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    VERFAHREN ZUR HERSTELLUNG VON ALIPHATISCHEN ALPHA,OMEGA-AMINONITRILEN
    8.
    发明公开
    VERFAHREN ZUR HERSTELLUNG VON ALIPHATISCHEN ALPHA,OMEGA-AMINONITRILEN 失效
    VERFAHREN ZUR HERSTELLUNG VON ALIPHATIS​​CHEN ALPHA，OMEGA-AMINONITRILEN

    公开(公告)号：EP0800508A1

    公开(公告)日：1997-10-15

    申请号：EP95941718.0

    申请日：1995-12-16

    申请人： BASF AKTIENGESELLSCHAFT

    发明人： MELDER, Johann-Peter ,  SCHNURR, Werner ,  FLICK, Klemens ,  EBEL, Klaus ,  WITZEL, Tom ,  FISCHER, Rolf ,  HARDER, Wolfgang ,  REHFINGER, Alwin

    IPC分类号： B01J23 ,  B01J27 ,  B01J37 ,  C07B61 ,  C07C253 ,  C07C255

    CPC分类号： B01J23/8898 ,  B01J23/76 ,  B01J23/8892 ,  B01J37/0201 ,  C07C253/30 ,  C07C255/24

    摘要： Aliphatic alpha,omega-aminonitriles are prepared by partially hydrogenating aliphatic alpha,omega-dinitriles at an increased temperature and pressure in the presence of a solvent and a catalyst. The catalyst contains (a) a compound based on a metal selected from the group made up of nickel, cobalt, iron, ruthenium and rhodium; (b) 0.01 to 25 % by weight in relation to (a) of a promoter based on a metal selected from the group comprising of palladium, platinum, iridium, osmium, copper, silver, gold, chromium, molybdenum, tungsten, manganese, rhenium, zinc, cadmium, lead, aluminium, tin, phosphorus, arsenic, antimony, bismuth, silicium, titanium, zirconium and rare earth metals; and (c) 0 to 5 % by weight in relation to (a) of a compound based on an alkaline or alkaline-earth metal, provided that component (a) not be based on iron or iron and a metal selected from the group comprising cobalt, ruthenium and rhodium when (b) is a promoter based on a metal selected from the group comprising titanium, manganese, chromium and molybdenum. Moreover, when component (a) is a compound based only on ruthenium or on rhodium, ruthenium and rhodium, or nickel and rhodium, promoter (b) may be dispensed with.

    摘要翻译： 通过在溶剂和催化剂存在下在升高的温度和压力下部分氢化脂族α，ω-二腈来制备脂族α，ω-氨基腈。 该催化剂含有（a）基于选自镍，钴，铁，钌和铑的金属的化合物; （b）相对于（a）0.01至25重量％的基于选自钯，铂，铱，锇，铜，银，金，铬，钼，钨，锰， 铼，锌，镉，铅，铝，锡，磷，砷，锑，铋，硅，钛，锆和稀土金属; 和（c）相对于（a）基于碱或碱土金属的化合物为0-5重量％，条件是组分（a）不基于铁或铁以及选自 （b）是基于选自钛，锰，铬和钼的金属的促进剂时，钴，钌和铑。 此外，当组分（a）是仅基于钌或铑，钌和铑或者镍和铑的化合物时，可以省去助催化剂（b）。