MULTILAYERED STRUCTURE
    10.
    发明公开
    MULTILAYERED STRUCTURE 有权
    多层结构

    公开(公告)号:EP2433794A1

    公开(公告)日:2012-03-28

    申请号:EP10777763.3

    申请日:2010-05-18

    IPC分类号: B32B27/28 B32B27/32

    摘要: [Problems] To provide a multilayered structure which eliminates the need of providing any particular adhesive layer, enables the ethylene/vinyl alcohol copolymer to exhibit excellent oxygen-barrier property to a sufficient degree, and can be effectively used even when a polyolefin resin is used as the inner and outer layers.
    [Means for Solution] A multilayered structure having an adhesive intermediate layer of a blend of an ethylene/vinyl alcohol copolymer (A) and a maleic anhydride-modified olefin resin (B) between an inner layer and an outer layer, the adhesive intermediate layer containing the ethylene/vinyl alcohol copolymer (A) and the maleic anhydride-modified olefin resin (B) at a weight ratio of 4: 6 to 8:2, the phase structure of the adhesive intermediate layer being a sea-island structure with the maleic anhydride-modified olefin resin (B) as the sea or being a bicontinuous phase, and the adhesive intermediate layer having a standard deviation of not less than 65 when a contrast profile of the ethylene/vinyl alcohol copolymer (A) and the maleic anhydride-modified olefin resin (B) in the adhesive intermediate layer near the interface thereof is numerically expressed on a scanning electron microphotograph of the cross section of the multilayered structure in the direction of thickness by using an image analysis software.

    摘要翻译: 为了提供不需要设置任何特定粘合剂层的多层结构,乙烯/乙烯醇共聚物能够充分发挥优异的阻氧性,并且即使在使用聚烯烃树脂的情况下也能够有效地使用 作为内层和外层。 [溶液的方法]在内层和外层之间具有乙烯/乙烯醇共聚物(A)和马来酸酐改性的烯烃树脂(B)的共混物的粘合剂中间层的多层结构,粘合剂中间层 含有重量比为4:6〜8:2的乙烯 - 乙烯醇共聚物(A)和马来酸酐改性烯烃树脂(B),粘合性中间层的相结构为海岛结构, 当乙烯/乙烯醇共聚物(A)和马来酸酐共聚物(A)与马来酸酐共聚物(A)的对比度分布不同时,作为海或共连续相的马来酸酐改性烯烃树脂(B)和标准偏差不小于65的粘合剂中间层 在其界面附近的粘合中间层中的改性烯烃树脂(B)在厚度方向上在多层结构的横截面的扫描电子显微照片上用数字表示 法师分析软件。