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公开(公告)号：EP3195932A1
公开(公告)日：2017-07-26
申请号：EP15831768.5
申请日：2015-08-12
发明人： NAGASHIMA, Hideo , SUNADA, Yusuke , TAHARA, Atsushi , NODA, Daisuke , SOEJIMA, Hiroe , SAKUTA, Koji
CPC分类号： C07F7/0879 , B01J31/1805 , B01J31/22 , B01J31/2208 , B01J31/2226 , B01J31/2273 , B01J2231/323 , B01J2531/821 , B01J2531/842 , B01J2531/845 , B01J2531/847 , C07B61/00 , C07F7/08
摘要： A hydrosilylation reaction catalyst prepared from: a catalyst precursor comprising a transition metal compound, excluding platinum, belonging to group 8-10 of the periodic table, e.g., iron acetate, cobalt acetate, nickel acetate, etc.; and a ligand comprising an isocyanide compound such as t-butyl isocyanide. The hydrosilylation reaction catalyst has excellent handling and storage properties. As a result of using this catalyst, a hydrosilylation reaction can be promoted under gentle conditions.
摘要翻译： 一种氢化硅烷化反应催化剂，其由包含属于元素周期表第8-10族的除铂之外的过渡金属化合物如乙酸铁，乙酸钴，乙酸镍等的催化剂前体制备。 和包含异氰化物化合物如叔丁基异氰化物的配体。 氢化硅烷化反应催化剂具有优异的处理和储存性能。 作为使用该催化剂的结果，可以在温和条件下促进氢化硅烷化反应。
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2.发明公开MONONUCLEAR IRON COMPLEX AND ORGANIC SYNTHESIS REACTION USING SAME 有权MONONUKLEARER EISENKOMPLEX UND ORGANISCHE SYNTHESEREAKENEN UNTER DESSEN VERWENDUNG
公开(公告)号：EP2963047A1
公开(公告)日：2016-01-06
申请号：EP14757365.3
申请日：2014-02-26
IPC分类号： C07F19/00 , B01J31/22 , C07C5/03 , C07C9/16 , C07C13/10 , C07C13/18 , C07C15/073 , C07C15/18 , C07C29/14 , C07C29/143 , C07C29/147 , C07C31/135 , C07C33/20 , C07C41/26 , C07C43/23 , C07C209/50 , C07C211/27 , C07C211/29 , C07C213/00 , C07C217/58
CPC分类号： B01J31/1608 , B01J31/20 , B01J31/226 , B01J2231/323 , B01J2231/643 , B01J2231/645 , B01J2531/842 , C07C5/03 , C07C29/14 , C07C29/147 , C07C41/18 , C07C41/26 , C07C209/50 , C07C213/00 , C07C213/02 , C07C227/06 , C07C227/16 , C07C227/18 , C07C2531/16 , C07C2531/20 , C07C2531/22 , C07C2601/08 , C07C2601/14 , C07D223/04 , C07F7/0805 , C07F7/0829 , C07F15/02 , Y02P20/52 , C07C43/23 , C07C9/16 , C07C13/18 , C07C13/10 , C07C15/073 , C07C15/18 , C07C211/29 , C07C211/27 , C07C217/58 , C07C229/38 , C07C33/20 , C07C31/1355
摘要： Provided is a mononuclear iron complex that comprises an iron-silicon bond that is represented by formula (1) and that exhibits excellent catalyst activity in each of a hydrosilylation reaction, a hydrogenation reaction, and reduction of a carbonyl compound.
In formula (1), R 1 -R 6 either independently represent an alkyl group, an aryl group, an aralkyl group or the like that may be substituted with a hydrogen atom or X, or represent a crosslinking substituent in which at least one pair comprising one of R 1 -R 3 and one of R 4 -R 6 is combined. X represents a halogen atom, an organoxy group, or the like. L represents a two-electron ligand other than CO. When a plurality of L are present, the plurality of L may be the same as or different from each other. When two L are present, the two L may be bonded to each other. n and m independently represent an integer of 1 to 3 with the stipulation that n+m equals 3 or 4.摘要翻译： 提供一种单核铁络合物，其包含由式（1）表示的铁 - 硅键，并且在氢化硅烷化反应，氢化反应和羰基化合物的还原中表现出优异的催化剂活性。 在式（1）中，R 1 -R 6独立地表示可被氢原子或X取代的烷基，芳基，芳烷基等，或表示交联取代基，其中至少一对 包括R 1 -R 3中的一个和R 4 -R 6中的一个组合。 X表示卤原子，有机氧基等。 L表示除CO以外的双电子配体，当存在多个L时，多个L可以彼此相同或不同。 当存在两个L时，两个L可以彼此结合。 n和m独立地表示1〜3的整数，并且n + m等于3或4。
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公开(公告)号：EP3118205B1
公开(公告)日：2020-04-22
申请号：EP15762299.4
申请日：2015-03-03
发明人： NAGASHIMA, Hideo , SUNADA, Yusuke , OGUSHI, Hajime , SAKUTA, Koji
IPC分类号： C07F19/00 , B01J31/22 , C07C5/03 , C07C9/15 , C07C15/073 , C07C209/50 , C07C211/04 , C07F7/08 , C07B61/00 , C07F15/00 , C07C67/303 , C07C69/42 , C07C69/38 , C07C69/612 , C07C15/00 , C07C15/18 , C07C9/16 , C07C13/48 , C07C13/465 , C07C211/00
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公开(公告)号：EP3406616A1
公开(公告)日：2018-11-28
申请号：EP17741439.8
申请日：2017-01-18
发明人： SAKUTA, Koji , NAGASHIMA, Hideo , SUNADA, Yusuke , NODA, Daisuke
摘要： Provided are a novel isocyanide compound, a hydrosilylation reaction catalyst having excellent handling properties and storage properties that allows a hydrosilylation reaction to proceed under moderate conditions by using the isocyanide compound, and a method for producing an addition compound by a hydrosilylation reaction using the hydrosilylation reaction catalyst.
A hydrosilylation reaction catalyst prepared from a catalyst precursor comprising a transition metal compound of groups 8, 9, or 10 of the periodic table, excluding platinum, such as an iron carboxylate, cobalt carboxylate, or nickel carboxylate, and a ligand comprising an isocyanide compound having an organosiloxane group.-
公开(公告)号：EP2963047B1
公开(公告)日：2018-11-14
申请号：EP14757365.3
申请日：2014-02-26
IPC分类号： B01J31/22 , C07C13/10 , C07C13/18 , C07C15/073 , C07C15/18 , C07C29/14 , C07C29/143 , C07C29/147 , C07C31/135 , C07C33/20 , C07C41/26 , C07C43/23 , C07C209/50 , C07C211/27 , C07C211/29 , C07C213/00 , C07C217/58 , B01J31/16 , B01J31/20 , C07C41/18 , C07F15/02
CPC分类号： B01J31/1608 , B01J31/20 , B01J31/226 , B01J2231/323 , B01J2231/643 , B01J2231/645 , B01J2531/842 , C07C5/03 , C07C29/14 , C07C29/147 , C07C41/18 , C07C41/26 , C07C209/50 , C07C213/00 , C07C213/02 , C07C227/06 , C07C227/16 , C07C227/18 , C07C2531/16 , C07C2531/20 , C07C2531/22 , C07C2601/08 , C07C2601/14 , C07D223/04 , C07F7/0805 , C07F7/0829 , C07F15/02 , Y02P20/52 , C07C43/23 , C07C9/16 , C07C13/18 , C07C13/10 , C07C15/073 , C07C15/18 , C07C211/29 , C07C211/27 , C07C217/58 , C07C229/38 , C07C33/20 , C07C31/1355
摘要： Provided is a mononuclear iron complex that comprises an iron-silicon bond that is represented by formula (1) and that exhibits excellent catalyst activity in each of a hydrosilylation reaction, a hydrogenation reaction, and reduction of a carbonyl compound. In formula (1), R 1 -R 6 either independently represent an alkyl group, an aryl group, an aralkyl group or the like that may be substituted with a hydrogen atom or X, or represent a crosslinking substituent in which at least one pair comprising one of R 1 -R 3 and one of R 4 -R 6 is combined. X represents a halogen atom, an organoxy group, or the like. L represents a two-electron ligand other than CO. When a plurality of L are present, the plurality of L may be the same as or different from each other. When two L are present, the two L may be bonded to each other. n and m independently represent an integer of 1 to 3 with the stipulation that n+m equals 3 or 4.
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公开(公告)号：EP2963046B1
公开(公告)日：2018-10-17
申请号：EP14756744.0
申请日：2014-02-26
IPC分类号： C07F19/00 , B01J31/22 , C07C5/03 , C07C9/16 , C07C13/10 , C07C13/18 , C07C15/073 , C07C15/18 , C07C209/50 , C07C211/27 , C07C211/29 , C07C213/00 , C07C217/58 , C07D223/04 , C07F7/08 , C07B61/00 , C07F15/00
CPC分类号： B01J31/1608 , B01J31/22 , B01J2231/323 , B01J2231/643 , B01J2231/645 , B01J2531/821 , C07C5/03 , C07C9/16 , C07C13/10 , C07C13/18 , C07C15/073 , C07C15/18 , C07C29/14 , C07C209/50 , C07C213/00 , C07C2531/16 , C07C2531/22 , C07C2531/28 , C07C2601/08 , C07C2601/14 , C07D223/04 , C07F7/08 , C07F15/0046 , C07C217/58 , C07C211/29 , C07C211/27 , C07C9/18
摘要： Provided is a mononuclear ruthenium complex that comprises a ruthenium-silicon bond that is represented by formula (1) and that exhibits excellent catalyst activity in each of a hydrosilylation reaction, a hydrogenation reaction, and reduction of a carbonyl compound. In formula (1), R 1 -R 6 either independently represent an alkyl group, an aryl group, an aralkyl group or the like that may be substituted with a hydrogen atom or X, or represent a crosslinking substituent in which at least one pair comprising one of R 1 -R 3 and one of R 4 -R 6 is combined. X represents a halogen atom, an organoxy group, or the like. L represents a two-electron ligand other than CO and phosphine. When a plurality of L are present, the plurality of L may be the same as or different from each other. When two L are present, the two L may be bonded to each other. n and m independently represent an integer of 1 to 3 with the stipulation that n+m equals 3 or 4.
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7.发明公开MONONUCLEAR RUTHENIUM COMPLEX AND ORGANIC SYNTHESIS REACTION USING SAME 审中-公开MONONUKLEARER RUTHENIUMKOMPLEX UND ORGANISCHE SYNTHESEREAKENEN UNTER DESSEN VERWENDUNG
公开(公告)号：EP2963046A1
公开(公告)日：2016-01-06
申请号：EP14756744.0
申请日：2014-02-26
IPC分类号： C07F19/00 , B01J31/22 , C07C5/03 , C07C9/16 , C07C13/10 , C07C13/18 , C07C15/073 , C07C15/18 , C07C209/50 , C07C211/27 , C07C211/29 , C07C213/00 , C07C217/58 , C07D223/04 , C07F7/08 , C07B61/00 , C07F15/00
CPC分类号： B01J31/1608 , B01J31/22 , B01J2231/323 , B01J2231/643 , B01J2231/645 , B01J2531/821 , C07C5/03 , C07C9/16 , C07C13/10 , C07C13/18 , C07C15/073 , C07C15/18 , C07C29/14 , C07C209/50 , C07C213/00 , C07C2531/16 , C07C2531/22 , C07C2531/28 , C07C2601/08 , C07C2601/14 , C07D223/04 , C07F7/08 , C07F15/0046 , C07C217/58 , C07C211/29 , C07C211/27 , C07C9/18
摘要： Provided is a mononuclear ruthenium complex that comprises a ruthenium-silicon bond that is represented by formula (1) and that exhibits excellent catalyst activity in each of a hydrosilylation reaction, a hydrogenation reaction, and reduction of a carbonyl compound.
In formula (1), R 1 -R 6 either independently represent an alkyl group, an aryl group, an aralkyl group or the like that may be substituted with a hydrogen atom or X, or represent a crosslinking substituent in which at least one pair comprising one of R 1 -R 3 and one of R 4 -R 6 is combined. X represents a halogen atom, an organoxy group, or the like. L represents a two-electron ligand other than CO and phosphine. When a plurality of L are present, the plurality of L may be the same as or different from each other. When two L are present, the two L may be bonded to each other. n and m independently represent an integer of 1 to 3 with the stipulation that n+m equals 3 or 4.摘要翻译： 提供了包含由式（1）表示的钌 - 硅键并且在氢化硅烷化反应，氢化反应和羰基化合物的还原中表现出优异的催化剂活性的单核钌络合物。 在式（1）中，R 1 -R 6独立地表示可被氢原子或X取代的烷基，芳基，芳烷基等，或表示交联取代基，其中至少一对 包括R 1 -R 3中的一个和R 4 -R 6中的一个组合。 X表示卤原子，有机氧基等。 L表示除CO和膦以外的双电子配体。 当存在多个L时，多个L可以彼此相同或不同。 当存在两个L时，两个L可以彼此结合。 n和m独立地表示1〜3的整数，并且n + m等于3或4。
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