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    ACTINIDE-CONTAINING MOLECULAR SIEVES
    9.
    发明公开
    ACTINIDE-CONTAINING MOLECULAR SIEVES 失效
    ACTINID ENTHALTENDE MOLEKULARSIEBE

    公开(公告)号：EP0977710A1

    公开(公告)日：2000-02-09

    申请号：EP98919363.6

    申请日：1998-04-30

    申请人： British Nuclear Fuels PLC

    发明人： LEE, Darren, FrankBritish Nuclear Fuels plc ,  O'HARE, Dermot ,  FRANCIS, Robin

    IPC分类号： C01B37/00

    CPC分类号： C01B37/00 ,  B01J20/06 ,  B01J23/12 ,  B01J29/005 ,  B01J29/0308 ,  B01J29/049 ,  B01J29/82 ,  B01J39/09 ,  B01J39/12

    摘要： Molecular sieves (often loosely termed microporous materials) contain an actinide in combination with atoms selected from the group consisting of oxygen, fluorine, phosphorus, transition metals and mixtures thereof. The molecular sieve material may contain a template species, which suitably comprises an organic template molecule and/or a cationic metal species; it may also contain water. Additionally, it may contain a dopant, usually in a minor amount; suitable dopants include transition metals to modify the catalytic properties of the materials. Preferred molecular sieves comprise layered structures in which layers containing actinide in combination with atoms selected from the group consisting of oxygen, fluorine, phosphorus, transition metals and mixtures thereof have organic templates and/or cationic metal species located between them. In one class of materials, the layers contain an oxoanion (preferably a phosphate, notably orthophosphate, or a transition metal oxoanion); in this class, the actinide may usually be represented as an oxo ion, expecially an oxocation. In another class of materials, the layers contain actinide and fluorine. Exemplary materials have U/P/O or U/F frameworks.

    摘要翻译： 分子筛（通常松散地称为微孔材料）含有与选自氧，氟，磷，过渡金属及其混合物的原子组合的锕系元素。 分子筛材料可以包含适当地包含有机模板分子和/或阳离子金属物质的模板物质; 它也可能含有水分。 另外，它可以含有通常少量的掺杂剂; 合适的掺杂剂包括过渡金属以改变材料的催化性能。 优选的分子筛包括层状结构，其中含有锕系元素与选自氧，氟，磷，过渡金属及其混合物的原子的组合的层具有位于它们之间的有机模板和/或阳离子金属物质。 在一类材料中，层包含氧阴离子（优选磷酸盐，特别是正磷酸盐或过渡金属氧代阴离子）; 在该类中，锕系通常可以表示为氧离子，特别是氧化。 在另一类材料中，这些层含有锕系和氟。 示例性材料具有U / P / O或U / F框架。

    Synthetic dioctahedral smectite clays
    10.
    发明公开
    Synthetic dioctahedral smectite clays 失效
    Synthetische dioktaedrische Smektittone。

    公开(公告)号：EP0613718A1

    公开(公告)日：1994-09-07

    申请号：EP93103519.0

    申请日：1993-03-05

    申请人： UOP

    发明人： Holmgren, Jennifer S.

    IPC分类号： B01J29/02 ,  C01B33/20

    CPC分类号： B01J29/049 ,  B01J20/12 ,  B01J21/16

    摘要： A novel synthetic dioctahedral smectite layered clay, a process for preparing the clay and a process using the clay is disclosed. The clays that are prepared are gallium/silicon, gallium/germanium, or aluminum/germanium smectite clays. The clay is prepared from a reaction mixture containing reactive sources of the metals, i.e., aluminum, silicon, gallium and germanium, a templating agent and water. This reaction mixture is reacted at a pH of 8.5 to 14, a temperature of 150 to 210 o C for a time of 1 to 20 days to give a desired composition. The clay compositions of the instant invention can be used to catalyze various hydrocarbon conversion processes such as alkylation and hydrocracking.

    摘要翻译： 公开了一种新型合成二八面体蒙皂石层状粘土，一种制备粘土的方法和使用该粘土的方法。 制备的粘土是镓/硅，镓/锗或铝/锗蒙皂石粘土。 粘土由含有金属反应源的反应混合物制备，即铝，硅，镓和锗，模板剂和水。 该反应混合物在8.5至14的pH，150至210℃的温度下反应1至20天，得到所需的组合物。 本发明的粘土组合物可用于催化各种烃转化方法如烷基化和加氢裂化。