摘要:
A neutral or cationic mononuclear ruthenium divalent complex represented by formula (1) can actualize exceptional catalytic activity in at least one reaction among a hydrosilylation reaction, hydrogenation reaction, and carbonyl compound reduction reaction. (In the formula, R 1 -R 6 each independently represent a hydrogen atom or an alkyl group, aryl group, aralkyl group, organooxy group, monoorganoamino group, diorganoamino group, monoorganophosphino group, diorganophosphino group, monoorganosilyl group, diorganosilyl group, triorganosilyl group, or organothio group optionally substituted by X; at least one pair comprising any of R 1 -R 3 and any of R 4 -R 6 together represents a crosslinkable substituent; X represents a halogen atom, organooxy group, monoorganoamino group, diorganoamino group, or organothio group; L each independently represent a two-electron ligand other than CO and thiourea ligands; two L may bond to each other; and m represents an integer of 3 or 4.)
摘要:
An object is to provide a process for providing hydrogen or heavy hydrogens conveniently without the necessity of large-scale equipment and a process capable of performing hydrogenation (protiation, deuteration or tritiation) reaction conveniently without the use of an expensive reagent and a special catalyst. The production process includes a process for producing hydrogen or heavy hydrogens, containing subjecting water or heavy water to mechanochemical reaction in the presence of a catalyst metal, and a process for producing a hydrogenated (protiated, deuterated or tritiated) organic compound, containing subjecting an organic compound and water or heavy water to mechanochemical reaction in the presence of a catalyst metal.
摘要:
Composition having an organic semiconducting material and a triplet-accepting material of formula (I) with a triplet energy level lower than the triplet energy level of the organic semiconducting material, in which each Ar is optionally substituted aryl or heteroaryl group, n is 1-3, m is 1-5, q is 0 or 1, each R3 is H or a substituent, and each R4 is H or a substituent. Where R4 is not H, R4 and (Ar)m bound to the same carbon atom may be linked by a direct bond or a divalent group. Where n or m is at least 2, adjacent Ar groups may be linked by a divalent group. Where q=0, R3 is not H and is linked to (Ar)n by a direct bond or a divalent group.
摘要:
The invention relates to Group 1 metal/silica gel compositions comprising silica gel and an alkali metal or an alkali metal alloy. The compositions of the inventions are described as Stage 0, I, II, and III materials. These materials differ in their preparation and chemical reactivity. Each successive stage may be prepared directly using the methods described below or from an earlier stage material. Stage 0 materials may, for example, be prepared using liquid alloys of Na and K which are rapidly absorbed by silica gel (porous Si02) under isothermal conditions, preferably at or just above room temperature, to form loose black powders that retain much of the reducing ability of the parent metals. When the low melting Group 1 metals are absorbed into the silica gel, a mild exothermic reaction produces Stage I material, loose black powders that are indefinitely stable in dry air. Subsequent heating to 400°C produces Stage II materials, which are also loose black powders. Further heating above 400°C forms Stage III material with release of some Group 1 metal. It is believed that Stage I, II and III materials represent reductions of the silica gel after absorption of the Group 1 metal. Preferred Group 1 metal/silica gel compositions of the invention are those containing sodium, potassium, or sodium-potassium alloys with sodium and sodium- potassium alloys being most preferred. Each stage of the Group 1 metal/silica gel composition of the invention may be used as a reducing agent reacting with a number of reducible organic materials in the same manner known for alkali metals and their alloys.
摘要:
1,2-Di(4-isobutylphenyl)hydrocarbons represented by the following formula (I): wherein the symbol .... represents either a carbon-carbon single bond or a carbon-carbon double bond, are prepared by reacting ethylene with a iodonium salt represented by wherein X⊖ is a counter ion which is inert to said reaction. The compounds of formula (1) can be converted in 4-isobutylstyrene, which can be converted to α-(4-isobutylphenel)propionic acid.
摘要:
1,2-Di(4-isobutylphenyl)hydrocarbons represented by the following formula (I): wherein the symbol .... represents either a carbon-carbon single bond or a carbon-carbon double bond, are prepared by reacting ethylene with a iodonium salt represented by wherein X⊖ is a counter ion which is inert to said reaction. The compounds of formula (1) can be converted in 4-isobutylstyrene, which can be converted to α-(4-isobutylphenel)propionic acid.
摘要:
A solvent for a chromogenic dye-precursor material for a pressure-sensitive recording paper comprises diarylalkanes, contains not less than 80% by weight of 1-tolyl-2-phenylpropane and 1,2-ditolyl-ethane, and has been obtained by subjecting ethylbenzene and xylene to coupling by side-chain dehydrogenation. Such a solvent is prepared by subjecting a mixture mixture of ethylbenzene and xylene to coupling by side-chain dehydrogenation at a temperature of not less than 100 DEG C in the presence of an aqueous solution of a peroxodisulfate and recovering from the reaction mixture the diarylalkanes thus produced as a mixture.
摘要:
Organische Verbindungen mit beweglichem Wasserstoff an primären, sekundären oder tertiären C-Atomen (z.B. Isopropylbenzol) werden mittels Peroxyketale (z. B. 1, 1-Bis (t-butylperoxy)-cyclohexan, 2,2,-Bis(t-butylperoxy)-butani oder einer Kombination aus Perketalen und Di-t-butylperoxid unter drucklosen bedingungen in einer einfachen Apparatur zwischen z. B. 100°C und 180°C dimerisiert (z. B. zu Biscumyl) oder polymerisiert.
摘要:
The invention relates to a method for producing particles containing at least one metal species with the aid of an eutectic solvent mixture, to carbon particles that are produced accordingly and contain at least one metal species, to a method for hydrogenating at least one hydrogenation compound, to a method for cross-coupling aryl halides or vinyl halides and terminal alkynes, and to a method for producing metal particles, metal complex particles, metal oxide particles and/or metal mixed oxide particles.