 ,  H01M10/0566 ,  H01M2300/0085

摘要： The invention relates to a method of purifying an ionic electrolyte containing at least one alkaline earth salt, said method comprising at least one contact step involving particles of at least one calcium salt. The inventive method can be used to obtain novel electrolytes which are especially characterised by the particularly-low water content thereof. The corresponding electrochemical generators that contain the electrolyte as a component are characterised by excellent stability and are very secure.

公开(公告)号：EP2016635A1

公开(公告)日：2009-01-21

申请号：EP07719346.4

申请日：2007-01-25

申请人： HYDRO-QUEBEC

发明人： ZAGHIB, Karim ,  PETITCLERC, Michel ,  CHAREST, Patrick ,  GUERFI, Abdelfast ,  DONTIGNY, Martin

IPC分类号： H01M4/36 ,  B05D5/12 ,  C09D5/00 ,  G11B5/706 ,  G11B5/708 ,  H01B1/00 ,  H01B1/14 ,  H01B1/18 ,  H01M4/48 ,  H01M4/58

CPC分类号： G11B5/714 ,  C09D5/00 ,  H01B1/24 ,  H01M4/36 ,  H01M4/485 ,  H01M4/505 ,  H01M4/525 ,  H01M4/587 ,  Y10T428/2982

摘要： The invention concerns a mixture of particles consisting of a carrier based on at least one active material M1of average size T1 and of specific surface S1 on which are bonded, via physical and/or chemical bonds, particles of at least an electronically conductive material M2 of average size T2 and of specific surface S2. The mixture is characterized in that: the average size ratio T1/T2 ranges between 5 and 10000; The specific surface ratio S1/S2 ranges between 1/300 and 1/2; and the amount of active material present in the mixture preferably represents more than 80% of the amount of the conductive material. The incorporation of said mixtures into elements constituting electrochemical systems substantially improves the performances of the latter.

公开(公告)号：EP1602143A2

公开(公告)日：2005-12-07

申请号：EP04706112.2

申请日：2004-01-29

申请人： HYDRO-QUEBEC

发明人： ZAGHIB, Karim ,  PERRIER, Michel ,  GUERFI, Abdelbast ,  DUPUIS, Elizabeth ,  CHAREST, Patrick

IPC分类号： H01M10/40

CPC分类号： H01M10/0566 ,  H01M2/1653 ,  H01M4/134 ,  H01M6/168 ,  H01M10/0436 ,  H01M10/052 ,  H01M10/0567 ,  H01M10/4235 ,  H01M2300/0037 ,  H01M2300/0042 ,  H01M2300/0085 ,  Y02E60/122 ,  Y02P70/54

摘要： The invention relates to a metallic lithium rechargeable electrochemical accumulator, comprising at least one lithium metal electrode and at least one polymeric electrolyte gel. Said accumulator is capable of operating at temperatures from - 20 to 60 °C, essentially without formation of lithium dendrites on the whole surface of the metallic lithium electrode. The above is also characterised by a particularly long life, even with intensive use at low temperature. Said inventive rechargeable accumulator can be produced by use of a production method with particular application of temperature control during the specific production stages. As a result of the extremely high electrochemical performance of said accumulator, in particular the remarkable stability thereof, said accumulator can be used in new application fields such as hybrid vehicles, electric vehicles and emergency supply systems such as those of the UPS type.

摘要翻译： 本发明涉及一种金属锂可再充电电化学蓄电池，其包括至少一种锂金属电极和至少一种聚合物电解质凝胶。 所述蓄电池能够在-20至60℃的温度下操作，基本上在金属锂电极的整个表面上不形成锂枝晶。 以上也是其中特别长的使用寿命，即使在低温下密集使用也是如此。 所述本发明的可充电蓄电池可以通过使用在特定生产阶段中特别应用温度控制的生产方法来生产。 由于所述蓄电池的电化学性能极高，特别是其显着的稳定性，所述蓄电池可用于诸如混合动力车辆，电动车辆和诸如UPS型的紧急供电系统的新的应用领域。