Abstract:
The present invention relates to a method for producing functionalized isotactic polystyrene, functionalized isotactic polystyrene that can be produced according to the method of the invention, the use of the functionalized isotactic polystyrene according to the invention as a macromonomer, a method for producing a macroinitiator, a macroinitiator that can be produced according to the method mentioned above, the use of the macroinitiator for controlled radical polymerization, the use of the functionalized isotactic polystyrene according to the invention as a macromonomer, preferably in the copolymerization with olefins, the ROMP with cycloolefins or for coupling with silicon segments, a method for epoxidating the functionalized isotactic polystyrene according to the invention, epoxidized isotactic polystyrene that can be produced according to the method mentioned above, and a method for producing soft thermoplastic elastomers (TPE) by metathesis polymerization of the functionalized isotactic polystyrene according to the invention using suitable polymers, which comprise terminal double bounds, and soft thermoplastic elastomer that can be produced according to the invention.
Abstract:
A mixture comprising a) 5 to 95 wt.-% of a copolymer A that contains one or more copolymer blocks (B/S) A , each made of 65 to 95 wt.-% of vinyl aromatic monomers and 5 to 35 wt.-% dienes and having a glass transition temperature Tg A in the range of 40° to 90°C, b) 5 to 95 wt.-% of a block copolymer B containing at least one hard block S made of 95 to 100 wt.-% of vinyl aromatic monomers and 0 to 5 wt.-% dienes, one or more copolymer blocks (B/S) A , each made of 65 to 95 wt.-% of vinyl aromatic monomers and 5 to 35 wt.-% dienes and having a glass transition temperature Tg A in the range of 40° to 90°C and one or more copolymer blocks (B/S) B , each made of 20 to 60 wt.-% of vinyl aromatic monomers and 40 to 80 wt.-% dienes and having a glass transition temperature Tg B in the range of –70° to 0°C, c) 0 to 45 wt.-% of A and B of various thermoplastic polymers C and d) 0 to 6 wt.-% of processing aids D, wherein the total of A through D is 100 wt.-%, and use thereof for the production of shrink-wrap films.
Abstract:
The present invention relates to a method for producing functionalized isotactic polystyrene, functionalized isotactic polystyrene that can be produced according to the method of the invention, the use of the functionalized isotactic polystyrene according to the invention as a macromonomer, a method for producing a macroinitiator, a macroinitiator that can be produced according to the method mentioned above, the use of the macroinitiator for controlled radical polymerization, the use of the functionalized isotactic polystyrene according to the invention as a macromonomer, preferably in the copolymerization with olefins, the ROMP with cycloolefins or for coupling with silicon segments, a method for epoxidating the functionalized isotactic polystyrene according to the invention, epoxidized isotactic polystyrene that can be produced according to the method mentioned above, and a method for producing soft thermoplastic elastomers (TPE) by metathesis polymerization of the functionalized isotactic polystyrene according to the invention using suitable polymers, which comprise terminal double bounds, and soft thermoplastic elastomer that can be produced according to the invention.
Abstract:
The invention relates to a multi-layer finish on a substrate, containing at least one radiation-curable paint system (F) and at least one elastic intermediate layer (D) which is located between the substrate and the radiation-curable paint system (F) and has a maximum glass transition temperature (Tg) of -20 °C.
Abstract:
The invention relates to a mixture, comprising a) 5 to 50 wt. % of a block copolymer (A), with one or more block copolymers (B/S)A, each made from 65 to 95 wt. % vinylaromatic monomers and 35 to 5 wt. % dienes with a glass transition temperature TgA in the range 40° to 90 °C, b) 95 to 50 wt. % of a block copolymer B, with at least one hard block (S) made from vinylaromatic monomers and one or more copolymer blocks (B/S)B, each made from 20 to 60 wt. % vinylaromatic monomers and 80 to 40 wt. % dienes and a glass temperature TgB in the range -70° to 0 °C, c) 0 to 45 wt. % of a block copolymer (C) different from (A) and (B), or polystyrol and d) 0 to 6 wt. % of a plastifier and the use thereof for the production of shrink films.
Abstract:
The manufacture of flat molded members or films that have anisotropic thermal expansion coefficients is done from extrudable thermoplastic polymer molding materials by filling the thermoplastic polymer molding materials with lamellar layered silicates that have a diameter in the range of 10 to 1000 nm and an aspect ratio from 1 to 5 to 1 to 10000, extruding the filled thermoplastic polymer molding materials and subsequently uniaxially or biaxially stretching the extrudate into flat molded members or films.
Abstract:
The manufacture of flat molded members or films that have anisotropic thermal expansion coefficients is done from extrudable thermoplastic polymer molding materials by filling the thermoplastic polymer molding materials with lamellar layered silicates that have a diameter in the range of 10 to 1000 nm and an aspect ratio from 1 to 5 to 1 to 10000, extruding the filled thermoplastic polymer molding materials and subsequently uniaxially or biaxially stretching the extrudate into flat molded members or films.