公开(公告)号：EP3768420A1

公开(公告)日：2021-01-27

申请号：EP19712184.1

申请日：2019-03-19

Applicant: Shell Internationale Research Maatschappij B.V.

Inventor： MEEUWISSEN, Jurjen ,  STOBBE, Erwin Roderick

IPC: B01J23/75

公开(公告)号：EP2519605B1

公开(公告)日：2015-01-21

申请号：EP10795398.6

申请日：2010-12-22

Applicant: Shell Internationale Research Maatschappij B.V.

Inventor： BOS, Alouisius Nicolaas Renée ,  VAN DEN BRINK, Peter John ,  REMANS, Thomas Joris ,  STOBBE, Erwin Roderick ,  UNRUH, Dominik Johannes Michael ,  WISMAN, Ronald Vladimir

IPC: C10G2/00 ,  C07C1/04 ,  B01J8/06

CPC classification number: B01J8/06 ,  B01J2208/00017 ,  B01J2208/00663 ,  B01J2208/00672 ,  B01J2208/00681 ,  B01J2208/025 ,  C10G2/341

公开(公告)号：EP2519605A1

公开(公告)日：2012-11-07

申请号：EP10795398.6

申请日：2010-12-22

Applicant: Shell Internationale Research Maatschappij B.V.

Inventor： BOS, Alouisius Nicolaas Renée ,  VAN DEN BRINK, Peter John ,  REMANS, Thomas Joris ,  STOBBE, Erwin Roderick ,  UNRUH, Dominik Johannes Michael ,  WISMAN, Ronald Vladimir

IPC: C10G2/00 ,  C07C1/04 ,  B01J8/06

CPC classification number: B01J8/06 ,  B01J2208/00017 ,  B01J2208/00663 ,  B01J2208/00672 ,  B01J2208/00681 ,  B01J2208/025 ,  C10G2/341

Abstract: The present invention pertains to a reactor tube comprising a fixed bed of Fischer-Tropsch catalyst particles, wherein the catalyst particles in 5% to 40% of the fixed bed volume at the upstream end have an average outer surface to volume ratio (S/V) in the range of between 3.0 to 4.5 mm
-1 , and the catalyst particles in the remaining fixed bed volume have an average outer surface to volume ratio (S/V) in the range of between 4.5 to 8.0 mm
-1 , and wherein the difference between the average S/V of the particles at the upstream end and the average S/V of the particles in the remaining fixed bed volume is at least 0.5 mm
-1 .

公开(公告)号：EP2367630A1

公开(公告)日：2011-09-28

申请号：EP09775199.4

申请日：2009-12-16

Applicant: Shell Internationale Research Maatschappij B.V.

Inventor： BEZEMER, Gerrit Leendert ,  NKRUMAH, Stephen ,  OOSTERBEEK, Heiko ,  STOBBE, Erwin Roderick

IPC: B01J23/00 ,  B01J23/40 ,  B01J31/00 ,  B01J38/64 ,  B01J38/66 ,  C07C27/00 ,  C07C27/06 ,  C10G2/00

CPC classification number: B01J31/403 ,  B01J23/75 ,  B01J38/02 ,  B01J38/10 ,  B01J38/66 ,  B01J2531/845 ,  C10G2/332 ,  C10G2300/70

Abstract: A process for regenerating one or more deactivated cobalt comprising Fischer-Tropsch catalyst particle (s)
in situ in a reactor tube, said process comprising the steps of : (i) oxidising the catalyst particle(s) at a temperature between 20 and 400 °C; (ii) treating the catalyst particle (s) for more than 5 minutes with a solvent, (iii) drying the catalyst particle (s); and (iv) optionally reducing the catalyst with hydrogen or a hydrogen comprising gas. This process may be preceded by a step in which Fischer-Tropsch product is removed from the catalyst particle(s).

公开(公告)号：EP3233764B1

公开(公告)日：2020-01-29

申请号：EP15820134.3

申请日：2015-12-21

Applicant: Shell Internationale Research Maatschappij B.V.

Inventor： KLEMT, Andreas ,  DOMOKOS, László ,  FRIEDEL, Frank ,  BOETTCHER, Stefan ,  STOBBE, Erwin Roderick

IPC: C07C1/02 ,  C10G2/00 ,  B01J23/74 ,  B01J23/745 ,  B01J23/75 ,  B01J23/889 ,  B01J37/04 ,  B01J37/16 ,  B01J37/08 ,  B01J37/00 ,  C07C1/04 ,  C07C1/10

公开(公告)号：EP3024573A1

公开(公告)日：2016-06-01

申请号：EP14739804.4

申请日：2014-07-14

Applicant: Shell Internationale Research Maatschappij B.V.

Inventor： BEZEMER, Gerrit Leendert ,  STOBBE, Erwin Roderick

IPC: B01J21/06 ,  B01J27/13 ,  B01J27/128 ,  B01J37/04 ,  B01J35/02 ,  C07C1/00 ,  C10G2/00 ,  B01J37/24

CPC classification number: B01J27/135 ,  B01J21/063 ,  B01J23/8892 ,  B01J27/128 ,  B01J27/13 ,  B01J35/023 ,  B01J37/0009 ,  B01J37/0018 ,  B01J37/0201 ,  B01J37/0236 ,  B01J37/08 ,  B01J37/18 ,  B01J37/24 ,  C10G2/332

Abstract: The invention concerns a process for preparing a chlorine comprising catalyst using one or more metal salts of chloride, hydrochloric acid (HCl), one or more organic chloride compounds, or a combination thereof. The prepared catalyst preferably comprises 0.13 –3weight percent of the element chlorine. The invention further relates to the prepared catalyst and its use.

公开(公告)号：EP3024576A1

公开(公告)日：2016-06-01

申请号：EP14738844.1

申请日：2014-07-14

Applicant: Shell Internationale Research Maatschappij B.V.

Inventor： STOBBE, Erwin Roderick ,  BEZEMER, Gerrit Leendert ,  VAN DEN BRINK, Peter John ,  VAN BAVEL, Alexander Petrus

IPC: B01J23/889 ,  B01J21/06 ,  B01J23/75 ,  C10G2/00 ,  B01J27/10

CPC classification number: C10G2/332 ,  B01J21/063 ,  B01J23/8892 ,  B01J23/8896 ,  B01J27/128 ,  B01J27/135 ,  B01J37/0201 ,  B01J37/18 ,  B01J37/24 ,  C10G2/341 ,  C10G2300/4031

Abstract: The invention relates to a method to start up a Fischer-Tropsch process. A catalyst with a latent activity is used. The catalyst comprises titania, cobalt, promoter, and chlorine. The catalyst comprises more than 0.7 and less than 4 weight percent of the element chlorine, calculated on the total weight of the catalyst.

Abstract translation: 本发明涉及一种启动费 - 托方法。 使用具有潜在活性的催化剂。 催化剂包括二氧化钛，钴，助催化剂和氯。 根据催化剂的总重量，催化剂含有大于0.7且小于4重量％的元素氯。

公开(公告)号：EP3024576B1

公开(公告)日：2019-03-27

申请号：EP14738844.1

申请日：2014-07-14

Applicant: Shell Internationale Research Maatschappij B.V.

Inventor： STOBBE, Erwin Roderick ,  BEZEMER, Gerrit Leendert ,  VAN DEN BRINK, Peter John ,  VAN BAVEL, Alexander Petrus

IPC: B01J23/889 ,  B01J37/18 ,  B01J37/24 ,  C10G2/00 ,  B01J27/128 ,  B01J27/135 ,  B01J37/02 ,  B01J21/06

公开(公告)号：EP3233764A1

公开(公告)日：2017-10-25

申请号：EP15820134.3

申请日：2015-12-21

Applicant: Shell Internationale Research Maatschappij B.V.

Inventor： KLEMT, Andreas ,  DOMOKOS, László ,  FRIEDEL, Frank ,  BOETTCHER, Stefan ,  STOBBE, Erwin Roderick

IPC: C07C1/02 ,  C10G2/00 ,  B01J23/74 ,  B01J23/745 ,  B01J23/75 ,  B01J23/889 ,  B01J37/04 ,  B01J37/16 ,  B01J37/08 ,  B01J37/00 ,  C07C1/04 ,  C07C1/10

CPC classification number: B01J23/8892 ,  B01J23/74 ,  B01J23/745 ,  B01J23/75 ,  B01J35/023 ,  B01J37/0072 ,  B01J37/009 ,  B01J37/0236 ,  B01J37/035 ,  B01J37/04 ,  B01J37/06 ,  B01J37/08 ,  B01J37/088 ,  B01J37/16 ,  C10G2/332

Abstract: The invention relates to a method for preparing a catalyst or catalyst precursor comprising a catalytically active material and a carrier material. The invention relates to a catalyst particle and catalyst precursor thereof obtainable by said method. The catalyst may be used in a process for synthesising hydrocarbons.

Abstract translation: 本发明涉及制备包含催化活性材料和载体材料的催化剂或催化剂前体的方法。 本发明涉及可通过所述方法获得的催化剂颗粒及其催化剂前体。 该催化剂可以用于合成烃的方法中。

公开(公告)号：EP3024577A1

公开(公告)日：2016-06-01

申请号：EP14739153.6

申请日：2014-07-14

Applicant: Shell Internationale Research Maatschappij B.V.

Inventor： VAN BAVEL, Alexander Petrus ,  BEZEMER, Gerrit Leendert ,  VAN DEN BRINK, Peter John ,  STOBBE, Erwin Roderick

IPC: B01J27/10 ,  B01J27/138 ,  B01J37/00 ,  B01J37/04 ,  B01J37/24

CPC classification number: B01J27/135 ,  B01J23/8892 ,  B01J23/8896 ,  B01J27/10 ,  B01J27/138 ,  B01J35/023 ,  B01J37/0009 ,  B01J37/0201 ,  B01J37/04 ,  B01J37/08 ,  B01J37/24 ,  C07C1/0435 ,  C07C11/10 ,  C07C2521/06 ,  C07C2523/34 ,  C07C2523/75 ,  C07C2523/889 ,  C10G2/332 ,  C07C9/14

Abstract: The invention concerns a process for preparing a chlorine comprising catalyst by (a) providing a Fischer-Tropsch catalyst comprising titania and at least 5 weight percent cobalt; (b) impregnating the catalyst with a solution comprising chloride ions;and (c) heating the impregnated catalyst at a temperature in the range of between 100 and 500 °C for at least 5 minutes up to 2 days. The prepared catalyst preferably comprises 0.13 –3 weight percent of the element chlorine. The invention further relates to the prepared catalyst and its use.

Abstract translation: 本发明涉及用于制备氯通过（a）提供一个费 - 托催化剂，其包含二氧化钛和至少5％重量的钴包含催化剂的方法; （B）含浸溶液，其包含氯离子的催化剂; 和（c）在100℃。500℃之间的范围内的温度下加热浸渍过的催化剂的至少5分钟至2天。 所制备的催化剂优选包含0.13-3重量％的元素氯。 本发明还涉及到制备的催化剂和其使用。