SILICA GEL COMPOSITIONS CONTAINING ALKALI METALS AND ALKALI METAL ALLOYS
    5.
    发明公开
    SILICA GEL COMPOSITIONS CONTAINING ALKALI METALS AND ALKALI METAL ALLOYS 审中-公开
    碱金属和碱金属合金在含KIESELGELZUSAMMENSETZUNGEN

    公开(公告)号:EP1692075A2

    公开(公告)日:2006-08-23

    申请号:EP04811935.8

    申请日:2004-11-24

    IPC分类号: C01B3/00

    摘要: The invention relates to Group 1 metal/silica gel compositions comprising silica gel and an alkali metal or an alkali metal alloy. The compositions of the inventions are described as Stage 0, I, II, and III materials. These materials differ in their preparation and chemical reactivity. Each successive stage may be prepared directly using the methods described below or from an earlier stage material. Stage 0 materials may, for example, be prepared using liquid alloys of Na and K which are rapidly absorbed by silica gel (porous Si02) under isothermal conditions, preferably at or just above room temperature, to form loose black powders that retain much of the reducing ability of the parent metals. When the low melting Group 1 metals are absorbed into the silica gel, a mild exothermic reaction produces Stage I material, loose black powders that are indefinitely stable in dry air. Subsequent heating to 400°C produces Stage II materials, which are also loose black powders. Further heating above 400°C forms Stage III material with release of some Group 1 metal. It is believed that Stage I, II and III materials represent reductions of the silica gel after absorption of the Group 1 metal. Preferred Group 1 metal/silica gel compositions of the invention are those containing sodium, potassium, or sodium-potassium alloys with sodium and sodium- potassium alloys being most preferred. Each stage of the Group 1 metal/silica gel composition of the invention may be used as a reducing agent reacting with a number of reducible organic materials in the same manner known for alkali metals and their alloys.

    Solvent for chromogenic dye-precursors for pressure-sensitive recording papers.
    8.
    发明公开
    Solvent for chromogenic dye-precursors for pressure-sensitive recording papers. 失效
    LösungsmittelfürchromogeneFarbstoffvorläuferfürdruckempfindliche Aufzeichnungspapiere。

    公开(公告)号:EP0206699A1

    公开(公告)日:1986-12-30

    申请号:EP86304582

    申请日:1986-06-13

    摘要: A solvent for a chromogenic dye-precursor material for a pressure-sensitive recording paper comprises diarylalkanes, contains not less than 80% by weight of 1-tolyl-2-phenylpropane and 1,2-ditolyl-ethane, and has been obtained by subjecting ethylbenzene and xylene to coupling by side-chain dehydrogenation. Such a solvent is prepared by subjecting a mixture mixture of ethylbenzene and xylene to coupling by side-chain dehydrogenation at a temperature of not less than 100 DEG C in the presence of an aqueous solution of a peroxodisulfate and recovering from the reaction mixture the diarylalkanes thus produced as a mixture.

    摘要翻译: 用于压敏记录纸的显色染料前体材料的溶剂包括二芳基烷烃,含有不少于80重量%的1-甲苯基-2-苯基丙烷和1,2-二甲苯基乙烷,并且通过 乙苯和二甲苯通过侧链脱氢偶联。 这样的溶剂是通过使乙苯和二甲苯的混合物混合物在二氯乙酸的水溶液存在下,在不低于100℃的温度下通过侧链脱氢进行偶联反应,然后从反应混合物中回收二芳基烷烃 作为混合物生产。

    Verfahren zur dehydrierenden Dimerisierung und/oder Polymerisierung von organischen Verbindungen mit beweglichen Wasserstoffatomen unter Verwendung von Perketalen
    9.
    发明公开
    Verfahren zur dehydrierenden Dimerisierung und/oder Polymerisierung von organischen Verbindungen mit beweglichen Wasserstoffatomen unter Verwendung von Perketalen 失效
    一种用于脱氢二聚化和/或有机化合物的聚合使用过缩酮移动的氢原子的过程。

    公开(公告)号:EP0190720A1

    公开(公告)日:1986-08-13

    申请号:EP86101422.3

    申请日:1986-02-05

    申请人: Luperox GmbH

    IPC分类号: C07B37/04

    摘要: Organische Verbindungen mit beweglichem Wasserstoff an primären, sekundären oder tertiären C-Atomen (z.B. Isopropylbenzol) werden mittels Peroxyketale (z. B. 1, 1-Bis (t-butylperoxy)-cyclohexan, 2,2,-Bis(t-butylperoxy)-butani oder einer Kombination aus Perketalen und Di-t-butylperoxid unter drucklosen bedingungen in einer einfachen Apparatur zwischen z. B. 100°C und 180°C dimerisiert (z. B. zu Biscumyl) oder polymerisiert.

    摘要翻译: 1.一种用于二聚化脱氢和/或与在伯,仲,或叔碳原子移动氢的有机化合物其中,在大气压下,煮沸至少在95℃下和不含有任何酸性基团的聚合,与处理 使用过氧化物作为脱氢剂和不加压条件下,在从下方到略高于化合物的沸点待脱氢的温度,但高于过氧化物的服务中作为脱氢剂装置,包括可加热的反应器中的分解温度和 回流冷凝器连接到其上,通过使用一个或多个二(烷基过氧)缩酮和/或以10小时的小于115度C(确定性开采苯)的组合或半衰期温度(aralkylperoxy)缩酮为特征的 一个或多个所述的与过氧化二叔丁基过缩酮,并蒸掉挥发性过氧化物分解产物和二叔丁基对任选的一部分 通过降除回流冷凝器提供冷凝器eroxide。