公开(公告)号：EP1878075A2

公开(公告)日：2008-01-16

申请号：EP06755473.3

申请日：2006-05-05

申请人： Phostech Lithium Inc. ,  UNIVERSITE DE MONTREAL

发明人： GAUTHIER, Michel ,  MICHOT, Christophe

IPC分类号： H01M4/04 ,  H01M4/48 ,  H01M10/40

CPC分类号： H01M4/485 ,  H01M4/04 ,  H01M4/13 ,  H01M4/131 ,  H01M4/136 ,  H01M4/1397 ,  H01M4/366 ,  H01M4/505 ,  H01M4/525 ,  H01M4/5805 ,  H01M4/5815 ,  H01M4/582 ,  H01M4/5825 ,  H01M4/622 ,  H01M4/625 ,  H01M10/0525

摘要： The invention relates to an electrode material and a composite electrode including same. The electrode material consists of particles or particulate aggregates of a complex LiiMmM'm'ZzOoNnFf oxide, wherein M is at least one transition metal, M' is at least one metal other than a transition metal; Z is at least one non-metal; coefficients i, m, m', z, o, n and f are selected in such a way that the complex oxide is electrically neutral, with i = 0, m > 0, z = 0, m' =0, o > 0, n = 0 and f = 0. At least part of the complex oxide particle or particulate aggregate surface is coated with a carbon layer bound by chemical bonds and/or physical bonds to the carbon. The complex oxide has formula; the carbon has covalently bonded functional GF groups.

公开(公告)号：EP1702373A1

公开(公告)日：2006-09-20

申请号：EP04802357.6

申请日：2004-12-22

申请人： UNIVERSITE DE MONTREAL ,  CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (CNRS) ,  Phostech Lithium Inc.

发明人： GAUTHIER, Laurent ,  GAUTHIER, Michel ,  LAVOIE, Donald ,  MICHOT, Christophe ,  RAVET, Nathalie

IPC分类号： H01M4/04 ,  C25B11/04 ,  C07F1/02 ,  H01M4/48 ,  C01B25/26

CPC分类号： C01B25/45 ,  C01B25/37 ,  H01M4/136 ,  H01M4/1397 ,  H01M4/366 ,  H01M4/525 ,  H01M4/5825 ,  H01M4/625 ,  H01M10/052 ,  H01M2004/028

摘要： The invention relates to a process for preparing an at least partially lithiated transition metal oxyanion-based lithium-ion reversible electrode material, which comprises providing a precursor of said lithium-ion reversible electrode material, heating said precursor, melting same at a temperature sufficient to produce a melt comprising an oxyanion containing liquid phase, cooling said melt under conditions to induce solidification thereof and obtain a solid electrode that is capable of reversible lithium ion deinsertion/insertion cycles for use in a lithium battery. The invention also relates to lithiated or partially lithiated oxyanion-based-lithium-ion reversible electrode materials obtained by the aforesaid process.

公开(公告)号：EP2529431A1

公开(公告)日：2012-12-05

申请号：EP11736573.4

申请日：2011-01-28

申请人： Phostech Lithium Inc.

发明人： GEOFFROY, Denis ,  LIANG, Guoxian ,  GAUTHIER, Michel ,  LAHRS, Thorsten ,  RAVET, Nathalie ,  PARENT, Michel ,  VALLÉE, Alain ,  LEBLANC, Patrick ,  COTTON, Frederic

IPC分类号： H01M4/136 ,  H01M10/052 ,  H01M4/58

CPC分类号： H01M4/5825 ,  C01B25/37 ,  C01B25/45 ,  H01M4/131 ,  H01M4/136 ,  H01M4/621 ,  H01M4/622 ,  H01M4/625 ,  H01M10/052 ,  H01M10/0565 ,  H01M2004/021

摘要： The invention relates to a material C-A
x M(XO
4 )
y that consists of particles of a compound of the formula A
x M(XO
4 )
y , wherein said particles comprise a carbon deposit deposited by means of pyrolysis on at least a portion of the surface thereof, and where: A is Li alone or partially replaced by at most 10 atomic % of Na or K; M is Fe(II), or Μn(II), or mixtures thereof alone or partially replaced by at most 30 atomic % of one or more metals selected from Mn, Ni and Co and/or at most 5 % of Fe(III); XO
4 is PO
4 alone or partially replaced by at most 10 molar % of at least one group selected from SO
4 , Si0
4 and MoO
4 ; and where said material has a calcium impurity content of lower than about 1000 ppm.

公开(公告)号：EP2095451A1

公开(公告)日：2009-09-02

申请号：EP07855518.2

申请日：2007-12-07

申请人： Phostech Lithium Inc.

发明人： LIANG, Guoxian ,  CHAREST, Patrick ,  GAUTHIER, Michel ,  GUERFI, Abdelbast ,  MICHOT, Christophe ,  ZAGHIB, Karim

IPC分类号： H01M4/58 ,  C09C3/04 ,  C09C3/08

CPC分类号： C01B25/45 ,  B82Y30/00 ,  C01P2002/32 ,  C01P2002/72 ,  C01P2004/03 ,  C01P2004/04 ,  C01P2004/45 ,  C01P2004/50 ,  C01P2004/51 ,  C01P2004/52 ,  C01P2004/53 ,  C01P2004/61 ,  C01P2004/62 ,  C01P2004/64 ,  C09C1/00 ,  C09C1/22 ,  C09C3/08 ,  H01M4/136 ,  H01M4/5825 ,  H01M4/625 ,  H01M2004/021

摘要： A particle composition comprising particles having a complex oxide core and a conductive carbon deposit on at least part of the surface of the core, wherein the particles comprise elementary nanoparticles having a nanoscale size and agglomerates or aggregates of elementary nanoparticles having a submicron to micron scale particle size; said conductive carbon deposit is a non powdery deposit, and is present on at least part of the surface of the elementary particles and on the surface of the aggregates.

摘要翻译： 一种颗粒组合物，包括具有复杂氧化物芯和在所述芯的表面的至少一部分上的导电性碳沉积物的颗粒，worin所述颗粒包含具有纳米级尺寸的基本纳米颗粒和附聚或具有亚微米到微米级粒子的基本纳米颗粒的聚集体 大小; 所述导电碳沉积物是一种非粉状沉积物，并且是存在于初级粒子的表面的至少一部分和所述聚集体的表面上。

公开(公告)号：EP2089316A2

公开(公告)日：2009-08-19

申请号：EP07870235.4

申请日：2007-10-30

申请人： Phostech Lithium Inc. ,  Université de Montréal

发明人： RAVET, Nathalie ,  GAUTHIER, Michel ,  LAHRS, Thorsten ,  LIANG, Guoxian ,  MICHOT, Christophe

IPC分类号： C01B25/45 ,  H01M4/58

CPC分类号： H01M4/136 ,  C01B25/45 ,  H01M4/0402 ,  H01M4/0471 ,  H01M4/1397 ,  H01M4/5825 ,  H01M4/622 ,  H01M4/625 ,  H01M10/0525 ,  H01M2004/028 ,  H01M2220/30

摘要： The invention relates to a method for preparing a carbonated complex oxide having a very low water content, and to the use thereof as a cathode material. The carbonated complex oxide is made of particles of an olivine-structure AMXO4 compound bearing on a portion at least of their surface a carbon film deposited by pyrolysis. A is Li alone or partially replaced with at most 10 at % of Na or K. M is FeII alone or partially replaced with at most 50 at % of one or more other metals selected from Mn, Ni and Co and/or with at most 10 at % of one or more aliovalent or isovalent metals other than Mn, Ni or Co and/or with at most 5 at % of FeIII. XO4 Is PO4 alone or partially replaced with at most 10 molar % of SO4 and SiO4. the material has a water content lower than 1000 ppm.

公开(公告)号：EP2514007A1

公开(公告)日：2012-10-24

申请号：EP10836900.0

申请日：2010-12-17

申请人： Phostech Lithium Inc.

发明人： LIANG, Guoxian ,  DUFOUR, Jasmin ,  GAUTHIER, Michel ,  RAVET, Nathalie ,  GEOFFROY, Denis

IPC分类号： H01M4/04 ,  H01M4/136 ,  H01M4/58

CPC分类号： H01M4/0471 ,  C01B25/37 ,  C01B25/45 ,  H01M4/136 ,  H01M4/1397 ,  H01M4/5825

摘要： Process for improving the electrochemical performance of an alkali metal oxyanion electrode material having a pyrolitic carbon deposit thereon, comprising a heat treatment under a humidified atmosphere where the heat treatment is performed at a temperature in the range of about 300°C to about 950°C.

公开(公告)号：EP2438105A1

公开(公告)日：2012-04-11

申请号：EP10782863.4

申请日：2010-06-01

申请人： Phostech Lithium Inc. ,  Universite Du Quebec A Montreal

发明人： SCHOUGAARD, Steen Brian ,  GAUTHIER, Michel ,  KUSS, Christian ,  LEPAGE, David ,  LIANG, Guoxian ,  MICHOT, Christophe

IPC分类号： C08G61/12 ,  C08F2/00 ,  C08F292/00 ,  C08F4/26

CPC分类号： C08F4/26 ,  C08F4/10 ,  C08G61/126 ,  C08G2261/3223 ,  C08K3/32 ,  H01M4/131 ,  H01M4/137 ,  H01M4/5825 ,  H01M10/0525

摘要： The invention relates to a process to induce polymerization of an organic electronically conductive polymer in the presence of a partially delithiated alkali metal phosphate which acts as the polymerization initiator.

公开(公告)号：EP0968181B1

公开(公告)日：2005-04-27

申请号：EP98958294.5

申请日：1998-12-01

申请人： ACEP INC. ,  UNIVERSITE DE MONTREAL ,  CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (CNRS)

发明人： MICHOT, Christophe ,  ARMAND, Michel ,  CHOQUETTE, Yves ,  GAUTHIER, Michel

IPC分类号： C07C317/04 ,  C07D339/06 ,  C07D311/82 ,  C07C317/12 ,  C08G61/02 ,  C08F232/04 ,  H01M10/40 ,  H01M6/16

CPC分类号： H01G9/038 ,  C07C211/63 ,  C07C211/64 ,  C07C317/04 ,  C07C317/12 ,  C07C381/00 ,  C07D213/20 ,  C07D213/74 ,  C07D231/12 ,  C07D233/56 ,  C07D249/08 ,  C07D311/82 ,  C07D339/06 ,  C07F9/54 ,  H01G9/028 ,  H01G9/2004 ,  H01G11/48 ,  H01G11/56 ,  H01G11/62 ,  H01M4/485 ,  H01M4/505 ,  H01M4/525 ,  H01M4/60 ,  H01M4/624 ,  H01M4/661 ,  H01M6/164 ,  H01M6/168 ,  H01M6/181 ,  H01M8/1023 ,  H01M8/1025 ,  H01M8/1027 ,  H01M8/103 ,  H01M8/1032 ,  H01M8/1048 ,  H01M8/1067 ,  H01M10/052 ,  H01M10/054 ,  H01M10/0565 ,  H01M10/0568 ,  H01M10/36 ,  Y02E10/542 ,  Y02E60/122 ,  Y02E60/13

公开(公告)号：EP1702373B1

公开(公告)日：2017-10-11

申请号：EP04802357.6

申请日：2004-12-22

申请人： UNIVERSITE DE MONTREAL ,  CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE -CNRS- ,  Johnson Matthey Public Limited Company

发明人： GAUTHIER, Laurent ,  GAUTHIER, Michel ,  LAVOIE, Donald ,  MICHOT, Christophe ,  RAVET, Nathalie

IPC分类号： C01B25/37 ,  C01B25/45 ,  H01M4/136 ,  H01M4/1397 ,  H01M4/36 ,  H01M4/58 ,  H01M4/525 ,  H01M10/052 ,  H01M4/02 ,  H01M4/62

CPC分类号： C01B25/45 ,  C01B25/37 ,  H01M4/136 ,  H01M4/1397 ,  H01M4/366 ,  H01M4/525 ,  H01M4/5825 ,  H01M4/625 ,  H01M10/052 ,  H01M2004/028

公开(公告)号：EP1325526A1

公开(公告)日：2003-07-09

申请号：EP01973907.7

申请日：2001-09-21

申请人： Hydro-Québec ,  UNIVERSITE DE MONTREAL ,  CNRS

发明人： ARMAND, Michel ,  GAUTHIER, Michel ,  MAGNAN, Jean-François ,  RAVET, Nathalie

IPC分类号： H01M4/48 ,  C01B25/37 ,  C01B33/20 ,  H01M4/58 ,  H01M4/62 ,  C01B17/96

CPC分类号： H01G9/155 ,  C01B17/96 ,  C01B25/37 ,  C01B25/45 ,  C01B33/20 ,  C01P2004/03 ,  C01P2004/04 ,  C01P2004/50 ,  C01P2004/80 ,  H01M4/136 ,  H01M4/366 ,  H01M4/485 ,  H01M4/525 ,  H01M4/5825 ,  H01M4/625 ,  H01M10/052 ,  H01M10/0525 ,  Y02E60/13 ,  Y10T428/2982 ,  Y10T428/2991 ,  Y10T428/30

摘要： The invention concerns a synthesis method for a material consisting of particles comprising a core and a coating and/or being interconnected by a carbon cross-linkage, the core of said particles including at least a compound of formula LixM1-yM'y(XO4)n wherein: x, y and n are numbers such that 0≤ x ≤2, 0 ≤ y ≤0.6 and 1 ≤ n ≤1.5; M is a transition metal; M' is a element of fixed valency, and the synthesis being performed by reacting and balancing the mixture of precursors, with a reducing gas atmosphere, so as to bring the transition metal(s) to the desired degree of valency, the synthesis being carried out in the presence of a carbon source called conductive carbon which is pyrolyzed. The resulting materials exhibit excellent electrical conductivity and a highly enhanced chemical activity. M' can be selected among Mg?2+, Ca2+ Al3+, Zn2+¿ or a combination of those elements, X is selected among S, P, and Si. Said material can be used as active electrode material in batteries.

摘要翻译： 制备含有过渡金属，固定的价态金属和磷酸盐，硫酸盐或硅酸盐形式的锂的碳桥化合物。 式CLi xM 1-yM 1> y（XO 4）n（A）的化合物的合成包括以所需比例平衡和/或均匀的均匀混合物，其包含：（a）氧化态的M源或多或少 最终化合物中的金属比; （b）元素M 1>的源; （c）锂源; （d）任选的X的源化合物; 和（e）导电碳源。 C：桥连碳与化合物CLi xM 1-yM 1> y（XO 4）n; x：0-2; y：0-0.6; n：1-1.5; M：过渡金属或周期表第一系列的混合物; M 1> Mg 2+>，Ca 2+>，Al 3+>或Zn 2+>或它们的组合; X，S，P或Si源M，M 1>，Li和X可以在至少一个阶段中引入，并且合成以气态气氛中所需比例的热力学或动力学平衡进行，以便施加氧化 过渡金属的状态达到所需的化合价; 对于Fe，Mn，Co，Ni，该化合价优选为2，对于Ti和V，该价数为3或4。这由气态气氛的组成，反应温度和源（c）化合物相对于（a ），（b）和（d）。 该方法包括化合物（e）的热解阶段，以获得化合物，其中在压力大于或等于3000，优选3750Kg·cm -2>的压实粉末上测量的电子传导性大于10- 8> S.cm -1>。 对于所获得的化合物（A）和含有这些材料的电化学电池，还包括独立权利要求。