公开(公告)号：EP0323915B1

公开(公告)日：1992-04-08

申请号：EP89300125.5

申请日：1989-01-06

申请人： SUMITOMO CHEMICAL COMPANY, LIMITED

发明人： Hiratsuka, Mitsunori ,  Shiroshita, Masao ,  Ohtsuka, Susumu ,  Arai, Kenji ,  Hirata, Naonori

IPC分类号： C07C323/22

CPC分类号： C07C319/20 ,  C07C323/22

公开(公告)号：EP0457505A2

公开(公告)日：1991-11-21

申请号：EP91304198.4

申请日：1991-05-09

申请人： SUMITOMO CHEMICAL COMPANY, LIMITED

发明人： Hiratsuka, Mitsunori ,  Hirata, Naonori ,  Saitoh, Kazuo ,  Shibata, Hideyuki

IPC分类号： C07D401/12 ,  C07D405/12 ,  C07D405/14 ,  C07D239/60 ,  C07D239/52 ,  A01N43/54

CPC分类号： C07D213/79 ,  C07C69/88 ,  C07D239/60 ,  C07D303/16 ,  C07D305/06 ,  C07D307/12 ,  C07D309/06 ,  C07D313/04 ,  C07D317/24 ,  C07D319/04 ,  C07D321/06 ,  C07D401/12 ,  C07D405/12 ,  C07D405/14

摘要： A pyrimidine derivative has the formula,
wherein A is C 3 -C 8 cycloalkyl C 1 -C 6 alkyl, C 3 -C 8 cycloalkyl C 1 -C 6 alkyl substituted with at least one member selected from the group consisting of C 1 -C 6 alkyl and halogen, C 3 -C 6 oxacycloalkyl, C 3 -C 6 oxacycloalkyl substituted with at least one member selected from the group consisting of C 1 -C 6 alkyl and halogen, C 3 -C 6 oxacydoalkyl C 1 -C 6 alkyl, C 3 -C 6 oxacycloalkyl C 1 -C 6 alkyl substituted with at least one member selected from the group consisting of C 1 -C 6 alkyl and halogen, C 3 -C 5 dioxacycloalkyl, C 3 -C 5 dioxacycloalkyl substituted with at least one member selected from the group consisting of C 1 -C 6 alkyl and halogen, C 3 -C 5 dioxacycloalkyl C 1 -C 6 alkyl or C 2 -C 5 dioxacycloalkyl C 1 -C 6 alkyl substituted with at least one member selected from the group consisting of C 1 -C 6 alkyl and halogen ;

each of R 1 and R 2 , which may be the same or different, is C 1 -C 6 alkyl, C 1 -C 6 alkoxy, halo C 1 -C 6 alkoxy or halogen ;
X is oxygen or sulfur ;
Z is nitrogen or CY 4 ;
each of Y 1 , Y 2 and Y 3 , which may be the same or different, is hydrogen, halogen, C 1 -C 6 alkyl or C 1 -C 6 alkoxy; and
Y 4 is hydrogen, hydroxyl, mercapto, nitro, halogen, C 1 -C 6 alkyl, C 2 -C 6 alkenyl, C 2 -C 6 alkynyl, C 1 -C 6 alkoxy, C 3 -C 6 alkenyloxy, C 3 -C 6 alkynyloxy, halo C 1 -C 6 alkyl, halo C 2 -C 6 alkenyl, halo C 2 -C 6 alkynyl, halo C 1 -C 6 alkoxy, halo C 3 -C 6 alkenyloxy, halo C 3 -C 6 alkynyloxy, C 1 -C 6 alkoxy C 1 -C 6 alkyl, C 3 -C 6 alkenyloxy C 1 -C 6 alkyl, C 3 -C 6 alkynyloxy C 1 -C 6 alkyl, cyano, formyl, carboxyl, C 1 -C 6 alkoxycarbonyl, C 3 -C 6 alkenyloxycarbonyl, C 3 -C 6 alkynyloxycarbonyl, phenyl, phenyl substituted with at least one member

摘要翻译： 嘧啶衍生物具有下式，其中X是氧或硫; Z是氮或CY 4。 嘧啶衍生物可以与惰性载体或稀释剂一起作为活性成分掺入除草组合物中。

公开(公告)号：EP0468690B1

公开(公告)日：1995-05-31

申请号：EP91306488.7

申请日：1991-07-17

申请人： SUMITOMO CHEMICAL COMPANY LIMITED

发明人： Hiratsuka, Mitsunori ,  Hirata, Naonori ,  Saitoh, Kazuo ,  Shibata, Hideyuki

IPC分类号： C07D239/46 ,  C07D239/60 ,  C07D401/12 ,  C07D213/62 ,  C07C311/48 ,  A01N43/54

CPC分类号： C07D213/81 ,  C07C311/48 ,  C07D239/52 ,  C07D239/56 ,  C07D239/60 ,  C07D401/12

公开(公告)号：EP0549344A1

公开(公告)日：1993-06-30

申请号：EP92311759.2

申请日：1992-12-23

申请人： SUMITOMO CHEMICAL COMPANY, LIMITED

发明人： Hiratsuka, Mitsunori ,  Uekawa, Toru ,  Hirata, Naonori ,  Saito, Kazuo ,  Shibata, Hideyuki

IPC分类号： C07D251/16 ,  A01N43/66 ,  C07D251/34

CPC分类号： C07D401/12 ,  A01N43/66 ,  C07D251/20 ,  C07D251/22 ,  C07D251/26 ,  C07D251/34 ,  C07D251/38

摘要： A herbicidally active triazine derivative has the formula :
wherein each of R 1 and R 2 , which may be the same or different, represents a hydrogen atom ; a C 1 -C 6 alkyl group; a C 3 -C 6 alkenyl group; a C 3 -C 6 alkynyl group; a halo-C 1 -C 6 alkyl group; a C 1 -C 6 alkoxy-C 1 -C 6 alkyl group ; a C 3 -C 6 alkenyloxy-C 1 -C 6 alkyl group ; a C 3 -C 6 alkynyloxy-C 1 -C 6 alkyl group ; a C 1 -C 6 alkoxycarbonyl-C 1 -C 6 alkyl group; a C 3 -C 6 alkenyloxycarbonyl-C 1 -C 6 alkyl group; a C 3 -C 6 alkynyloxycarbonyl-C 1 -C 6 alkyl group; a cyano-C 1 -C 6 alkyl group; a cyclo-C 3 -C 8 alkyl group; a group represented by the formula,

摘要翻译： 除草活性三嗪衍生物具有下式：，其中R 1和R 2各自可以相同或不同，表示氢原子; C1-C6烷基; C3-C6烯基; C3-C6炔基; 卤代-C 1 -C 6烷基; C1-C6烷氧基-C1-C6烷基; C 3 -C 6烯氧基-C 1 -C 6烷基; C 3 -C 6炔氧基-C 1 -C 6烷基; C1-C6烷氧基羰基-C1-C6烷基; C 3 -C 6烯氧基羰基-C 1 -C 6烷基; C3-C6炔氧基羰基-C1-C6烷基; 氰基-C 1 -C 6烷基; 环-C 3 -C 8烷基; 由式表示的基团（其中R 5和R 6各自可以相同或不同，表示氢原子，C1-C6烷基，C3-C6烯基 基团或C3-C6炔基，n表示1,2,3或4的整数）; 由式表示的基团（其中n如上定义，R 7表示C 1 -C 6烷基，C 3 -C 6烯基或C 3 -C 6炔基，m表示整数 0，1或2）; 任选被至少一个选自C 1 -C 6烷基，C 1 -C 6烷氧基，C 1 -C 6卤代烷基，（C 1 -C 6烷氧基）羰基，硝基和氰基和卤素原子的基团取代的苯基; 或任选被至少一个选自C 1 -C 6烷基，C 1 -C 6烷氧基，C 1 -C 6卤代烷基，（C 1 -C 6烷氧基）羰基，硝基和氰基和卤素原子的基团取代的苄基，或R R 1和R 2在其末端键合在一起形成任选被至少一个选自C 1 -C 6烷基和卤素原子的基团取代的C 4 -C 7亚烷基或R 1和R <2>在其末端键合在一起形成含有任选被至少一个选自C 1 -C 6烷基和卤素原子的基团取代的杂原子的C 3 -C 6亚烷基（R 1中的杂原子 并且R 2表示氮原子，氧原子或硫原子），R 3和R 4各自可以相同或不同，表示C1-C6烷基; C1-C6烷氧基; 卤代-C 1 -C 6烷氧基; 或卤素原子，X表示氧原子或硫原子，Z表示CH，N或CY 4，Y 1，Y 2和Y 3各自可以相同或不同 ，表示氢原子; 卤素原子; C1-C6烷基; C1-C6烷氧基; 硝基; 氰基; 或苯基，Y 4表示羟基; 巯基; 硝基; 卤素原子; C1-C6烷基; C2-C6烯基; C2-C6炔基; C1-C6烷氧基; C3-C6烯氧基; C3-C6炔氧基; 卤代-C 1 -C 6烷基; 卤代C 2 -C 6烯基; 卤代-C2-C6炔基; 卤代-C 1 -C 6烷氧基; 卤代-C 3 -C 6烯氧基; 卤代-C 3 -C 6炔氧基; C1-C6烷氧基-C1-C6烷基; C 3 -C 6烯氧基-C 1 -C 6烷基; C 3 -C 6炔氧基-C 1 -C 6烷基; 氰基; 甲酰基; 羧基; （C1-C6烷氧基）羰基; （C 3 -C 6烯氧基）羰基; （C 3 -C 6炔氧基）羰基; 任选被至少一个选自C 1 -C 6烷基，C 1 -C 6烷氧基，C 1 -C 6卤代烷基，（C 1 -C 6烷氧基）羰基，硝基和氰基和卤素原子的基团取代的苯基; 任选被至少一个选自C 1 -C 6烷基，C 1 -C 6烷氧基，C 1 -C 6卤代烷基，（C 1 -C 6烷氧基）羰基，硝基和氰基和卤素原子的基团取代的苯氧基; 任选被至少一个选自C 1 -C 6烷基，C 1 -C 6烷氧基，C 1 -C 6卤代烷基，（C 1 -C 6烷氧基）羰基，硝基，氰基和卤素原子的基团取代的苯硫基; 任选被至少一个选自C 1 -C 6烷基，C 1 -C 6烷氧基，C 1 -C 6卤代烷基，（C 1 -C 6烷氧基）羰基，硝基和氰基和卤素原子的基团取代的苄氧基; 任选被至少一个选自C 1 -C 6烷基，C 1 -C 6烷氧基，C 1 -C 6卤代烷基，（C 1 -C 6烷氧基）羰基，硝基和氰基和卤素原子的基团取代的苄硫基， 式中，如上所述的（其中R 5和R 6各自）; 由下式表示的基团（其中R 5和R 6如上所定义）; 由公式表示的组，

公开(公告)号：EP0426476A1

公开(公告)日：1991-05-08

申请号：EP90311985.7

申请日：1990-11-01

申请人： SUMITOMO CHEMICAL COMPANY, LIMITED

发明人： Hiratsuka, Mitsunori ,  Hirata, Naonori ,  Saitoh, Kazuo ,  Shibata, Hideyuki

IPC分类号： C07D239/34 ,  C07D239/52 ,  C07D239/38 ,  C07D401/12 ,  C07D213/62 ,  C07C239/22 ,  C07C323/62 ,  A01N43/54

CPC分类号： C07D213/81 ,  A01N43/54 ,  A01N43/647 ,  C07C239/22 ,  C07D239/34 ,  C07D239/52 ,  C07D239/60 ,  C07D295/24 ,  C07D401/12 ,  A01N43/707 ,  A01N41/10 ,  A01N41/06 ,  A01N41/04 ,  A01N37/48 ,  A01N37/22 ,  A01N37/10 ,  A01N37/02 ,  A01N37/00 ,  A01N35/10 ,  A01N2300/00

摘要： A pyrimidine derivative useful as a herbicide is represented by the formula
wherein each of R 1 and R 2 , which may be the same or different, represents a hydrogen atom, a C 1 -C 6 alkyl group, a C 3 -C 6 alkenyl group, a C 3 -C 6 alkynyl group, a halo C 1 -C 6 alkyl group, a C 1 -C 6 alkoxy C 1 -C 6 alkyl group, a C 3 -C 6 alkenyloxy C,-C 6 alkyl group, a C 3 -C 6 alkynyloxy C 1 -C 6 alkyl group, a C 1 -C 6 alkoxycarbonyl Ci-C 6 alkyl group, a C 3 -C 6 alkenyloxycarbonyl C 1 -C 6 alkyl group, a C 3 -C 6 alkynyloxycarbonyl C 1 -C 6 alkyl group, a cyano C 1 -C 6 alkyl group, a group represented by the formula,
(in which each of R 5 and R 6 , which may be the same or different, represents a hydrogen atom, a C 1 -C 6 alkyl group, a C 3 -C 6 alkenyl group or a C 3 -C 6 alkynyl group, and n represents an integer of 1, 2, 3, or 4), a group represented by the formula,
(in which n is as defined above, R 7 represents a C 1 -C 6 alkyl group, a C 3 -C 6 alkenyl group or a C 3 -C 6 alkynyl group, and m represents an integer of 0, 1 or 2), a cyclo C 3 -C 8 alkyl group, or an optionally substituted phenyl group, an optionally substituted benzyl group, or R 1 and R 2 , bonded together at their ends, form an optionally substituted C 4 -C 7 alkylene group or an optionally substituted C 3 -C 6 alkylene group containing hetero atom; the hetero atom in R' and R 2 means a nitrogen atom, an oxygen atom or a sulfur atom; each of R 3 and R 4 , which may be the same or different, represents a C 1 -C 6 alkyl group, a C 1 -C 6 alkoxy group, a halo C 1 -C 6 alkoxy group or a halogen atom; X represents an oxygen atom or a sulfur atom; Z represents N or CY 4 ; each of Y 1 , Y 2 , Y 3 , which may be the same or different, represents a hydrogen atom, a halogen atom, a C 1 -C 6 alkyl group, or a Ci-C 6 alkoxy group; and Y 4 represents a hydrogen atom, a hydroxyl group, a mercapto group, a nitro group, a halogen atom, a C 1 -C 6 alkyl group, a C 2 -C 6 alkenyl group, a C 2 -C 6 alkynyl group, a C 1 -C 6 alkoxy group, a C 3 -C 6 alkenyloxy group, a C 3 -C 6 alkynyloxy group, a halo C 1 -C 6 alkyl group, a halo C 2 -C 6 alkenyl group, a halo C 2 -C 6 alkynyl group, a halo C 1 -C 6 alkoxy group, a halo C 3 -C 6 alkenyloxy group, a halo C 3 -C 6 alkynyloxy group, a C 1 -C 6 alkoxy C 1 -C 6 alkyl group, a C 3 -C 6 alkenyloxy C 1 -C 6 alkyl group, a C 3 -C 6 alkynyloxy C 1 -C 6 alkyl group, a cyano group, a formyl group, a carboxyl group, a C 1 -C 6 alkoxycarbonyl group, a C 3 -C 6 alkenyloxycarbonyl group, a alkynyloxycarbonyl group; an optionally substituted phenyl group, an optionally substituted phenoxy group, an optionally substituted phenylthio group, an optionally substituted benzyloxy group, an optionally substituted benzylthio group, a group represented by the formula,
(in which R 5 and R 6 are as defined above), a group represented by the formula,
(in which R 5 and R 6 are as defined above),
(in which R 7 and m are as defined above), a group represented by the formula,
(in which R 7 and X are as defined above), or a group represented by the formula,
(in which R 7 , m and n are as defined above), each optionally substituted group in the above being substituted with a C 1 -C 6 alkyl group, a C 1 -C 6 alkoxy group, a halo C 1 -C 6 alkyl group, a C 1 -C 6 alkoxycarbonyl group or a halogen atom.

摘要翻译： 可用作除草剂的嘧啶衍生物由式CHEM表示，其中R 1和R 2各自可以相同或不同，表示氢原子，C1-C6烷基，C3 -C 6烯基，C 3 -C 6炔基，卤代C 1 -C 6烷基，C 1 -C 6烷氧基C 1 -C 6烷基，C 3 -C 6烯氧基C 1 -C 6烷基，C 3 -C 6炔氧基C 1 -C 6烷基， C6烷基，C1-C6烷氧基羰基C1-C6烷基，C3-C6烯氧基羰基C1-C6烷基，C3-C6炔氧基羰基C1-C6烷基，氰基C1-C6烷基，由 式（CHEM）（其中R 5和R 6各自可以相同或不同，表示氢原子，C1-C6烷基，C3-C6烯基或C3- C6炔基，n表示1,2,3或4的整数），由式表示的基团（其中n如上定义，R 7表示C 1 -C 6烷基 ，C3-C6烯基或C3-C6炔基，m表示0,1或2的整数） ，环C3-C8烷基或任选取代的苯基，任选取代的苄基或R 1和R 2在其末端键合在一起形成任选取代的C 4 -C 7亚烷基或 任选取代的含C3-C6亚烷基的杂原子; R 1和R 2中的杂原子是指氮原子，氧原子或硫原子; R 3和R 4各自可以相同或不同，表示C1-C6烷基，C1-C6烷氧基，卤代C1-C6烷氧基或卤素原子; X表示氧原子或硫原子; Z表示N或CY 4; Y 1，Y 2，Y 3各自可以相同或不同，表示氢原子，卤素原子，C1-C6烷基或C1-C6烷氧基; Y 4表示氢原子，羟基，巯基，硝基，卤原子，C 1〜C 6烷基，C 2〜C 6烯基，C 2〜C 6炔基，C 1〜 C 3烷氧基，C 3 -C 6烯氧基，C 3 -C 6炔氧基，卤代C 1 -C 6烷基，卤代C 2 -C 6烯基，卤代C 2 -C 6炔基，卤代C 1 -C 6烷氧基， 卤代C 3 -C 6烯氧基，卤代C 3 -C 6炔氧基，C 1 -C 6烷氧基C 1 -C 6烷基，C 3 -C 6烯氧基C 1 -C 6烷基，C 3 -C 6炔氧基C 1 -C 6烷基， 氰基，甲酰基，羧基，C 1 -C 6烷氧基羰基，C 3 -C 6烯氧基羰基，炔氧基羰基; 任选取代的苯基，任选取代的苯氧基，任选取代的苯硫基，任选取代的苄氧基，任选取代的苄硫基，由式表示的基团（其中R 5和R“ 6>如上所定义），由式表示的基团（其中R 5和R 6如上所定义），（其中R 7和m分别为 由式-X-R-R 7表示的基团（其中R 7和X如上所定义），或由下式表示的基团（其中R 式中，m和n如上定义），上述每个任选取代的基团被C 1 -C 6烷基，C 1 -C 6烷氧基，卤代C 1 -C 6烷基，C 1 -C 6烷氧基羰基 基团或卤素原子。

公开(公告)号：EP0426476B1

公开(公告)日：1994-07-27

申请号：EP90311985.7

申请日：1990-11-01

申请人： SUMITOMO CHEMICAL COMPANY LIMITED

发明人： Hiratsuka, Mitsunori ,  Hirata, Naonori ,  Saitoh, Kazuo ,  Shibata, Hideyuki

IPC分类号： C07D239/34 ,  C07D239/52 ,  C07D239/38 ,  C07D401/12 ,  C07D213/62 ,  C07C239/22 ,  C07C323/62 ,  A01N43/54

CPC分类号： C07D213/81 ,  A01N43/54 ,  A01N43/647 ,  C07C239/22 ,  C07D239/34 ,  C07D239/52 ,  C07D239/60 ,  C07D295/24 ,  C07D401/12 ,  A01N43/707 ,  A01N41/10 ,  A01N41/06 ,  A01N41/04 ,  A01N37/48 ,  A01N37/22 ,  A01N37/10 ,  A01N37/02 ,  A01N37/00 ,  A01N35/10 ,  A01N2300/00

公开(公告)号：EP0579469A3

公开(公告)日：1994-04-27

申请号：EP93305439.7

申请日：1993-07-12

申请人： SUMITOMO CHEMICAL COMPANY, LIMITED

发明人： Uekawa, Toru ,  Hiratsuka, Mitsunori ,  Hirata, Naonori ,  Saito, Kazuo ,  Yogai, Hiroyuki

IPC分类号： C07D401/06 ,  A01N43/42 ,  C07D409/14 ,  C07D405/14

CPC分类号： C07D401/06 ,  A01N43/42 ,  A01N43/60 ,  A01N47/20 ,  C07D405/14 ,  C07D409/14

摘要： Novel N-acyldihydroquinoline derivatives represented by the formula (I),

   wherein each of R¹, R² and R³, which may be the same or different, represents a hydrogen atom; a halogen atom; a C₁-C₆ alkyl group; a C₁-C₆ alkoxy group; a a halo-C₁-C₆ alkyl group; a halo-C₁-C₆ alkoxy group; a (C₁-C₆ alkoxy)carbonyl group; a C₁-C₆ alkylthio group; a C₁-C₆ alkylamino group; a di(C₁-C₆ alkyl)amino group; a phenyl group; or a phenoxy group,
   each of R⁴ and R⁵, which may be the same or different, represents a hydrogen atom or a C₁-C₆ alkyl group, or R⁴ and R⁵ are bonded together at their ends to form a C₂-C₅ alkylene group,
   R⁶ represents a hydrogen atom; a halogen atom; an amino group; a C₁-C₆ alkylamino group; a di(C₁-C₆ alkyl)amino group; a (C₁-C₆ alkoxy)carbonylamino group; a cyano group; or a group represented by the formula, -C(=O)-Y-R⁷ (wherein Y represents an oxygen atom or a sulfur atom and R⁷ represents a hydrogen atom; a C₁-C₁₀ alkyl group; a C₂-C₁₀ alkenyl group; a C₂-C₁₀ alkynyl group; a halo-C₁-C₁₀ alkyl group; a halo-C₂-C₁₀ alkenyl group; a halo-C₂-C₁₀ alkynyl group; a C₃-C₁₀ cycloalkyl group; a C₃-C₁₀ cycloalkenyl group; a C₁-C₁₀ alkoxy-C₁-C₁₀ alkyl group; a C₁-C₁₀ alkylamino-C₁-C₁₀ alkyl group; a di(C₁-C₁₀ alkyl)amino-C₁-C₁₀ alkyl group; a furyl-C₁-C₁₀ alkyl group; a thienyl-C₁-C₁₀ alkyl group; a C₁-C₁₀ alkylamino group; a di(C₁-C₁₀ alkyl)amino group;
-N=CH(C₁-C₁₀ alkyl) group;

group;
or a phenyl group optionally substituted with at least one member selected from the group consisting of (C₁-C₆ alkoxy)carbonyl groups, halogen atoms and C₁-C₆ alkyl groups; or a phenyl-C₁-C₆ alkyl group optionally substituted with at least one member selected from the group consisting of (C₁-C₆ alkoxy)carbonyl groups, halogen atoms and C₁-C₆ alkyl groups);
or a group represented by the formula,

(wherein each of R⁸ and R⁹, which may be the same or different, represents a hydrogen atom; a C₁-C₆ alkyl group; a C₂-C₆ alkenyl group; a C₂-C₆ alkynyl group; a halo-C₁-C₆ alkyl group; a halo-C₂-C₆ alkenyl group; a halo-C₂-C₆ alkynyl group; a C₃-C₆ cycloalkyl group; a C₃-C₆ cycloalkenyl group; an amino group; a C₁-C₆ alkylamino group; a di(C₁-C₆ alkyl)amino group; or a phenyl group optionally substituted with at least one member selected from the group consisting of halogen atoms and C₁-C₆ alkyl groups; or a phenyl-C₁-C₆ alkyl group optionally substituted with at least one member selected from the group consisting of halogen atoms and C₁-C₆ alkyl groups),
   X represents CH or a nitrogen atom, a method for producing the same and their use as herbicides. The N-acyldihydroquinoline derivatives have herbicidal activity and selectivity between crops and weeds and therefore, can be used as an active ingredient for herbicides.

摘要翻译： 由式（Ⅰ）表示的新的N-酰基二氢喹啉衍生物，其中R 1，R 2和R 3可以相同或不同，代表氢原子; 卤素原子; 一个C 1 -C 6烷基; C 1 -C 6烷氧基; 卤代-C 1 -C 6烷基; 卤代-C 1 -C 6烷氧基; （C 1 -C 6烷氧基）羰基; C 1 -C 6烷硫基; C 1 -C 6烷基氨基; 二（C 1 -C 6烷基）氨基; 苯基; 或苯氧基，R 4和R 5可以相同或不同，各自代表氢原子或C 1 -C 6烷基，或R 4和R 5在它们的末端结合在一起形成C 2 -C 5亚烷基， R 6代表氢原子; 卤素原子; 氨基; C 1 -C 6烷基氨基; 二（C 1 -C 6烷基）氨基; （C 1 -C 6烷氧基）羰基氨基; 氰基; （式中，Y表示氧原子或硫原子，R 6表示氢原子，C 1 -C 10烷基，C 2 -C 10链烯基，C 2 -C 10链烯基， C 2 -C 10炔基;卤代C 1 -C 10烷基;卤代C 2 -C 10烯基;卤代C 2 -C 10炔基; C 3 -C 10环烷基; C 3 -C 10环烯基; C 1 -C 10炔基 C 1-10烷氧基-C 1 -C 10烷基; C 1 -C 10烷基氨基-C 1 -C 10烷基;二（C 1 -C 10烷基）氨基-C 1 -C 10烷基;呋喃基-C 1 -C 10烷基;噻吩基-C 1 -C 10烷基; C 1 -C 10烷基; C 1 -C 10烷基氨基;二（C 1 -C 10烷基）氨基; -N = CH（C 1 -C 10烷基）基团;或任选被至少一个选择的基团取代的苯基 （C 1 -C 6烷氧基）羰基，卤素原子和C 1 -C 6烷基组成的组;或任选被至少一个成员取代的苯基-C 1 -C 6烷基 （C 1 -C 6烷氧基）羰基，卤素原子和C 1 -C 6烷基组成的组中的基团; （其中每个R 6和R 6可以相同或不同，代表氢原子; C 1 -C 6烷基; C 2 -C 6链烯基; C 2 -C 6炔基; 卤代C 1 -C 6烷基;卤代C 2 -C 6链烯基;卤代C 2 -C 6炔基; C 3 -C 6环烷基; C 3 -C 6环烯基;氨基; C 1 -C 6烷基氨基 （C 1 -C 6烷基）氨基;或任选被至少一个选自卤素原子和C 1 -C 6烷基的成员取代的苯基;或任意取代的苯基-C 1 -C 6烷基 其中至少一个选自卤素原子和C 1 -C 6烷基的成员），X代表CH或氮原子，其制备方法及其作为除草剂的用途。 N-酰基二氢喹啉衍生物具有作物和杂草之间的除草活性和选择性，因此可以用作除草剂的活性成分。

公开(公告)号：EP0323915A1

公开(公告)日：1989-07-12

申请号：EP89300125.5

申请日：1989-01-06

申请人： SUMITOMO CHEMICAL COMPANY, LIMITED

发明人： Hiratsuka, Mitsunori ,  Shiroshita, Masao ,  Ohtsuka, Susumu ,  Arai, Kenji ,  Hirata, Naonori

IPC分类号： C07C323/22

CPC分类号： C07C319/20 ,  C07C323/22

摘要： Compounds of the present invention are represented by the formula,
wherein X represents a lower alkyl, lower alkoxy, lower haloalkyl or lower haloalkoxy group or a halogen atom, and R¹ and R², which may be the same or different, represent a hydrogen atom or a methyl group. They are useful intermediates for preparing herbicidal compounds of the formula
which compounds are obtained by dehydrating the corresponding compounds (I) with any of a certain number of acids.
The compounds (I) are prepared by reaction of an aldehyde
with an acetoacetic acid salt in the presence of a C₁₋₆ carboxylic acid salt.

摘要翻译： 本发明化合物由下式表示，其中X代表低级烷基，低级烷氧基，低级卤代烷基或低级卤代烷氧基或卤素原子，R 1和R 2可以是 相同或不同，表示氢原子或甲基。 它们是用于制备式CHEM的除草化合物的有用中间体，该化合物通过用一定数量的酸中的任何一种脱水相应的化合物（I）而获得。 化合物（I）通过在C 1-6羧酸盐的存在下使醛与乙酰乙酸盐反应来制备。

公开(公告)号：EP0579469A2

公开(公告)日：1994-01-19

申请号：EP93305439.7

申请日：1993-07-12

申请人： SUMITOMO CHEMICAL COMPANY, LIMITED

发明人： Uekawa, Toru ,  Hiratsuka, Mitsunori ,  Hirata, Naonori ,  Saito, Kazuo ,  Yogai, Hiroyuki

IPC分类号： C07D401/06 ,  A01N43/42 ,  C07D409/14 ,  C07D405/14

CPC分类号： C07D401/06 ,  A01N43/42 ,  A01N43/60 ,  A01N47/20 ,  C07D405/14 ,  C07D409/14

摘要： Novel N-acyldihydroquinoline derivatives represented by the formula (I),

   wherein each of R¹, R² and R³, which may be the same or different, represents a hydrogen atom; a halogen atom; a C₁-C₆ alkyl group; a C₁-C₆ alkoxy group; a a halo-C₁-C₆ alkyl group; a halo-C₁-C₆ alkoxy group; a (C₁-C₆ alkoxy)carbonyl group; a C₁-C₆ alkylthio group; a C₁-C₆ alkylamino group; a di(C₁-C₆ alkyl)amino group; a phenyl group; or a phenoxy group,
   each of R⁴ and R⁵, which may be the same or different, represents a hydrogen atom or a C₁-C₆ alkyl group, or R⁴ and R⁵ are bonded together at their ends to form a C₂-C₅ alkylene group,
   R⁶ represents a hydrogen atom; a halogen atom; an amino group; a C₁-C₆ alkylamino group; a di(C₁-C₆ alkyl)amino group; a (C₁-C₆ alkoxy)carbonylamino group; a cyano group; or a group represented by the formula, -C(=O)-Y-R⁷ (wherein Y represents an oxygen atom or a sulfur atom and R⁷ represents a hydrogen atom; a C₁-C₁₀ alkyl group; a C₂-C₁₀ alkenyl group; a C₂-C₁₀ alkynyl group; a halo-C₁-C₁₀ alkyl group; a halo-C₂-C₁₀ alkenyl group; a halo-C₂-C₁₀ alkynyl group; a C₃-C₁₀ cycloalkyl group; a C₃-C₁₀ cycloalkenyl group; a C₁-C₁₀ alkoxy-C₁-C₁₀ alkyl group; a C₁-C₁₀ alkylamino-C₁-C₁₀ alkyl group; a di(C₁-C₁₀ alkyl)amino-C₁-C₁₀ alkyl group; a furyl-C₁-C₁₀ alkyl group; a thienyl-C₁-C₁₀ alkyl group; a C₁-C₁₀ alkylamino group; a di(C₁-C₁₀ alkyl)amino group;
-N=CH(C₁-C₁₀ alkyl) group;

group;
or a phenyl group optionally substituted with at least one member selected from the group consisting of (C₁-C₆ alkoxy)carbonyl groups, halogen atoms and C₁-C₆ alkyl groups; or a phenyl-C₁-C₆ alkyl group optionally substituted with at least one member selected from the group consisting of (C₁-C₆ alkoxy)carbonyl groups, halogen atoms and C₁-C₆ alkyl groups);
or a group represented by the formula,

(wherein each of R⁸ and R⁹, which may be the same or different, represents a hydrogen atom; a C₁-C₆ alkyl group; a C₂-C₆ alkenyl group; a C₂-C₆ alkynyl group; a halo-C₁-C₆ alkyl group; a halo-C₂-C₆ alkenyl group; a halo-C₂-C₆ alkynyl group; a C₃-C₆ cycloalkyl group; a C₃-C₆ cycloalkenyl group; an amino group; a C₁-C₆ alkylamino group; a di(C₁-C₆ alkyl)amino group; or a phenyl group optionally substituted with at least one member selected from the group consisting of halogen atoms and C₁-C₆ alkyl groups; or a phenyl-C₁-C₆ alkyl group optionally substituted with at least one member selected from the group consisting of halogen atoms and C₁-C₆ alkyl groups),
   X represents CH or a nitrogen atom, a method for producing the same and their use as herbicides.
The N-acyldihydroquinoline derivatives have herbicidal activity and selectivity between crops and weeds and therefore, can be used as an active ingredient for herbicides.

摘要翻译： 由式（I）表示的新型N-酰基二氢喹啉衍生物，其中R 1，R 2和R 3各自可以相同或不同，表示氢原子; 卤素原子; C1-C6烷基; C1-C6烷氧基; 卤代-C 1 -C 6烷基; 卤代-C 1 -C 6烷氧基; （C1-C6烷氧基）羰基; C1-C6烷硫基; C1-C6烷基氨基; 二（C1-C6烷基）氨基; 苯基; 或苯氧基，R 4和R 5各自可以相同或不同，表示氢原子或C1-C6烷基，或R 4和R 5结合在一起 在其末端形成C 2 -C 5亚烷基，R 6表示氢原子; 卤素原子; 氨基; C1-C6烷基氨基; 二（C1-C6烷基）氨基; （C1-C6烷氧基）羰基氨基; 氰基; 或由式-C（= O）-YR 7表示的基团（其中Y表示氧原子或硫原子，R 7表示氢原子; C1-C10烷基; C2- C10链烯基; C2-C10炔基;卤代-C1-C10烷基;卤代-C2-C10烯基;卤代-C2-C10炔基; C3-C10环烷基; C3-C10环烯基 C1-C10烷氧基-C1-C10烷基; C1-C10烷基氨基-C1-C10烷基;二（C1-C10烷基）氨基-C1-C10烷基;呋喃基-C1-C10烷基 ; C 1 -C 10烷基; C 1 -C 10烷基氨基;二（C 1 -C 10烷基）氨基; -N = CH（C 1 -C 10烷基）基团; CHEM基团;或任选地 被选自（C1-C6烷氧基）羰基，卤素原子和C1-C6烷基的至少一个成员取代的苯基-C 1 -C 6烷基;或任选被至少一个选自 由（C 1 -C 6烷氧基）羰基，卤素原子和C 1 -C 6烷基组成）; 或由式表示的基团（其中R 8和R 9各自可以相同或不同，表示氢原子; C 1 -C 6烷基; C 2 -C 6烯基 基团; C 2 -C 6炔基; C 1 -C 6环烷基; C 3 -C 6环烯基; C 3 -C 6环烷基; C 3 -C 6环烷基; C 3 -C 6环烷基; 氨基; C1-C6烷基氨基;二（C1-C6烷基）氨基;或任选被至少一个选自卤素原子和C 1 -C 6烷基的成员取代的苯基;或 苯基-C 1 -C 6烷基，任选被至少一个选自卤素原子和C 1 -C 6烷基的成员取代），X代表CH或氮原子，其制备方法及其作为除草剂的用途。 N-酰基二氢喹啉衍生物在作物和杂草之间具有除草活性和选择性，因此可用作除草剂的活性成分。

公开(公告)号：EP0469711A1

公开(公告)日：1992-02-05

申请号：EP91305672.7

申请日：1991-06-24

申请人： SUMITOMO CHEMICAL COMPANY, LIMITED

发明人： Hiratsuka, Mitsunori ,  Hirata, Naonori ,  Saitoh, Kazuo ,  Shibata, Hideyuki

IPC分类号： C07D239/60 ,  C07D239/34 ,  C07D239/38 ,  C07D401/12 ,  A01N43/54 ,  C07D413/12 ,  C07D413/14

CPC分类号： C07D401/12 ,  A01N43/54 ,  A01N47/24 ,  C07D239/60 ,  C07D401/14 ,  C07D413/10 ,  C07D413/14

摘要： A pyrimidine derivative has the formula,
wherein each of R 1 and R 2 , which may be the same or different, is C 1 -C 6 alkyl, C 1 -C 6 alkoxy, halo C 1 -C 6 alkoxy or halogen;

R 3 is hydrogen, C 1 -C 6 alkyl, phenyl or phenyl substituted with at least one member selected from the group consisting of C 1 -C 6 alkyl, C 1 -C 6 alkoxy, halo C 1 -C 6 alkyl, C 1 -C 6 alkoxycarbonyl, nitro and halogen;
each of R 4 and R 5 , which may be the same or different, is hydrogen, C 1 -C 6 alkyl, halo C 1 -C 6 alkyl, phenyl, phenyl substituted with at least one member selected from the group consisting of C 1 -C 6 alkyl, C 1 -C 6 alkoxy, halo C 1 -C 6 alkyl, C 1 -C 6 alkoxycarbonyl, nitro and halogen, benzyl, pyridyl, pyridyl substituted with at least one member selected from the group consisting of Ci-C 6 alkyl, Ci-C 6 alkoxy, halo Ci-C 6 alkyl, Ci-C 6 alkoxycarbonyl, nitro and halogen, quinolinyl, quinolinyl substituted with at least one member selected from the group consisting of C 1 -C 6 alkyl, C 1 -C 6 alkoxy, halo C 1 -C 6 alkyl, C 1 -C 6 alkoxycarbonyl, nitro and halogen, C 1 -C 6 alkylcarbonyl, C 1 -C 6 alkoxycarbonyl, and
wherein A 1 is C 4 -C 7 alkylene, C 4 -C 7 alkylene substituted with C 1 -C 6 alkyl, a group of the formula, -(CH 2 ) q -A 2- (CH 2 ) r -,
wherein A 2 is S, O,
wherein R 9 is hydrogen, C 1 -C 6 alkyl, q and r are integers and satisfy the criteria, 3 ≦ q + r ≦ 6, q ≧ 1, r ≧ 1, or a group of the formula,
-(CR 2 ) q -A 2 -(CH 2 ) r -,
substituted with C 1 -C 6 alkyl wherein q, r and A 2 are as defined above; or a group of the formula,
wherein A is C 2 -C 4 alkylene or C 2 -C 4 alkylene substituted with C 1 -C 6 alkyl, or a group of the formula,
wherein A is as defined above;
X is oxygen or sulfur;
Z is nitrogen or CY 4 ;
each of Y 1 , Y 2 and Y 3 , which may be the same or different, is hydrogen, halogen, C 1 -C 6 alkyl or C 1 -C 6 alkoxy; and
Y 4 is hydrogen, hydroxyl, mercapto, nitro, halogen, C 1 -C 6 alkyl, C 2 -C 6 alkenyl, C 2 -C 6 alkynyl, C 1 -C 6 alkoxy, C 3 -C 6 alkenyloxy, C 3 -C 6 alkynyloxy, halo C 1 -C 6 alkyl, halo C 2 -C 6 alkenyl, halo C 2 -C 6 alkynyl, halo C 1 -C 6 alkoxy, halo C 3 -C 6 alkenyloxy, halo C 3 -C 6 alkynyloxy, C 1 -C 6 alkoxy C 1 -C 6 alkyl, C 3 -C 6 alkenyloxy C 1 -C 6 alkyl,C 3 -C 6 alkynyloxy C 1 -C 6 alkyl, cyano, formyl, carboxyl, C 1 -C 6 alkoxycarbonyl, C 3 -C 6 alkenyloxycarbonyl, C 3 -C 6 alkynyloxycarbonyl, phenyl, phenyl substituted with at least one member selected from the group consisting of C 1 -C 6 alkyl, C 1 -C 6 alkoxy, halo C 1 -C 6 alkyl, C 1 -C 6 alkoxycarbonyl and halogen, phenoxy, phenoxy substituted with at least one member selected from the group consisting of C 1 -C 6 alkyl, C 1 -C 6 alkoxy, halo C 1 -C 6 alkyl, C 1 -C 6 alkoxycarbonyl and halogen, phenylthio, phenylthio substituted with at least one member selected from the group consisting of C 1 -C 6 alkyl, C 1 -C 6 alkoxy, halo C 1 -C 6 alkyl, C 1 -C 6 alkoxycarbonyl and halogen, benzyloxy, benzyloxy substituted with at least one member selected from the group consisting of C 1 -C 6 alkyl, C 1 -C 6 alkoxy, halo C 1 -C 6 alkyl, C 1 -C 6 alkoxycarbonyl and halogen, benzylthio, benzylthio substituted with at least one member selected from the group consisting of C 1 -C 6 alkyl, C 1 -C 6 alkoxy, halo C 1 -C 6 alkyl, C 1 -C 6 alkoxycarbonyl and halogen,

wherein each of R 8 and R 6 , which may be the same or different, is hydrogen, C 1 -C 6 alkyl, C 3 -C 6 alkenyl or C 3 -C 6 alkynyl,

wherein R 8 and R 6 are as defined above,

wherein R 7 is C 1 -C 6 alkyl, C 3 -C 6 alkenyl or C 3 -C 6 alkynyl and m is an integer of 0, 1 or 2,

wherein X 1 is oxygen or sulfur, and R 7 is as defined above, or

wherein R 7 and m are as defined above, and n is an integer from 1 to 4.

摘要翻译： 嘧啶衍生物具有下式其中R1和R2可以相同或不同，为C1-C6烷基，C1-C6烷氧基，卤代C1-C6烷氧基或卤素; R 3是氢，C 1 -C 6烷基，苯基或被至少一个选自C 1 -C 6烷基，C 1 -C 6烷氧基，卤代C 1 -C 6烷基，C 1 -C 6烷氧基羰基，硝基和卤素的成员取代的苯基; 每个R 4和R 5可以相同或不同，为氢，C 1 -C 6烷基，卤代C 1 -C 6烷基，苯基，被至少一个选自C 1 -C 6烷基，C 1 -C 6烷基， C 1 -C 6烷氧基，卤代C 1 -C 6烷基，C 1 -C 6烷氧基羰基，硝基和卤素，苄基，吡啶基，被至少一个选自C 1 -C 6烷基，C 1 -C 6烷氧基， C 1 -C 6烷氧基，卤代C 1 -C 6烷基，C 1 -C 6烷氧基羰基，硝基和卤素中的至少一个取代的C 1 -C 6烷氧基羰基，硝基和卤素，喹啉基，喹啉基， C 1 -C 6烷基羰基，C 1 -C 6烷氧基羰基，并且其中A 1是C 4 -C 7亚烷基，被C 1 -C 6烷基取代的C 4 -C 7亚烷基，式 - （CH 2）q -A 2 - （CH 2）r - 其中A2是S，O，其中R9是氢，C1-C6烷基，q和r是整数且满足标准，3≤q+r≤6，q≥1，r≥1或式 - （CR 2）q -A 2 - （CH 2）r - ，s 用C1-C6烷基取代，其中q，r和A2如上所定义; 或下式的基团，其中A是C2-C4亚烷基或被C1-C6烷基取代的C2-C4亚烷基，或下式的基团，其中A如上所定义; X是氧或硫; Z是氮或CY4; Y1，Y2和Y3中的每一个可以相同或不同，为氢，卤素，C1-C6烷基或C1-C6烷氧基; 羟基，巯基，硝基，卤素，C 1 -C 6烷基，C 2 -C 6烯基，C 2 -C 6炔基，C 1 -C 6烷氧基，C 3 -C 6烯氧基，C 3 -C 6炔氧基，卤代C 1 -C 6烷基，卤代 卤代C 1 -C 6烷氧基，卤代C 3 -C 6烯氧基，卤代C 3 -C 6炔氧基，C 1 -C 6烷氧基C 1 -C 6烷基，C 3 -C 6烯氧基C 1 -C 6烷基，C 3 -C 6烯基 炔氧基C 1 -C 6烷基，氰基，甲酰基，羧基，C 1 -C 6烷氧基羰基，C 3 -C 6烯氧基羰基，C 3 -C 6炔基氧基羰基，苯基，被至少一个选自C 1 -C 6烷基， 烷氧基，卤代C 1 -C 6烷基，C 1 -C 6烷氧基羰基和卤素，苯氧基，被至少一个选自C 1 -C 6烷基，C 1 -C 6烷氧基，卤代C 1 -C 6烷基，C 1 -C 6烷氧基羰基 和被选自C1-C6烷基，C1-C6烷氧基，卤代C1-C6烷基，C1-C6烷氧羰基和卤素中的至少一员取代的苯硫基，苯硫基，苯硫基，苄氧基，苄氧基亚氨基 用至少一个选自C1-C6烷基，C1-C6烷氧基，卤代C1-C6烷基，C1-C6烷氧基羰基和卤素的苄基硫基，被至少一个选自下列基团的基团取代： C 1 -C 6烷基，C 1 -C 6烷氧基，卤代C 1 -C 6烷基，C 1 -C 6烷氧基羰基和卤素，其中R 8和R 6可以相同或不同，为氢，C 1 -C 6烷基， 或C 3 -C 6炔基，其中R 8和R 6如上所定义，其中R 7是C 1 -C 6烷基，C 3 -C 6烯基或C 3 -C 6炔基，m是0,1或2的整数，其中X 1是氧或硫 ，并且R 7如上所定义，或者其中R 7和m如上所定义，并且n是1至4的整数。