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1.发明公开METHOD FOR RECOVERING CATALYST MATERIAL, CATALYST MATERIAL RECOVERED BY SAID RECOVERING METHOD, METHOD FOR RECOVERING SUBSTRATE, SUBSTRATE RECOVERED BY SAID RECOVERING METHOD 有权VERFAHREN ZURRÜCKGEWINNUNGVON KATALYSATORMATERIAL
公开(公告)号：EP1609527A1
公开(公告)日：2005-12-28
申请号：EP04718766.1
申请日：2004-03-09
IPC分类号： B01J38/00
CPC分类号： C22B11/028 , B01J23/96 , B01J38/00 , C22B7/009 , C22B11/048 , Y02P10/214
摘要： The present invention is a method for recovering a catalyst from a catalyst body comprising a carrier having a catalyst layer formed on at least a part of the surface thereof, which comprises (a) a step of forming an overcoat layer on the surface of the catalyst layer, and (b) a step of allowing the catalyst body having the overcoat layer formed thereon to stand under the condition to result in a difference in expansibility or contractility exhibited by the overcoat layer from that exhibited by the carrier, wherein exfoliation of the catalyst layer from the carrier is permitted by means of the resulting difference in expansibility or contractility under the condition.
摘要翻译： 本发明是一种从催化剂体中回收催化剂的方法，该催化剂体包括在其表面的至少一部分上形成有催化剂层的载体，其包括（a）在催化剂表面上形成外涂层的步骤 层，以及（b）在其上形成有外涂层的催化剂体在使载体表现出的外涂层的扩展性或收缩性差异的状态下进行的工序，其中催化剂的剥离 通过在该条件下产生的可扩展性或收缩性差异允许来自承运人的层。
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公开(公告)号：EP1386882A1
公开(公告)日：2004-02-04
申请号：EP02722892.3
申请日：2002-04-30
发明人： MAENISHI, Akira , ASOU, Tomonori , MUKAI, Yuji , OZEKI, Masataka , NAKAMURA, Akinari , UKAI, Kunihiro , TAGUCHI, Kiyoshi , TOMIZAWA, Takeshi , FUJIWARA, Seiji
CPC分类号： H01M8/0631 , B01J2208/00707 , B01J2208/00716 , B01J2219/00006 , C01B3/384 , C01B3/48 , C01B3/583 , C01B2203/0227 , C01B2203/0283 , C01B2203/044 , C01B2203/047 , C01B2203/0811 , C01B2203/0822 , C01B2203/0827 , C01B2203/1604 , C01B2203/1609 , C01B2203/1619 , C01B2203/169 , C01B2203/1695 , Y02P20/128 , Y02P20/52
摘要： A hydrogen generating part is provided for reacting water and a raw material composed of carbon and hydrogen atoms to generate hydrogen gas, a raw material supply part is provided for supplying a raw material to the hydrogen generating part, a water supply part is provided for supplying water to the hydrogen generating part, a catalyst combustion part is provided, an air supply part is provided for supplying air to the catalyst combustion part, a path switching part is provided for switching raw material supply paths between the raw material supply part and the hydrogen generating part, a bypass path is provided for supplying a raw material to the catalyst combustion part from the path switching part, and a combustion gas path is provided for supplying combustion gas after the catalyst combustion part to the hydrogen generating part. The control part switches the path switching part, and the inside of the hydrogen generating part is replaced with combustion gas after the catalyst combustion part.
摘要翻译： 提供氢生成部分，用于使水和由碳和氢原子组成的原料反应以产生氢气，提供原料供应部分，用于向氢产生部分供应原料;供水部分，用于供应 向生成氢的部分供水，设置催化剂燃烧部，设置用于向催化剂燃烧部供给空气的供气部，设置路径切换部，切换原料供给部与氢原子的原料供给路径 提供旁通路径，用于从路径切换部分向催化剂燃烧部分供应原料，并且提供燃烧气体路径以将催化剂燃烧部分之后的燃烧气体供应到氢气发生部分。 控制部切换路径切换部，在催化剂燃烧部之后，用燃烧气体代替氢生成部的内部。
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公开(公告)号：EP1271679A1
公开(公告)日：2003-01-02
申请号：EP01915753.6
申请日：2001-03-23
发明人： FUJII, Yasuhiro , HOSAKA, Masato , TOMIZAWA, Takeshi , UKAI, Kunihiro , TAGUCHI, Kiyoshi , SHONO, Toshiyuki , YOSHIDA, Yutaka , KITAGAWA, Koichiro
CPC分类号： H01M8/0612 , B01J8/001 , B01J8/0242 , B01J8/0278 , B01J21/04 , B01J23/40 , B01J23/70 , B01J37/0201 , B01J2208/00061 , B01J2208/00548 , B01J2208/00707 , C01B3/38 , C01B3/382 , C01B3/386 , C01B3/40 , C01B2203/0244 , C01B2203/045 , C01B2203/0485 , C01B2203/066 , C01B2203/0811 , C01B2203/0844 , C01B2203/1052 , C01B2203/1058 , C01B2203/1064 , C01B2203/107 , C01B2203/1076 , C01B2203/1082 , C01B2203/1241 , C01B2203/1276 , C01B2203/1288 , C01B2203/142 , C01B2203/1604 , C01B2203/1609 , C01B2203/1614 , C01B2203/169 , C01B2203/82 , Y02P20/52
摘要： When a hydrogen producing apparatus is stopped, the flow rates of a hydrocarbon-type fuel feedstock, water and an oxygen-containing oxidant gas are decreased respectively. A random decrease of the flow rates, however, invites a rapid increase in the temperature of a catalyst beyond the limit of thermal resistance, resulting in deactivation of the catalyst. Further, this poses a danger, for example, that the residual hydrocarbon-type fuel in the apparatus may be mixed with the oxidant gas after the stopping of the apparatus.
Thus, in stopping the operation, the present invention exerts such control as to decrease the flow rate of the hydrocarbon-type fuel and simultaneously increase the flow rate of water while maintaining the flow rate of the oxidant gas at a constant level, stop the hydrocarbon-type fuel, and thereafter stop the water and the oxidant gas.摘要翻译： 当氢生成装置停止的烃类燃料原料，水和氧的流率对气体分别减少含氧化剂。 流量的减少随机然而，邀请超出热阻的限制催化剂的温度迅速上升，在催化剂的失活所致。 此外，该会造成危险，例如，管芯DASS在装置残余烃类燃料可以与氧化剂气体的装置的停止后进行混合。 因此，在停止手术，本发明施加寻轨控制以降低烃类燃料的流率，并且同时增加水的流量，同时以恒定电平保持氧化剂气体的流量，停止烃 型燃料，此后停止水和氧化剂气体。
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4.发明公开
公开(公告)号：EP1162679A1
公开(公告)日：2001-12-12
申请号：EP00987776.2
申请日：2000-12-27
发明人： UKAI, Kunihiro , TOMIZAWA, Takeshi , TAGUCHI, Kiyoshi , SHONO, Toshiyuki , KITAGAWA, Koichiro , ASOU, Tomonori , OZEKI, Masataka , MIYAUCHI, Shinji , MAENISHI, Akira , YOSHIDA, Yutaka
CPC分类号： H01M8/04425 , B01J8/0457 , B01J2208/00061 , B01J2208/00309 , B01J2208/00504 , B01J2208/00548 , B01J2219/00157 , B01J2219/002 , B01J2219/00213 , B01J2219/00231 , C01B3/323 , C01B3/38 , C01B3/48 , C01B3/583 , C01B2203/0233 , C01B2203/0283 , C01B2203/0288 , C01B2203/044 , C01B2203/0445 , C01B2203/047 , C01B2203/0495 , C01B2203/066 , C01B2203/0811 , C01B2203/0816 , C01B2203/0822 , C01B2203/0827 , C01B2203/0844 , C01B2203/0866 , C01B2203/0877 , C01B2203/0883 , C01B2203/1011 , C01B2203/1023 , C01B2203/1041 , C01B2203/1047 , C01B2203/1064 , C01B2203/107 , C01B2203/1076 , C01B2203/1082 , C01B2203/1223 , C01B2203/1241 , C01B2203/1247 , C01B2203/1288 , C01B2203/146 , C01B2203/1604 , C01B2203/1609 , C01B2203/1619 , C01B2203/1638 , C01B2203/1657 , C01B2203/1685 , C01B2203/169 , C01B2203/1695 , H01M8/04014 , H01M8/04022 , H01M8/04373 , H01M8/04738 , H01M8/04776 , H01M8/0612 , H01M8/0662 , Y02P20/128
摘要： The present invention relates to an electric power generator and its operation method, which electric power generator is equipped with a hydrogen generator, a polymer electrolyte fuel cell for generating electric power using hydrogen rich gas from the hydrogen generator, a burner for burning the hydrogen generator, a flow rate controller for controlling the supply amount of a burning fuel to the burner, a communicating pathway connecting the flow rate controller and the burner, a joint where at least a residual fuel gas from a fuel electrode of the fuel cell and/or an incompletely generated gas from the hydrogen generator are combined into the communicating pathway, and a pressure-transferring pipe for releasing the pressure between the joint and the flow rate controller into the flow rate controller; the electric power generator being characterized in that the flow rate controller controls the supply amount of the burning fuel on the basis of the above-mentioned pressure.
摘要翻译： 发电机及其运行方法技术领域本发明涉及一种发电机及其运行方法，该发电机配备有氢发生器，使用来自氢发生器的富氢气体发电的聚合物电解质型燃料电池，燃烧氢发生器的燃烧器 用于控制向燃烧器燃烧燃料的供给量的流量控制器，连接流量控制器和燃烧器的连通路径，至少来自燃料电池的燃料电极的残留燃料气体和/或 来自氢发生器的不完全产生的气体被组合到连通通道中，以及用于将接头和流量控制器之间的压力释放到流量控制器中的压力传递管; 所述发电机的特征在于，所述流量控制器基于上述压力来控制燃烧燃料的供给量。
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公开(公告)号：EP1329417A1
公开(公告)日：2003-07-23
申请号：EP01972486.3
申请日：2001-09-26
CPC分类号： B01J19/2485 , B01D53/864 , B01J8/0496 , B01J23/63 , B01J37/0215 , B01J2208/00061 , B01J2208/00407 , B01J2208/00415 , B01J2208/00504 , B01J2208/00548 , B01J2219/00063 , B01J2219/00164 , B01J2219/002 , B01J2219/00213 , B01J2219/00236 , C01B3/48 , C01B2203/0233 , C01B2203/0283 , C01B2203/066 , C01B2203/0811 , C01B2203/085 , C01B2203/1023 , C01B2203/1041 , C01B2203/1064 , C01B2203/107 , C01B2203/1082 , C01B2203/1235 , C01B2203/1604 , C01B2203/1614 , C01B2203/1619 , C01B2203/1623 , C01B2203/1647 , C01B2203/1661 , C01B2203/169 , C01B2203/1695 , H01M8/0612 , H01M8/0662
摘要： Since carbon monoxide is generated as subcomponent in a water vapor reforming reaction, in many cases, a shifter for conducting a shift reaction on water and carbon monoxide is used in combination. Generally, in the case of a stable operation, a concentration of carbon monoxide hardly increases. However, when using conditions of a catalyst are changed due to external factors in the shifter, a concentration of carbon monoxide increases.
A device includes a reformer 1 containing carbon monoxide and water vapor, and a shifter 3 having a shift catalyst body 3a, and the device supplies hydrogen gas to the shifter from a gas supply part 1. In the above device, carbon monoxide concentration detection means 6 is provided at an exit of hydrogen gas of the shifter.
When a concentration of carbon monoxide that is detected by the carbon monoxide concentration detection means is larger than a set value, a quantity of water vapor is increased in the gas supply part 1.-
公开(公告)号：EP1256545A1
公开(公告)日：2002-11-13
申请号：EP00987775.4
申请日：2000-12-27
发明人： TAGUCHI, Kiyoshi , TOMIZAWA, Takeshi , UKAI, Kunihiro , SHONO, Toshiyuki , KITAGAWA, Koichiro , UEDA, Tetsuya , FUJIHARA, Seiji , YOSHIDA, Yutaka
CPC分类号： H01M8/0631 , B01J8/0453 , B01J8/0457 , B01J8/0488 , B01J8/0496 , B01J19/2485 , B01J23/40 , B01J23/63 , B01J23/72 , B01J35/0006 , B01J2208/00061 , B01J2208/00194 , B01J2208/00504 , B01J2208/00716 , B01J2219/0004 , B01J2219/00198 , B01J2219/002 , B01J2219/00202 , B01J2219/00213 , B01J2219/00231 , C01B3/16 , C01B3/48 , C01B3/583 , C01B3/586 , C01B2203/0233 , C01B2203/0283 , C01B2203/0288 , C01B2203/044 , C01B2203/0445 , C01B2203/047 , C01B2203/066 , C01B2203/0811 , C01B2203/0816 , C01B2203/085 , C01B2203/0866 , C01B2203/0877 , C01B2203/0883 , C01B2203/0894 , C01B2203/1023 , C01B2203/1041 , C01B2203/1064 , C01B2203/107 , C01B2203/1076 , C01B2203/1082 , C01B2203/1223 , C01B2203/1241 , C01B2203/1247 , C01B2203/1604 , C01B2203/1609 , C01B2203/1619 , C01B2203/1661 , C01B2203/169 , C01B2203/1695 , C01B2203/82 , C10K3/04 , Y02P20/52
摘要： A hydrogen producing apparatus comprising: a reforming section having a reforming catalyst which causes a reaction between a carbon-containing organic compound as a feedstock and water; a feedstock supply section for supplying the feedstock to the reforming section; a water supply section for supplying water to the reforming section; a heating section for heating the reforming catalyst; a shifting section having a shift catalyst which causes a shift reaction between carbon monoxide and water contained in a reformed gas supplied from the reforming section; and a purifying section having a purifying catalyst which causes oxidation or methanation of carbon monoxide contained in a gas supplied from the shifting section, wherein the shift catalyst comprises a platinum group metal and a metal oxide.
摘要翻译： 一种制氢装置，其特征在于，包括：重整部，其具有引起作为原料的含碳有机化合物与水的反应的重整催化剂; 原料供给部，用于将原料供给到重整部; 供水部，其向所述重整部供给水; 用于加热所述重整催化剂的加热部分; 具有变换催化剂的变速部分，其引起从重整部分供应的重整气体中包含的一氧化碳和水之间的转化反应; 以及净化部，其具有使从所述变速部供给的气体中含有的一氧化碳发生氧化或甲烷化的净化催化剂，其中所述变换催化剂包含铂族金属和金属氧化物。
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7.发明公开GAS CONCENTRATION SENSOR, HYDROGEN PURIFICATION UNIT USING THIS AND FUEL CELL SYSTEM 审中-公开加拿大卫生研究所，加拿大卫生组织
公开(公告)号：EP1308719A1
公开(公告)日：2003-05-07
申请号：EP01921972.4
申请日：2001-04-20
CPC分类号： G01N25/30 , G01N25/36 , G01N33/0026 , H01M8/0618 , H01M8/0662 , H01M8/0668 , Y10T436/11 , Y10T436/23
摘要： In order to provide a step capable of reliably detecting a CO concentration in a reformed gas at low cost and a hydrogen purifier capable of fully exerting a function of a CO purifying catalyst, a gas concentration detector comprising a reaction chamber which has a catalyst layer and a gas temperature detector and capable of detecting the concentration of carbon monoxide in the gas by means of a signal of the temperature detector referring to a reformed gas passing along through the reaction chamber.
摘要翻译： 为了提供能够可靠地检测低成本的重整气体中的CO浓度的步骤和能够充分发挥CO净化催化剂功能的氢气净化器的气体浓度检测器，其包括具有催化剂层的反应室和 气体温度检测器，其能够通过参考通过反应室的重整气体的温度检测器的信号来检测气体中的一氧化碳浓度。
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8.发明公开HYDROGEN FORMATION APPARATUS, FUEL CELL SYSTEM AND METHOD FOR CONTROLLING HYDROGEN FORMATION APPARATUS 审中-公开装置产生氢气，燃料电池及其控制方法氢气发生装置，
公开(公告)号：EP1396473A1
公开(公告)日：2004-03-10
申请号：EP02733453.1
申请日：2002-06-11
CPC分类号： H01M8/04302 , B01J8/025 , B01J23/42 , B01J2208/00061 , B01J2208/00504 , B01J2208/0053 , B01J2208/025 , B01J2219/00006 , B01J2219/0004 , B01J2219/002 , B01J2219/00211 , B01J2219/00213 , B01J2219/00231 , C01B3/38 , C01B3/48 , C01B2203/0233 , C01B2203/0283 , C01B2203/0415 , C01B2203/044 , C01B2203/045 , C01B2203/047 , C01B2203/0485 , C01B2203/066 , C01B2203/068 , C01B2203/0811 , C01B2203/0816 , C01B2203/0822 , C01B2203/0827 , C01B2203/0866 , C01B2203/0872 , C01B2203/1052 , C01B2203/1064 , C01B2203/107 , C01B2203/1076 , C01B2203/1082 , C01B2203/1223 , C01B2203/1241 , C01B2203/1247 , C01B2203/127 , C01B2203/142 , C01B2203/143 , C01B2203/146 , C01B2203/147 , C01B2203/16 , C01B2203/1604 , C01B2203/1609 , C01B2203/1619 , C01B2203/1623 , C01B2203/1676 , C01B2203/169 , C01B2203/1695 , C01B2203/82 , H01M8/04089 , H01M8/04223 , H01M8/04291 , H01M8/04303 , H01M8/0618 , H01M8/0625 , H01M8/0668 , H01M8/0675 , H01M8/2483 , Y02P20/128 , Y02P20/52
摘要： Many organic raw materials contain sulfur components, and the sulfur component is a catalyst poisoning component for their catalysts to decrease steam reforming reactivity.
A hydrogen generator including a raw material supplying unit 4 supplying a raw material containing a sulfur component and composed of an organic compound, a water supplying unit 5 supplying water, a reformer 1 producing hydrogen gas, the reformer 1 provided with a reforming catalyst to make the raw material and water undergo a reaction, and a carbon monoxide removing unit 6 reducing the content of carbon monoxide in hydrogen gas produced in the reformer 1, wherein the reforming catalyst is constituted by a carrier composed of platinum and a metal oxide is provided.摘要翻译： 许多有机原料中含有的硫成分，硫成分为他们的催化剂以降低蒸汽重整反应性的催化剂中毒组分。 一种氢发生器，其包括一个剃刀供给单元4供给的剃刀含有硫组分和有机化合物组成，水供给部5供给水，重整器1产生氢气，重整器1设置有 重整催化剂，使原料与水发生反应，以及一氧化碳去除单元6降低一氧化碳的重整器1产生的氢气中的内容，worin重整催化剂由铂和由金属构成的载体构成 设置氧化物。
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9.发明公开
公开(公告)号：EP1354853A1
公开(公告)日：2003-10-22
申请号：EP02710339.9
申请日：2002-01-24
IPC分类号： C01B3/48 , C01B3/16 , H01M8/06 , B01J23/652 , B01J23/42 , B01J23/656 , B01J29/14 , B01J29/16 , B01J29/12 , B01J29/62 , B01J29/22 , B01J29/44 , B01J29/74 , B01J29/89 , B01J29/072 , B01J29/068
CPC分类号： H01M8/0662 , B01J8/009 , B01J8/0453 , B01J8/048 , B01J8/0496 , B01J19/2485 , B01J23/002 , B01J23/63 , B01J23/64 , B01J23/652 , B01J23/6567 , B01J23/89 , B01J23/8993 , B01J2208/00194 , B01J2208/00495 , C01B3/16 , C01B3/48 , C01B2203/0233 , C01B2203/0283 , C01B2203/0288 , C01B2203/044 , C01B2203/047 , C01B2203/066 , C01B2203/0811 , C01B2203/0822 , C01B2203/0827 , C01B2203/0883 , C01B2203/1023 , C01B2203/1064 , C01B2203/1076 , C01B2203/1082 , C01B2203/1094 , C01B2203/1241 , C01B2203/1288 , C01B2203/1604 , C01B2203/1609 , C01B2203/1619 , C01B2203/1661 , C01B2203/1676 , C10K3/04 , H01M8/0612 , Y02P20/128 , Y02P20/52
摘要： Conventional hydrogen purification apparatuses cannot be used satisfactorily for applications in which much time is required for startup of the apparatus, and the apparatus is repeatedly started and stopped at frequent intervals because of complicated handling.
In a hydrogen purification apparatus comprising at least a catalysis body 1 removing carbon monoxide from a reformed gas containing hydrogen, carbon monoxide and steam, the catalyst body 1 is constituted by a carrier comprised of a complex oxide in which at least one of Mo, W and Re is compounded with Zr, or comprised of an oxide of one of Mo, W, Re and Zr, and at least one of Pt, Pd, Rh and Ru carried on the surface of the carrier.摘要翻译： 传统的氢气净化装置不能令人满意地用于在其中大部分时间是必需的设备的启动应用程序，并且该装置被启动，并在频繁的时间间隔由于复杂的处理的反复停止。 在氢气提纯装置从含有氢气，一氧化碳和水蒸气的重整气体，其包括至少一个催化体1中去除一氧化碳，催化体1由其中的至少一个由一复合氧化物的载体构成 的Mo，W和Re是复合有Zr或包括钼，钨，Re和Zr中的一种的氧化物，以及铂，钯，Rh和Ru中的至少一种所述载体的表面上。
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公开(公告)号：EP1314690A1
公开(公告)日：2003-05-28
申请号：EP01955648.9
申请日：2001-08-10
CPC分类号： B01J19/2485 , B01J8/001 , B01J8/0085 , B01J8/0453 , B01J8/0457 , B01J8/0496 , B01J19/0013 , B01J23/40 , B01J23/63 , B01J2208/00061 , B01J2208/00132 , B01J2208/00168 , B01J2208/00176 , B01J2208/00495 , B01J2208/00504 , B01J2208/0053 , B01J2219/00063 , B01J2219/00081 , B01J2219/00087 , B01J2219/00155 , B01J2219/00157 , B01J2219/00159 , B01J2219/00198 , B01J2219/00202 , C01B3/48 , C01B2203/0233 , C01B2203/0288 , C01B2203/066 , C01B2203/1064 , C01B2203/1076 , C01B2203/1082 , C01B2203/1614 , C01B2203/1619 , C01B2203/1623 , H01M8/0612 , H01M8/0662
摘要： It was difficult to acquire a good CO cleanup efficiency in a hydrogen refining apparatus, for instance, when the start-up and stop operations are frequently repeated.
A hydrogen refining apparatus, including a shifter 3 having a shifting catalyst body 3a containing noble metals and metal oxides, and a reforming section 1 for supplying hydrogen gas containing carbon monoxide to the shifter 3, (1) the temperature of an upstream side of the shifting catalyst body 3a relative to the hydrogen gas flow being substantially between 300°C and 500°C and (2) the temperature of a downstream side of the shifting catalyst body 3a relative to the hydrogen gas flow being substantially at 300°C or less.摘要翻译： 在氢精炼装置中难以获得良好的CO净化效率，例如，当启动和停止操作经常重复时。 一种氢精炼装置，包括具有含有贵金属和金属氧化物的变换催化剂体3a的变速器3和用于向变速器3供给含有一氧化碳的氢气的转化部1，（1）上游侧的温度 转换催化剂体3a相对于氢气流量基本上在300℃至500℃之间，和（2）变换催化剂体3a的下游侧相对于氢气流的温度基本上在300℃以下 。
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