公开(公告)号：EP0014599B1

公开(公告)日：1986-06-04

申请号：EP80300418.3

申请日：1980-02-13

申请人： M & T CHEMICALS, INC.

发明人： Berger, Abe

IPC分类号： C07F7/08 ,  C07F7/18 ,  C08G77/38

CPC分类号： C07F7/1844 ,  C07F7/0852 ,  C07F7/0854 ,  C08G59/4085 ,  C08G77/38 ,  H01B3/46

公开(公告)号：EP0024926B1

公开(公告)日：1986-12-03

申请号：EP80302986.7

申请日：1980-08-28

申请人： M & T CHEMICALS, INC.

发明人： Berger, Abe

IPC分类号： C07F7/08 ,  C07F7/18

CPC分类号： C07F7/1892

公开(公告)号：EP0031996A1

公开(公告)日：1981-07-15

申请号：EP80304205.0

申请日：1980-11-24

申请人： M & T CHEMICALS, INC.

发明人： Berger, Abe

IPC分类号： C07F7/10 ,  C07F7/18

CPC分类号： C07F7/0854 ,  C07F7/0812 ,  C07F7/0874 ,  C07F7/0889 ,  C07F7/182

摘要： This invention relates to a novel class of organosilanes and bis(hydantoinyl)disiloxanes. The characteristic feature of these silanes and disiloxanes is the presence of a hydantoin residue that is bonded to silicon through an alkylene group. Methods are disclosed for their production. The said compounds are useful coupling agents for bonding glass fibres to organic resins and as self-bonding adhesion promoters for room temperature curable silicone adhesives.

摘要翻译： 本发明涉及一类新型的有机硅烷和双（乙酰乙烯基）二硅氧烷。 这些硅烷和二硅氧烷的特征是存在通过亚烷基与硅键合的乙内酰脲残基。 公开了其生产方法。 所述化合物是用于将玻璃纤维粘合到有机树脂上的有用的偶联剂，以及用于室温可固化的硅氧烷粘合剂的自粘合促进剂。

公开(公告)号：EP0014599A3

公开(公告)日：1981-07-01

申请号：EP80300418

申请日：1980-02-13

申请人： M & T CHEMICALS, INC.

发明人： Berger, Abe

IPC分类号： C07F07/08 ,  C07F07/18 ,  C08G77/38 ,  C08G59/40 ,  H01B03/46

CPC分类号： C07F7/1844 ,  C07F7/0852 ,  C07F7/0854 ,  C08G59/4085 ,  C08G77/38 ,  H01B3/46

摘要： Novel silicones having the general formula
wherein 0 is an aromatic nucleus, Z is-S-
or-0-, R is a bivalent group or a functional bivalent group, each R' is chosen from monovalent hydrocarbon radicals and functional hydrocarbon radicals and any one R' may be the same as or different from another R 1 , R 3 is hydrogen or a hydrocarbon radical or a functional group or atom, x is 0 or an integer of 1 or more, F is a functional group or atom, with the proviso that F is not primary amino when Z is other than -0-, and T is a group chosen from alkoxy, aryloxy or other substituted or unsubstituted oxyhydrocarbyl radical and a group having the general formula
wherein Q, Z, R, R 1 , R 3 and F are as defined above and any one R may be the same as or different from the other R and one R 3 may be different from the other R 3 . These compounds may be made by reacting the compound
with
or with
where G denotes alkoxy or aryloxy or other substituted or unsubstituted oxyhydrocarbyl radical under conditions set out in the specification. The compounds are suitable for making copolymers of silicones with other organic chemicals, curing catalys for epoxies, urethane and the like.

公开(公告)号：EP0024926A2

公开(公告)日：1981-03-11

申请号：EP80302986.7

申请日：1980-08-28

申请人： M & T CHEMICALS, INC.

发明人： Berger, Abe

IPC分类号： C07F7/08 ,  C07F7/18

CPC分类号： C07F7/1892

摘要： Certain organosilane derivatives are prepared by

(i) reacting substantially equimolar amounts of an anhydrous alkali metal - or alkaline earth metal compound having the general formula
or the general formula
wherein M is an alkali metal or alkaline earth metal, b is the valency of M and R 1 , R 2 , R 3 , R 4 ,Z, m,n, q and t are as defined in the Specification, with haloalkylsilane having the general formula
wherein R 5 , R 6 , R 7 andp are as defined in the Specification and X 1 is Cl, Br or 1, the reaction being conducted under substantially anhydrous conditions at a temperature of from ambient to 200°C in a liquid reaction medium comprising at least one liquid hydrocarbon boiling at a temperature of40 to 200°C and in the presence of a phase transfer catalyst chosen from onium salts of elements in Group VA of Mendeleeff's Periodic Table and "crown" ethers or cyclic polyethers, the said onium salts having the general formula
wherein E is N, P, As, Sb or Bi, R 15 is an alkyl group containing 1 to 18 carbon atoms or a phenyl group and the R 15 groups are the same or different, X 2 is F, Cl, Br, sulphate, phosphate, carbonate alkylsulphonate or fluoroborate and r is the valency of X 2 ;
(ii) maintaining the resultant reaction medium ata temperature of from 40 to 200°C for a period sufficient to obtain substantially complete conversion to the desired compound,
(iii) isolating the compound (I) or compound (II) by evaporating the liquid reaction medium from the liquid phase of the reaction mixture.

Examples of compounds (III) and (V) are m-amino phenol and 3-chloropropyl trimethoxy silane respectively.

摘要翻译： 某些有机硅烷衍生物通过以下方法制备：（i）使基本上等摩尔量的具有通式的无水碱金属或碱土金属化合物，其中M是碱金属或碱土金属，b是M和R的化合价 R 1，R 2，R 3，R 4，Z，m，n，q和t如本说明书中所定义，卤代烷基硅烷具有通式，其中R 5， R 6，R 7和p如本说明书中所定义，X 1是Cl，Br或I，反应在基本无水条件下，在室温至200℃的温度下在液体 反应介质包含至少一种在40至200℃的温度下沸腾的液体烃，并且在相转移催化剂存在下，选择门多尔夫周期表VA族的元素鎓盐和“冠醚”或环状聚醚， 所述具有通式的鎓盐，其中E是N，P，As，Sb或Bi，R 1是 含有1〜18个碳原子的烷基或苯基，R 1〜5的基团是

公开(公告)号：EP0015720A1

公开(公告)日：1980-09-17

申请号：EP80300600.6

申请日：1980-02-28

申请人： M & T CHEMICALS, INC.

发明人： Berger, Abe

IPC分类号： C08L79/08 ,  C09D3/00 ,  H01B3/30 ,  H01B3/46 ,  C08L83/10 ,  C08G77/42 ,  C08G73/10 ,  H01L23/28

CPC分类号： H01L23/3171 ,  C08G73/106 ,  C08G77/455 ,  H01B3/306 ,  H01B3/46 ,  H01L23/296 ,  H01L23/3178 ,  H01L2924/0002 ,  H01L2924/00

摘要： A coating composition comprising a curable copolymer material which is the product of a condensation reaction, preferably a condensation reaction of corresponding molar quantities of an organic diamine and a silicone containing a bis-amino aryl ether or bis-amino aryl thioether and an organic dianhydride in at least one organic solvent chosen from monoalkyl ethers of ethylene glycol, monoalkyl ethers of condensed polyethylene glycol, dialkyl ethers of ethylene glycol, dialkyl ethers of condensed polyethylene glycol, and cyclic ethers containing not less than a 5 member ring, is suitable for use as a wire coating composition, passivation and/or protective coating composition(s) for semiconductor devices and the like. A part or all of the organic diamine may be a macrocyclic crown ether which enables the curable copolymer material to have a chemically bonded chelant embodies therein. The curable copolymer material may be of a block type configuration, a random type configuration, or both, and either may be cured at a low temperature such as ~75°C when diethylene glycol dimethylether is chosen as solvent.

摘要翻译： 一种涂料组合物，其包含作为缩合反应产物的可固化共聚物材料，优选相应摩尔量的有机二胺与含有双氨基芳基醚或双 - 氨基芳基硫醚和有机二酐的硅氧烷的缩合反应 选自乙二醇的单烷基醚，缩聚的聚乙二醇的单烷基醚，乙二醇的二烷基醚，缩合的聚乙二醇的二烷基醚，以及含有不少于5个成员环的环醚的至少一种有机溶剂适用于 用于半导体器件的线涂组合物，钝化和/或保护涂层组合物等。 有机二胺的一部分或全部可以是大环冠醚，其使固化共聚物材料具有化学键合的螯合剂。 可固化共聚物材料可以是嵌段型构型，随机型构型或两者，并且当二乙二醇二甲醚选择为溶剂时，可以在类似于75℃的低温下固化。

公开(公告)号：EP0014599A2

公开(公告)日：1980-08-20

申请号：EP80300418.3

申请日：1980-02-13

申请人： M & T CHEMICALS, INC.

发明人： Berger, Abe

IPC分类号： C07F7/08 ,  C07F7/18 ,  C08G77/38

CPC分类号： C07F7/1844 ,  C07F7/0852 ,  C07F7/0854 ,  C08G59/4085 ,  C08G77/38 ,  H01B3/46

摘要： Novel silicones having the general formula
wherein 0 is an aromatic nucleus, Z is-S-
or-0-, R is a bivalent group or a functional bivalent group, each R' is chosen from monovalent hydrocarbon radicals and functional hydrocarbon radicals and any one R' may be the same as or different from another R 1 , R 3 is hydrogen or a hydrocarbon radical or a functional group or atom, x is 0 or an integer of 1 or more, F is a functional group or atom, with the proviso that F is not primary amino when Z is other than -0-, and T is a group chosen from alkoxy, aryloxy or other substituted or unsubstituted oxyhydrocarbyl radical and a group having the general formula
wherein Q, Z, R, R 1 , R 3 and F are as defined above and any one R may be the same as or different from the other R and one R 3 may be different from the other R 3 .
These compounds may be made by reacting the compound
with
or with
where G denotes alkoxy or aryloxy or other substituted or unsubstituted oxyhydrocarbyl radical under conditions set out in the specification.
The compounds are suitable for making copolymers of silicones with other organic chemicals, curing catalys for epoxies, urethane and the like.

摘要翻译： 具有通式的新型硅酮，其中Q为芳香核，Z为-S-， -​​ CHEM或-O-，R为二价基团或官能二价基团，每个R 1为 由一价烃基和官能烃基和任何一个R 1可以与另一个R 1相同或不同，R 3是氢或烃基或官能团或原子，x是O或 F为1以上的整数，F为官能团或原子，条件是当Z不为-O-时，F不为伯氨基，T为选自烷氧基，芳氧基或其它取代或未取代的羟基烃基的基团 和具有通式的基团，其中Q，Z，R，R 1，R 3和F如上所定义，并且任何一个R可以与其它R相同或不同，并且一个R @可能与其他R <3不同。 这些化合物可以通过使化合物＆lt; CHEM＆gt;其中G表示烷氧基或芳氧基或其它取代或未取代的羟基烃基，在本说明书中列出的条件下进行。 该化合物适于制备硅氧烷与其它有机化学品的共聚物，环氧树脂固化催化剂，氨基甲酸乙酯等。

公开(公告)号：EP0163518A3

公开(公告)日：1987-12-23

申请号：EP85303748

申请日：1985-05-29

申请人： M & T CHEMICALS, INC.

发明人： Berger, Abe ,  Vora, Rohitkumar H.

IPC分类号： C08G73/10

CPC分类号： C08G73/14 ,  C08G73/1046 ,  C08G73/1064 ,  C08G73/16

摘要： Aromatic or aliphatic dianhydrides and/or acid anhydrides are reacted with aromatic diamines of formula (a) alone or in combination with other diamines to produce polyimides, polyamide acids, poly(amide-imides), poly(amide-amide acids), poly(esterimides) or poly)esteramide acids). These polymers are thermoplastic in nature and have improved processing characteristics and thermal stability. The polymers may be prepared by either melt or solution polymerization techniques.
wherein R 1 , R 2 and R 3 each independently is hydrogen, halogen or unsubstituted or substituted hydrocarbyl,
X 1 and X 2 each independently is substituted or unsubstituted branched, linear or cyclic alkylene or alkenylene of 1 to about 30 carbon atoms, -S-, or -O- with the proviso that X, or X 2 and may not both concurrently be -S- or -0-. n, n' and n" each independently is an integer of 1 to 4.

公开(公告)号：EP0015720B1

公开(公告)日：1983-10-12

申请号：EP80300600.6

申请日：1980-02-28

申请人： M & T CHEMICALS, INC.

发明人： Berger, Abe

IPC分类号： C08L79/08 ,  C09D3/00 ,  H01B3/30 ,  H01B3/46 ,  C08L83/10 ,  C08G77/42 ,  C08G73/10 ,  H01L23/28

CPC分类号： H01L23/3171 ,  C08G73/106 ,  C08G77/455 ,  H01B3/306 ,  H01B3/46 ,  H01L23/296 ,  H01L23/3178 ,  H01L2924/0002 ,  H01L2924/00

公开(公告)号：EP0031996B1

公开(公告)日：1983-01-26

申请号：EP80304205.0

申请日：1980-11-24

申请人： M & T CHEMICALS, INC.

发明人： Berger, Abe

IPC分类号： C07F7/10 ,  C07F7/18

CPC分类号： C07F7/0854 ,  C07F7/0812 ,  C07F7/0874 ,  C07F7/0889 ,  C07F7/182