摘要:
An object of the present invention is to provide a production method which can increase the activity of a catalyst particle comprising a core particle and an outermost layer, the core particle comprising at least one of palladium and a palladium alloy, and the outermost layer comprising at least one of platinum and a platinum alloy and covering the core particle. Disclosed is a method for producing a catalyst for fuel cells, in which a catalyst particle is supported by an electroconductive carrier, the method comprising the steps of: preparing a supported catalyst in which a catalyst particle comprising a core particle and an outermost layer is supported by an electroconductive carrier, the core particle comprising at least one of palladium and a palladium alloy, and the outermost layer comprising at least one of platinum and a platinum alloy and covering the core particle; acid treatment to bring the supported catalyst into contact with an acid solution which dissolves palladium more preferentially than platinum; and firing the supported catalyst at 80°C or more and less than 200°C in a reducing gas atmosphere after the acid treatment step.
摘要:
A fuel cell 10 includes an MEA 200, an anode separator 100 and a cathode separator 300. The anode separator 100 forms alternate first and second flow channels 110 and 120. The first flow channel 110 is blocked in the middle. The second flow channel 120 is blocked in the both ends. The anode separator 300 forms alternate first and second flow channels 310 and 320. The first flow channel 310 is blocked in the middle. The second flow channel 320 is blocked in the both ends.
摘要:
An object of the present invention is to provide core-shell type metal nanoparticles having a high surface coverage of the core portion with the shell portion, and a method for producing the same. Disclosed is core-shell type metal nanoparticles comprising a core portion and a shell portion covering the core portion, wherein the core portion comprises a core metal material selected from metals and alloys, and wherein the shell portion comprises an alloy of a first shell metal material and a second shell metal material.
摘要:
A catalyst particle is composed of an inner particle and an outermost layer that includes platinum and covers the inner particle. The inner particle includes on at least a surface thereof a first oxide having an oxygen defect.
摘要:
Disclosed is a catalyst particle having high catalyst activity and a method for producing the catalyst particle. A catalyst particle comprising a core particle which contains a palladium alloy and an outermost layer which contains platinum, wherein an interlayer comprising only palladium as a simple substance is present between the core particle and the outermost layer.
摘要:
The present invention provides a catalyst layer for fuel cells having improved characteristics and a production method therefor. A catalyst layer for a fuel cell, including a carbon carrier having pores, a catalyst metal carried on the carbon carrier, and an ionomer covering the carbon carrier, wherein the crystal length of the carbon carrier is not less than 6 nm, and the coverage of the catalyst metal by the ionomer is 55% to 65%, and a method for the production of a catalyst layer for a fuel cell, including heat-treating a carbon carrier having pores under an inert gas atmosphere so that the crystal length of the carbon carrier becomes not less than 6 nm, heat-treating the heat-treated carbon carrier under an oxygen atmosphere to activate the carbon carrier, allowing the activated carbon carrier to carry a catalyst metal, mixing the carbon carrier carrying the catalyst metal and an ionomer to cover the carbon carrier with the ionomer, and forming the catalyst layer for a fuel cell using the carbon carrier covered with the ionomer.
摘要:
A catalyst particle is composed of an inner particle and an outermost layer that includes platinum and covers the inner particle. The inner particle includes on at least a surface thereof a first oxide having an oxygen defect.