摘要:
A problem to be solved is to enhance the charge and discharge characteristics and rate characteristics of a B-type titanium oxide (TiO 2 (B)) powder by a simple treatment and to provide a B-type titanium oxide powder that can be suitably used as a negative electrode material for a lithium ion battery. A B-type titanium oxide powder is allowed to undergo a reaction under a fluorine-containing gas atmosphere at 0°C to 200°C for 1 minute to 10 days to obtain a surface-fluorinated B-type titanium oxide powder. It is preferred that the fluorination treatment is performed at 0.01 atm to 2 atm. It is preferred that a gas containing a fluorine compound selected from a fluorine (F 2 ) gas, a nitrogen trifluoride (NF 3 ) gas, a perfluorotrimethylamine (N(CF 3 ) 3 ) gas, a chlorine trifluoride (ClF 3 ) gas and the like is used as the fluorine-containing gas.
摘要:
A surface treatment apparatus 100 includes a diluent gas supplier 1, a fluorine gas supplier 2, a mixer 5 which mixes a diluent gas with a fluorine gas, and a reactor 6 which treats a treatment target by using a mixed gas generated by the mixer 5. A diluent gas supplied from a diluent gas supplier is heated by a heater 8, and the heated diluent gas is mixed with a fluorine gas supplied from a fluorine gas supplier, in the mixer 5. The mixed gas is supplied to the reactor 6. The gas in the reactor 6 is supplied from the reactor 6 to flow paths 219, 220, 221, and 222 by an exhauster 207. The valves 223, 224, 225, and 226 are serially opened, so that the gas in the reactor 6 is supplied to a harm removal apparatus 208 while the gas flow rate is being adjusted by the flow paths 219, 220, 221, and 222.
摘要:
A separator of the present invention for a nonaqueous electrolyte secondary battery is obtained by fluorinating a polyolefin based resin. A contact angle of the separator with a nonaqueous solvent electrolyte is 40° or less a shutdown temperature of the separator is 170°C or less. Further, a multilayered separator of the present invention for a nonaqueous electrolyte secondary battery includes a plurality of layers, at least one of which is the foregoing separator for a nonaqueous electrolyte secondary battery. These separators for nonaqueous electrolyte secondary battery have both a favorable electrolyte-retaining characteristic and a suitable shutdown performance.
摘要:
A high power lithium-ion secondary battery having an increased capacity and capable of maintaining high discharge voltage and repeating charging/discharging high current. A lithium-ion secondary battery having; an electrode group formed by laminating or winding a negative electrode layer and a positive electrode layer so as to interpose a separator made of synthetic resin, the negative electrode layer containing a material capable of intercalating/deintercalating lithium-ion, and a positive electrode layer including a lithium-containing metallic oxide; and a non-aqueous electrolyte containing lithium salt, where the electrode group is immersed. The positive electrode material unit contains a fluorinated lithium-containing metallic oxide as a main material, and the separator possesses a hydrophilic group. Further, the positive electrode material preferably contains a main material including LiNi x Co y Mn z O 2 , where 0.4 ≤ x ≤ 1,0≤ y ≤ 0.2, 0 ≤ z 0.2, x + y + z = 1.
摘要翻译:一种高功率锂离子二次电池,其具有增加的容量并且能够保持高放电电压并且重复充电/放电高电流。 一种锂离子二次电池,具有: 通过层叠或卷绕负极层和正极层形成的电极组,以便插入由合成树脂制成的隔板,所述负极层含有能够嵌入/脱嵌锂离子的材料,以及包括 含锂金属氧化物; 和含有锂盐的非水电解质,浸渍电极组。 正极材料单元包含含氟的含锂金属氧化物作为主要材料,并且隔膜具有亲水基团。 此外,正极材料优选含有包括LiNi x Co y Mn z O 2的主要材料,其中0.4‰x‰1.0‰y‰0.2,0‰z 0.2,x + y + z = 1。
摘要:
It is a task of the present invention to provide an electrolytic apparatus for producing fluorine or nitrogen trifluoride by electrolyzing a hydrogen fluoride-containing molten salt, the electrolytic apparatus being advantageous in that the electrolysis can be performed without the occurrence of the anode effect even at a high current density and without the occurrence of an anodic dissolution. In the present invention, this task has been accomplished by an electrolytic apparatus for producing fluorine or nitrogen trifluoride by electrolyzing a hydrogen fluoride-containing molten salt at an applied current density of from 1 to 1,000 A/dm 2 , the electrolytic apparatus using a conductive diamond-coated electrode as an anode.
摘要:
The invention pertains to a powder processing apparatus 100 that processes powder using a processing gas. It comprises a powder transport path 60 that has a strip-shaped transporter that extends spirally in a vertical direction and on which the powder moves; a powder supplier 3 for supplying the powder to the powder transport path; a vibration applier 40 that vibrates the powder transport path to move the powder supplied to the powder transport path along the strip-shaped transporter; a processing container 10 in which the powder supplied to the powder transport path is processed by the processing gas while moving; a powder recoverer that recovers the processed powder; and at least one height limitation member 64 that limits a height of the powder moving on the strip-shaped transporter.
摘要:
A powder stirring device includes a reaction container and a rotation driving device. The reaction container has a cylindrical outer peripheral wall and a pair of end surface walls. The end surface walls are respectively provided at one end and the other end of the outer peripheral wall. The reaction container is arranged in a heat-insulating cover such that an axis of the outer peripheral wall is in parallel with a horizontal direction. The outer peripheral wall has an inner peripheral surface rotationally symmetric with respect to the axis. During the powder process, the powder is stored in the reaction container, and the reaction container is rotated around a rotation axis that passes through the central axis of the outer peripheral wall by the rotation driving device. In this state, a processing gas is supplied into the reaction container. Also, the processing gas in the reaction container is discharged.
摘要:
This invention provides an electrolytic apparatus for producing fluorine or nitrogen trifluoride by electrolyzing a molten salt containing hydrogen fluoride, which electrolytic apparatus does not cause any anode effect even at high current density and can be operated without anodic dissolution. The electrolytic apparatus is an apparatus for producing fluorine or nitrogen trifluoride by electrolyzing a hydrogen fluoride-containing molten salt at an applied current density of 1 to 1,000 A/dm2 and is characterized in that an electrode covered with an electroconductive diamond is used as an anode.