OLEFIN TRIBLOCK POLYMERS VIA RING-OPENING METATHESIS POLYMERIZATION
    3.
    发明公开
    OLEFIN TRIBLOCK POLYMERS VIA RING-OPENING METATHESIS POLYMERIZATION 审中-公开
    烯烃三嵌段聚合物的开环聚合

    公开(公告)号:EP2688954A4

    公开(公告)日:2014-10-01

    申请号:EP12764275

    申请日:2012-03-05

    发明人: STEWART IAN C

    IPC分类号: C08G61/08 C08L53/00 C08L65/00

    摘要: This invention relates to a composition comprising a multiblock polyolefin represented by the formula: PO-(-C=C-Z-)n-C=C-PO* (I) or PO-(-C-C-Z-)n-C-C-PO* (la) wherein Z is the portion of a cyclic monomer having at least one internal double bond that remains after a ring-opening metathesis reaction; PO and PO* are each independently polyolefins; and n is 1 to 10,000; and a process to produce such comprising contacting an alkene metathesis catalyst with a dimer of vinyl terminated polyolefins, and a cyclic hydrocarbyl monomer comprising at least one internal double bond.

    摘要翻译: 本发明涉及一种组合物,其包含由下式表示的多嵌段聚烯烃:PO - ( - C = CZ-)nC = C-PO *(I)或PO - ( - CCZ-)nCC-PO *(Ia) 是具有在开环复分解反应之后保留的至少一个内部双键的环状单体的部分; PO和PO *各自独立地为聚烯烃; n为1〜10,000; 以及生产这样的方法,包括使烯烃复分解催化剂与乙烯基封端的聚烯烃的二聚体和包含至少一个内部双键的环状烃基单体接触。

    OLEFIN TRIBLOCK POLYMERS VIA RING-OPENING METATHESIS POLYMERIZATION
    4.
    发明公开
    OLEFIN TRIBLOCK POLYMERS VIA RING-OPENING METATHESIS POLYMERIZATION 审中-公开
    烯烃三嵌段聚合物的开环聚合

    公开(公告)号:EP2688954A2

    公开(公告)日:2014-01-29

    申请号:EP12764275.9

    申请日:2012-03-05

    发明人: STEWART, Ian, C.

    摘要: This invention relates to a composition comprising a multiblock polyolefin represented by the formula: PO-(-C=C-Z-)n-C=C-PO* (I) or PO-(-C-C-Z-)n-C-C-PO* (la) wherein Z is the portion of a cyclic monomer having at least one internal double bond that remains after a ring-opening metathesis reaction; PO and PO* are each independently polyolefins; and n is 1 to 10,000; and a process to produce such comprising contacting an alkene metathesis catalyst with a dimer of vinyl terminated polyolefins, and a cyclic hydrocarbyl monomer comprising at least one internal double bond.

    摘要翻译: 本发明涉及包含由下式表示的多嵌段聚烯烃的组合物:PO-( - C = CZ-)nC = C-PO *(I)或PO - ( - CCZ-)nCC-PO *(Ia)其中Z 是具有至少一个内部双键的环状单体的部分,其在开环复分解反应之后保留; PO和PO *各自独立地为聚烯烃; 并且n是1至10,000; 以及生产这种方法的方法,该方法包括使烯烃易位催化剂与乙烯基封端的聚烯烃的二聚体和包含至少一个内部双键的环状烃基单体接触。

    DIBLOCK COPOLYMERS PREPARED BY CROSS METATHESIS
    5.
    发明公开
    DIBLOCK COPOLYMERS PREPARED BY CROSS METATHESIS 审中-公开
    通过交叉复分解生产的二嵌段

    公开(公告)号:EP2688921A2

    公开(公告)日:2014-01-29

    申请号:EP12764240.3

    申请日:2012-03-05

    摘要: This invention relates to a composition comprising a multiblock polyolefin represented by the formula: PO-C(R11)(R12)-C(R13)=C(R14)-C(R15)(R16)-PO*, or isomers thereof, wherein R11, R12, R13, R14, R15, and R16, are each independently a substituted or unsubstituted C1 through C4 hydrocarbyl group or a hydrogen; PO and PO* are polyolefins; PO and PO* are each independently a substituted or unsubstituted hydrocarbyl group having 9 to 4000 carbon atoms, provided that at least one of PO and PO* are C20 or greater, said polyolefin having: 1) an internal unsaturation as shown by the 13C NMR peak at between about 128 and about 132 ppm; 2) an Mn ratio "Z" = 0.1 to 10 where Z is the Mn (as determined by 13C NMR) divided by Mn (as determined according to Gel Permeation Chromotography using polystyrene standards); and 3) optionally, from 0.3(J) and 0.75(J) internal unsaturations per 1000 carbons as determined by 1H NMR spectroscopy, where J is the number of reactive groups per 1000 carbons for the mixture of vinyl terminated polyolefins that become PO and PO*, before they are coupled by an alkene metathesis catalyst.

    Functionalized materials by catalyzed carbene copolymerization
    7.
    发明公开
    Functionalized materials by catalyzed carbene copolymerization 审中-公开
    复合材料

    公开(公告)号:EP2397509A1

    公开(公告)日:2011-12-21

    申请号:EP10006329.6

    申请日:2010-06-18

    IPC分类号: C08G61/04

    CPC分类号: C08G61/04 B60N2/7017 C08F2/00

    摘要: The present invention relates to a copolymer having the general formula:

             (̵CHR 1 )̵ n      Formula 1

    wherein the copolymer comprises a chain of n carbon atoms, each carbon atom bearing a R 1 group, each R 1 group being independently selected from the group consisting of:
    -H and hydrocarbyl-groups having between 1 and 50 carbon atoms and optionally one or more hetero atoms, and wherein the copolymer comprises at least two different R 1 groups, and wherein n is an integer ranging from 50 to 1000000.

    The present invention also relates to a method for preparing such copolymers.

    摘要翻译: 本发明涉及具有以下通式的共聚物:ƒ€ƒ€ƒ€ƒ€ƒ€ƒ(5CHR 1)5 n€ƒ€ƒ€ƒ€ƒ1其中共聚物包含 n个碳原子的链,每个含有R 1基团的碳原子,每个R 1基团独立地选自:-H和具有1至50个碳原子和任选的一个或多个杂原子的烃基,以及 其中所述共聚物包含至少两个不同的R 1基团,并且其中n是50至1000000的整数。本发明还涉及制备这种共聚物的方法。

    Method for producing polymerized hydrocarbon
    9.
    发明公开
    Method for producing polymerized hydrocarbon 有权
    Verfahren zur Herstellung聚合物Kohlenwasserstoffe

    公开(公告)号:EP1520846A1

    公开(公告)日:2005-04-06

    申请号:EP04022839.7

    申请日:2004-09-24

    IPC分类号: C07C1/00

    摘要: A method for producing a polymerized hydrocarbon includes a step of a dehalogenation of a halogenated hydrocarbon with a magnesium-diene complex. Low-molecular-weight compounds, such as dimers or trimers of hydrocarbon units, oligomers of hydrocarbon units, or polymers of hydrocarbon units can be produced by this method while generating significantly less odor.

    摘要翻译: 一种生产聚合烃的方法包括卤代烃与镁 - 二烯络合物脱卤的步骤。 低分子量化合物,例如烃单元的二聚体或三聚体,烃单元的低聚物或烃单元的聚合物可以通过该方法生产,同时产生显着较少的气味。