公开(公告)号：EP0889863A2

公开(公告)日：1999-01-13

申请号：EP97951051.0

申请日：1997-12-30

申请人： HYDRO-QUEBEC ,  CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (CNRS)

发明人： MICHOT, Christophe ,  ARMAND, Michel ,  GAUTHIER, Michel ,  CHOQUETTE, Yves

IPC分类号： C07D233 ,  B01J31 ,  C01B31 ,  C04B41 ,  C07B37 ,  C07B41 ,  C07B61 ,  C07C45 ,  C07C67 ,  C07C255 ,  C07C257 ,  C07C309 ,  C07C311 ,  C07C317 ,  C07D207 ,  C07D213 ,  C07D219 ,  C07D231 ,  C07D239 ,  C07D241 ,  C07D249 ,  C07D251 ,  C07D253 ,  C07D277 ,  C07D279 ,  C07D285 ,  C07D303 ,  C07D307 ,  C07D311 ,  C07D319 ,  C07D333 ,  C07D405 ,  C07D407 ,  C07D409 ,  C07D417 ,  C07D487 ,  C07F1 ,  C07F7 ,  C07F9 ,  C07F11 ,  C07F15 ,  C07F17 ,  C08F2 ,  C08F4 ,  C08F12 ,  C08F16 ,  C08F216 ,  C08F222 ,  C08F228 ,  C08G59 ,  C08G65 ,  C08G73 ,  C08G75 ,  C08G77 ,  C08G85 ,  C08J3 ,  C08J7 ,  C08L101 ,  C09B47 ,  C09B57 ,  C09B69 ,  C09C1 ,  C09C3 ,  C09D11 ,  G02F1 ,  H01B1 ,  H01B3 ,  H01G9 ,  H01M4 ,  H01M6 ,  H01M10

CPC分类号： B01J31/0224 ,  B01J31/0215 ,  B01J31/0222 ,  B01J31/0225 ,  B01J31/0227 ,  B01J31/0235 ,  B01J31/0239 ,  B01J31/0247 ,  B01J31/0251 ,  B01J31/0252 ,  B01J31/0267 ,  B01J31/0271 ,  B01J31/0281 ,  B01J31/0288 ,  B01J31/0289 ,  B01J31/04 ,  B01J31/06 ,  B01J31/068 ,  B01J31/124 ,  B01J31/1815 ,  B01J31/2208 ,  B01J2231/122 ,  B01J2231/14 ,  B01J2231/326 ,  B01J2231/341 ,  B01J2231/348 ,  B01J2231/4205 ,  B01J2231/543 ,  B01J2531/35 ,  B01J2531/824 ,  C07B37/02 ,  C07B37/12 ,  C07C45/46 ,  C07C45/69 ,  C07C67/00 ,  C07C255/10 ,  C07C255/17 ,  C07C255/27 ,  C07C255/46 ,  C07C255/65 ,  C07C257/14 ,  C07C311/03 ,  C07C311/04 ,  C07C311/09 ,  C07C311/48 ,  C07C317/04 ,  C07C317/08 ,  C07C317/14 ,  C07C317/22 ,  C07C317/24 ,  C07C317/34 ,  C07C317/44 ,  C07C2601/10 ,  C07C2602/42 ,  C07D207/452 ,  C07D213/76 ,  C07D219/10 ,  C07D231/18 ,  C07D233/90 ,  C07D239/60 ,  C07D241/42 ,  C07D249/04 ,  C07D249/10 ,  C07D249/12 ,  C07D251/70 ,  C07D277/64 ,  C07D277/82 ,  C07D285/125 ,  C07D285/135 ,  C07D285/15 ,  C07D285/16 ,  C07D303/34 ,  C07D307/54 ,  C07D307/64 ,  C07D311/52 ,  C07D311/58 ,  C07D311/82 ,  C07D319/06 ,  C07D333/16 ,  C07D333/24 ,  C07D405/06 ,  C07D409/12 ,  C07D417/10 ,  C07D417/14 ,  C07F17/02 ,  C08F4/04 ,  C08G65/3344 ,  C09B69/00 ,  C09B69/02 ,  C09B69/10 ,  G02F1/1525 ,  G02F2001/151 ,  H01B1/122 ,  H01B1/128 ,  H01G9/022 ,  H01G9/038 ,  H01G11/02 ,  H01G11/62 ,  H01M4/00 ,  H01M4/02 ,  H01M4/131 ,  H01M4/133 ,  H01M4/134 ,  H01M4/382 ,  H01M4/405 ,  H01M4/48 ,  H01M4/485 ,  H01M4/505 ,  H01M4/525 ,  H01M4/5815 ,  H01M4/5825 ,  H01M4/60 ,  H01M4/625 ,  H01M4/661 ,  H01M6/00 ,  H01M6/04 ,  H01M6/164 ,  H01M6/166 ,  H01M6/168 ,  H01M6/181 ,  H01M6/183 ,  H01M10/052 ,  H01M10/0525 ,  H01M10/0565 ,  H01M10/0567 ,  H01M10/0568 ,  Y02E60/13 ,  Y10S430/127 ,  Y10T29/49108 ,  Y10T428/2918 ,  C07C49/84 ,  C07C49/553

摘要： Disclosed is a method for grafting a polymer onto the surface of a carbonate material with carboxyl, amine, and/or hydroxyl functions on its surface. Said material is placed in suspension in a solution including the polymer to be grafted, which has a carboxyl, amine, and/or hydroxyl function, said solution also being comprised of a polymer solvent. A process which stimulates the dehydration into a carboxyl function of an amine and/or hydroxyl function is then performed, and the polymer is grafted onto the carbonate material using ester or amide links. The invention can be used in the cathode or naode of an electrochemical generator, in polymer materials with low polar properties, in ink, and also as a conductive coating on flexible plastic used as an electrical contact, as electromagnetic shielding, or as static protection.

摘要翻译： 电池具有包含溶剂的电解质和包含氢氧化物，亚硝鎓，铵，金属，有机或有机金属阳离子和5元（杂）环阴离子的盐（I）。 电池具有包含溶剂的电解质和包含氢氧化物，亚硝鎓，铵，金属，有机或有机金属阳离子的盐（I）和具有下式的5元（杂）环阴离子：[图像] X1-X5-N =（ - ） - ， - （ - ） - （ - ） - （ - ） - （ - ） - =，条件是不超过四个包括N，不超过两个包括S（不相邻），不超过一个包含P; Q'，Q：1-8C全卤代烷基，全卤代烯基或任选取代的6-12C芳基或芳烷基，各自任选含有O，S或N杂原子; 任选被卤素和/或醚取代的烷基，烯基，芳基，芳烷基，烷基芳基，烯基芳基，脂环族或杂环基，硫醚，胺，亚胺，酰胺，羧基，羰基，异氰酸酯，异硫氰酸酯和羟基; 具有含有杂原子的环和/或取代基的芳族基团; 聚合物组; 或具有一个或多个阳离子和/或阴离子离子基团的基团; Y：H，F，Cl，Br，CN，SCN，NCS，NCO，NO2，全氟烷基，全氟烷氧基，全氟烷基甲基，四氟乙氧基，SCF3，全氟烷硫基，四氟乙硫基，三氟乙氧基，三氟乙硫基，SO2F，SO2Q，COOQ，QN-SO2- ）或COQ; CN，CO 2，SCN，N 3，三氟乙烯基氧基，（1-12C全氟烷基）甲基，氟代烷氧基，氟烷基硫代，烷基，烯基， 氧杂烷基，氧杂链烯基，氮杂烷基，氮杂链烯基，硫杂烷基，硫杂链烯基，聚合基团和具有一个或多个阳离子和/或阴离子离子基团的基团; 或者，Y，Q，Q'和Q中的两个可以形成4-至8-元环，或者Y和Q中的一个是连接到第二个5元（杂）环阴离子上的多价基团，或Y中的一个 Q是聚合物的重复单元; 条件是至少一个Y或Q包含离解偶极子。

公开(公告)号：EP0699349A1

公开(公告)日：1996-03-06

申请号：EP95914390.0

申请日：1995-03-21

申请人： CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (CNRS) ,  HYDRO-QUEBEC

发明人： MICHOT, Christophe ,  ARMAND, Michel ,  SANCHEZ, Jean-Yves ,  CHOQUETTE, Yves ,  GAUTHIER, Michel

IPC分类号： C01B21 ,  C07C307 ,  C07C311 ,  C07C317 ,  C07F9 ,  H01B1 ,  H01G9 ,  H01M4 ,  H01M6 ,  H01M10

CPC分类号： H01G9/038 ,  C01B21/0935 ,  C07C307/00 ,  H01B1/122 ,  H01G11/20 ,  H01G11/56 ,  H01M6/181 ,  H01M10/052 ,  H01M10/0525 ,  H01M10/0565 ,  H01M10/0567 ,  H01M10/0568 ,  H01M10/0569 ,  Y02E60/13

摘要： An ionic conducting material, the preparation thereof and uses of said material are disclosed. The material includes at least one solution of at least one ionic compound in an aprotic solvent, which compound is selected from compounds (1/mM)+[(ZY)2N]-, (1/mM)+[(ZY)3C]-, (1/mM)+[(ZY)2CQ]-, Wherein Y is SO¿2? or POZ; Q is -H, -COZ or Z; each substituent Z is independently a fluorine atom or an optionally perfluorinated organic group optionally having at least one polymerisable function, one of substitutents Z being a fluorine atom; and M is a cation. The material is useful in electrochemical generators, supercapacitors, polymer doping and electrochromic devices.

公开(公告)号：EP0603370A1

公开(公告)日：1994-06-29

申请号：EP93914825.0

申请日：1993-07-07

申请人： CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (CNRS) ,  HYDRO-QUEBEC

发明人： SANCHEZ, Jean-Yves ,  GOULART SILVA, Glaura ,  CHOQUETTE, Yves ,  ARMAND, Michel ,  PETIT, Jean-Pierre

IPC分类号： C08F299 ,  C08F283 ,  C08F290 ,  C08G4 ,  C08G65 ,  H01M6

CPC分类号： H01M6/181 ,  C08F283/065 ,  C08G4/00 ,  C08G65/06 ,  C08F236/16

摘要： La présente invention concerne des copolymères, leur procédé de préparation et leur utilisation pour l'élaboration de matériaux à conduction ionique. Un copolymère selon l'invention est constitué par des unités monomères répondant à la formule -CH2-O-CHR-CH2-O- (I) et des unités monomères répondant à la formule -CH2-CHR'-O- (II) dans lesquelles: R représente un atome d'hydrogène, un radical alkyle linéaire ou ramifié comportant de 1 à 8 atomes de carbone ou un radical CH3(-O-CH2-CH2)n-O-CH2-, dans lequel 1 n 10; R' représente un radical aliphatique présentant une insaturation polymérisable par voie radicalaire et inerte dans les conditions de polymérisation cationique. Les copolymères peuvent être obtenus par polymérisation cationiques de l'oxiranne et du dioxolane appropriés. Application à l'élaboration de matériaux à conduction ionique.

公开(公告)号：EP0699349B1

公开(公告)日：2007-10-10

申请号：EP95914390.0

申请日：1995-03-21

申请人： CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (CNRS) ,  HYDRO-QUEBEC

发明人： MICHOT, Christophe ,  ARMAND, Michel ,  SANCHEZ, Jean-Yves ,  CHOQUETTE, Yves ,  GAUTHIER, Michel

IPC分类号： H01M10/40 ,  H01M6/18 ,  C01B21/093 ,  C07C317/04 ,  C23F11/16 ,  C07C311/48

CPC分类号： H01G9/038 ,  C01B21/0935 ,  C07C307/00 ,  H01B1/122 ,  H01G11/20 ,  H01G11/56 ,  H01M6/181 ,  H01M10/052 ,  H01M10/0525 ,  H01M10/0565 ,  H01M10/0567 ,  H01M10/0568 ,  H01M10/0569 ,  Y02E60/13

公开(公告)号：EP0889863B1

公开(公告)日：2003-05-07

申请号：EP97951051.8

申请日：1997-12-30

申请人： HYDRO-QUEBEC ,  CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (CNRS)

发明人： MICHOT, Christophe ,  ARMAND, Michel ,  GAUTHIER, Michel ,  CHOQUETTE, Yves

IPC分类号： C04B41/00

CPC分类号： B01J31/0224 ,  B01J31/0215 ,  B01J31/0222 ,  B01J31/0225 ,  B01J31/0227 ,  B01J31/0235 ,  B01J31/0239 ,  B01J31/0247 ,  B01J31/0251 ,  B01J31/0252 ,  B01J31/0267 ,  B01J31/0271 ,  B01J31/0281 ,  B01J31/0288 ,  B01J31/0289 ,  B01J31/04 ,  B01J31/06 ,  B01J31/068 ,  B01J31/124 ,  B01J31/1815 ,  B01J31/2208 ,  B01J2231/122 ,  B01J2231/14 ,  B01J2231/326 ,  B01J2231/341 ,  B01J2231/348 ,  B01J2231/4205 ,  B01J2231/543 ,  B01J2531/35 ,  B01J2531/824 ,  C07B37/02 ,  C07B37/12 ,  C07C45/46 ,  C07C45/69 ,  C07C67/00 ,  C07C255/10 ,  C07C255/17 ,  C07C255/27 ,  C07C255/46 ,  C07C255/65 ,  C07C257/14 ,  C07C311/03 ,  C07C311/04 ,  C07C311/09 ,  C07C311/48 ,  C07C317/04 ,  C07C317/08 ,  C07C317/14 ,  C07C317/22 ,  C07C317/24 ,  C07C317/34 ,  C07C317/44 ,  C07C2601/10 ,  C07C2602/42 ,  C07D207/452 ,  C07D213/76 ,  C07D219/10 ,  C07D231/18 ,  C07D233/90 ,  C07D239/60 ,  C07D241/42 ,  C07D249/04 ,  C07D249/10 ,  C07D249/12 ,  C07D251/70 ,  C07D277/64 ,  C07D277/82 ,  C07D285/125 ,  C07D285/135 ,  C07D285/15 ,  C07D285/16 ,  C07D303/34 ,  C07D307/54 ,  C07D307/64 ,  C07D311/52 ,  C07D311/58 ,  C07D311/82 ,  C07D319/06 ,  C07D333/16 ,  C07D333/24 ,  C07D405/06 ,  C07D409/12 ,  C07D417/10 ,  C07D417/14 ,  C07F17/02 ,  C08F4/04 ,  C08G65/3344 ,  C09B69/00 ,  C09B69/02 ,  C09B69/10 ,  G02F1/1525 ,  G02F2001/151 ,  H01B1/122 ,  H01B1/128 ,  H01G9/022 ,  H01G9/038 ,  H01G11/02 ,  H01G11/62 ,  H01M4/00 ,  H01M4/02 ,  H01M4/131 ,  H01M4/133 ,  H01M4/134 ,  H01M4/382 ,  H01M4/405 ,  H01M4/48 ,  H01M4/485 ,  H01M4/505 ,  H01M4/525 ,  H01M4/5815 ,  H01M4/5825 ,  H01M4/60 ,  H01M4/625 ,  H01M4/661 ,  H01M6/00 ,  H01M6/04 ,  H01M6/164 ,  H01M6/166 ,  H01M6/168 ,  H01M6/181 ,  H01M6/183 ,  H01M10/052 ,  H01M10/0525 ,  H01M10/0565 ,  H01M10/0567 ,  H01M10/0568 ,  Y02E60/13 ,  Y10S430/127 ,  Y10T29/49108 ,  Y10T428/2918 ,  C07C49/84 ,  C07C49/553

摘要： Disclosed is a method for grafting a polymer onto the surface of a carbonate material with carboxyl, amine, and/or hydroxyl functions on its surface. Said material is placed in suspension in a solution including the polymer to be grafted, which has a carboxyl, amine, and/or hydroxyl function, said solution also being comprised of a polymer solvent. A process which stimulates the dehydration into a carboxyl function of an amine and/or hydroxyl function is then performed, and the polymer is grafted onto the carbonate material using ester or amide links. The invention can be used in the cathode or naode of an electrochemical generator, in polymer materials with low polar properties, in ink, and also as a conductive coating on flexible plastic used as an electrical contact, as electromagnetic shielding, or as static protection.

公开(公告)号：EP0672291B1

公开(公告)日：2000-05-31

申请号：EP94900892.4

申请日：1993-11-30

申请人： CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (CNRS) ,  HYDRO-QUEBEC

发明人： ARMAND, Michel "Les Corjons" ,  BARIL, Daniel ,  CHOQUETTE, Yves ,  MICHOT, Christophe ,  SANCHEZ, Jean-Yves 781, chemin de Chartreuse

IPC分类号： H01B1/12 ,  C08G65/32 ,  C08G81/00 ,  H01M4/60 ,  G02F1/155

CPC分类号： H01G9/025 ,  C08G65/329 ,  C08G65/33317 ,  C08G73/10 ,  C08G81/00 ,  C09K9/02 ,  G02F1/15 ,  H01B1/122 ,  H01G9/022 ,  H01M4/36 ,  H01M4/364 ,  H01M4/60 ,  H01M6/181 ,  H01M10/052 ,  H01M10/0565

摘要： The copolymer described is a segmented copolymer consisting essentially of organic segments A which have a number i of reactive ends such that i is from 1 to 6 inclusive, and segments B which have a number j of reactive ends such that j is from 1 to 6 inclusive. The segments B have redox properties and each segment A is connected to at least one segment B by a group Y and vice versa, the group Y being an ether, thioether, secondary amine, tertiary amine, secondary amide, tertiary amide, imide, quaternary ammonium group, or a group having a carbon-carbon bond. The respective weighted molar mean of i and j is 2 or more. Application to electrochemical generators and electrochromic systems.

公开(公告)号：EP0672291A1

公开(公告)日：1995-09-20

申请号：EP94900892.0

申请日：1993-11-30

申请人： CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (CNRS) ,  HYDRO-QUEBEC

发明人： ARMAND, Michel "Les Corjons" ,  BARIL, Daniel ,  CHOQUETTE, Yves ,  MICHOT, Christophe ,  SANCHEZ, Jean-Yves 781, chemin de Chartreuse

IPC分类号： C08G65 ,  C08G69 ,  C08G73 ,  C08G77 ,  C08G81 ,  C09K9 ,  G02F1 ,  H01B1 ,  H01G9 ,  H01M4 ,  H01M10 ,  H01M6

CPC分类号： H01G9/025 ,  C08G65/329 ,  C08G65/33317 ,  C08G73/10 ,  C08G81/00 ,  C09K9/02 ,  G02F1/15 ,  H01B1/122 ,  H01G9/022 ,  H01M4/36 ,  H01M4/364 ,  H01M4/60 ,  H01M6/181 ,  H01M10/052 ,  H01M10/0565

摘要： The copolymer described is a segmented copolymer consisting essentially of organic segments A which have a number i of reactive ends such that i is from 1 to 6 inclusive, and segments B which have a number j of reactive ends such that j is from 1 to 6 inclusive. The segments B have redox properties and each segment A is connected to at least one segment B by a group Y and vice versa, the group Y being an ether, thioether, secondary amine, tertiary amine, secondary amide, tertiary amide, imide, quaternary ammonium group, or a group having a carbon-carbon bond. The respective weighted molar mean of i and j is 2 or more. Application to electrochemical generators and electrochromic systems.

公开(公告)号：EP0968181B1

公开(公告)日：2005-04-27

申请号：EP98958294.5

申请日：1998-12-01

申请人： ACEP INC. ,  UNIVERSITE DE MONTREAL ,  CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (CNRS)

发明人： MICHOT, Christophe ,  ARMAND, Michel ,  CHOQUETTE, Yves ,  GAUTHIER, Michel

IPC分类号： C07C317/04 ,  C07D339/06 ,  C07D311/82 ,  C07C317/12 ,  C08G61/02 ,  C08F232/04 ,  H01M10/40 ,  H01M6/16

CPC分类号： H01G9/038 ,  C07C211/63 ,  C07C211/64 ,  C07C317/04 ,  C07C317/12 ,  C07C381/00 ,  C07D213/20 ,  C07D213/74 ,  C07D231/12 ,  C07D233/56 ,  C07D249/08 ,  C07D311/82 ,  C07D339/06 ,  C07F9/54 ,  H01G9/028 ,  H01G9/2004 ,  H01G11/48 ,  H01G11/56 ,  H01G11/62 ,  H01M4/485 ,  H01M4/505 ,  H01M4/525 ,  H01M4/60 ,  H01M4/624 ,  H01M4/661 ,  H01M6/164 ,  H01M6/168 ,  H01M6/181 ,  H01M8/1023 ,  H01M8/1025 ,  H01M8/1027 ,  H01M8/103 ,  H01M8/1032 ,  H01M8/1048 ,  H01M8/1067 ,  H01M10/052 ,  H01M10/054 ,  H01M10/0565 ,  H01M10/0568 ,  H01M10/36 ,  Y02E10/542 ,  Y02E60/122 ,  Y02E60/13

公开(公告)号：EP0890192A1

公开(公告)日：1999-01-13

申请号：EP98900830.0

申请日：1998-01-19

申请人： HYDRO-QUEBEC

发明人： VALLEE, Alain ,  ARMAND, Michel ,  CHOQUETTE, Yves ,  BELANGER, André ,  GAUTHIER, Michel ,  PERRIER, Michel ,  ZAGHIB, Karim ,  POTVIN, Estelle ,  BESNER, Simon

IPC分类号： H01M2 ,  H01M6 ,  H01M10

CPC分类号： H01M2/1686 ,  H01M2/1673 ,  H01M6/181 ,  Y10T29/49108 ,  Y10T29/49115

摘要： The invention concerns an aprotic electrolytic composition located in the separator and in at least one composite electrode containing a powder of an active electrode material, and if necessary an electronic conduction additive of an electrochemical generator. The electrolytic composition comprises a first polymer matrix consisting of a polyether and at least a second polymer matrix, macroscopically separated, and also at least an alkaline salt as well as a polar aprotic solvent: The polymer matrices are capable of being swollen by at least one of the polar aprotic solvents. The solvent or mixture of solvents is unevenly distributed between the polymer matrices. The invention also concerns an electrochemical generator comprising a negative electrode and positive electrode reversible to alkaline ions and a separator with polymer electrolyte, the electrolytic component of which is the composition described above. The invention further concerns the manufacture in two or three steps of a subassembly of an electrochemical generator by coating an electrode support with a composite electrode containing the second matrix, followed by a surface coating on the electrode resulting from the preceding step with a solution containing the first polymer matrix so as to form the separator wholly or partly.