公开(公告)号：EP2152405B1

公开(公告)日：2012-10-17

申请号：EP08758608.7

申请日：2008-05-19

申请人： Merck Patent GmbH

发明人： GRAALFS, Heiner

IPC分类号： B01J20/32 ,  B01J29/20 ,  B01D15/08

CPC分类号： C08F22/38 ,  B01D15/327 ,  B01D15/362 ,  B01J20/3242 ,  B01J39/17 ,  B01J39/20 ,  B01J39/26

公开(公告)号：EP2229235A1

公开(公告)日：2010-09-22

申请号：EP08863050.4

申请日：2008-12-16

申请人： BP Chemicals Limited

发明人： DITZEL, Evert, Jan ,  LAW, David, John ,  MORRIS, George, Ernest ,  ROBERTS, Mark, Stephen ,  SCHUNK, Stephan, Andreas ,  SMIT, Martin ,  SUNLEY, John, Glenn

IPC分类号： B01J29/90 ,  B01J29/20 ,  B01J38/14 ,  C07C51/12 ,  C07C67/37

CPC分类号： B01J29/90 ,  B01J29/20 ,  B01J38/14 ,  C07C51/12 ,  C07C67/37 ,  Y02P20/584 ,  C07C53/08 ,  C07C69/14

摘要： A process for the carbonylation of dimethyl ether, dimethyl carbonate and/or methanol with carbon monoxide and hydrogen in the presence of a mordenite catalyst to produce at least one of acetic acid and methyl acetate in which process the mordenite catalyst is regenerated in-situ by contacting the catalyst with a regenerating gas comprising a molecular oxygen-containing gas and an inert diluent at a total pressure in the range 1 to 100 bar and wherein the partial pressure of the molecular oxygen-containing gas is such that the temperature of the catalyst is maintained within the range 225 to 325 °C.

公开(公告)号：EP0848859A4

公开(公告)日：2006-06-28

申请号：EP96925262

申请日：1996-06-07

申请人： UNIV IOWA RES FOUND

发明人： LEDDY JOHNA ,  AMARASINGHE SUDATH ,  ZOOK LOIS ANNE ,  TINOCO FLAVIO

IPC分类号： B03C1/00 ,  B01J19/08 ,  B01J29/20 ,  B03C1/01 ,  B03C1/025 ,  B03C1/034 ,  B03C1/035 ,  C23C6/00 ,  C23C24/08 ,  C23C30/00 ,  C25B11/06 ,  C25B11/12 ,  C25B13/00 ,  C25D3/54 ,  G21F9/12 ,  H01F1/00 ,  H01F10/00 ,  H01F41/24 ,  H01F41/26 ,  H01F41/30 ,  H01M2/00 ,  H01M2/02 ,  H01M2/14 ,  H01M2/16 ,  H01M2/18 ,  H01M4/02 ,  H01M4/32 ,  H01M4/36 ,  H01M4/52 ,  H01M4/58 ,  H01M4/86 ,  H01M4/88 ,  H01M4/90 ,  H01M4/92 ,  H01M8/00 ,  H01M8/02 ,  H01M8/04 ,  H01M8/06 ,  H01M8/10 ,  H01M8/24 ,  H01M10/04 ,  H01M10/42

CPC分类号： H01F1/37 ,  B03C1/00 ,  B03C1/01 ,  B03C1/025 ,  B03C1/034 ,  B03C1/035 ,  B82Y25/00 ,  B82Y40/00 ,  C23C4/12 ,  C23C6/00 ,  C23C24/00 ,  C23C24/08 ,  C23C30/00 ,  C25D5/006 ,  C25D7/001 ,  G21F9/12 ,  H01F1/0027 ,  H01F1/0054 ,  H01F1/009 ,  H01F10/007 ,  H01F41/24 ,  H01F41/26 ,  H01F41/301 ,  H01M2/0257 ,  H01M2/0292 ,  H01M4/02 ,  H01M4/86 ,  H01M4/8605 ,  H01M4/8657 ,  H01M4/8803 ,  H01M4/8857 ,  H01M4/8878 ,  H01M4/8882 ,  H01M4/9016 ,  H01M4/9083 ,  H01M4/926 ,  H01M8/00 ,  H01M8/1004 ,  H01M8/1009 ,  H01M8/249 ,  H01M10/04 ,  H01M10/42 ,  H01M2300/0082 ,  Y10T428/2991 ,  Y10T428/2998

摘要： Magnetic composites exhibit distinct flux properties due to gradient interfaces. The composites can be used to improve fuel cells and batteries and effect transport and separation of different chemical species. Devices utilizing the composites include a separator, an electrode (804) for channeling flux of magnetic species, an electrode (804) for effecting electrolysis of magnetic species, a system for channeling electrolyte species, a system for separating particles with different magnetic susceptibilities, improved fuel cells, batteries, and oxygen concentrators. Some composites can be used to make a separator for distinguishing between two species of materials and a flux switch to regulate the flow of a chemical species. Some composites can control chemical species transport and distribution. Other composites enable ambient pressure fuel cells having enhanced performance and reduced weight. Some other composites enable rechargeable batteries that have longer secondary cycle life and improved output power. Still other composites, disposed on the surface of electrodes, prevent passivation of those electrodes and enable direct reformation of liqui fuels. Methods involving these composites provide distinct ways for these composites to be utilized.

摘要翻译： 由于梯度界面，磁性复合材料呈现出不同的通量特性。 该复合材料可用于改进燃料电池和电池，并影响不同化学物质的传输和分离。 利用复合材料的装置包括隔膜，用于引导磁性物质通量的电极（804），用于实现磁性物质电解的电极（804），用于引导电解质物质的系统，用于分离具有不同磁化率的颗粒的系统，改进的 燃料电池，电池和氧气浓缩器。 一些复合材料可用于制造分隔物，用于区分两种物质和流量开关以调节化学物质的流动。 一些复合材料可以控制化学物质的运输和分配。 其他复合材料使环境压力燃料电池具有更高的性能和更轻的重量。 其他一些复合材料能够实现更长的二次循环寿命和更高输出功率的可充电电池。 设置在电极表面上的其他复合材料防止了这些电极的钝化并且能够直接重新形成液体燃料。 涉及这些复合材料的方法为这些复合材料的使用提供了不同的方法。

公开(公告)号：EP3157671A4

公开(公告)日：2018-02-14

申请号：EP15808974

申请日：2015-06-17

申请人： BASF CORP

发明人： YANG XIAOFAN ,  HOCHMUTH JOHN K ,  XUE WEN-MEI ,  WANG XIAOMING ,  CAUDLE MATTHEW TYLER ,  MOINI AHMAD ,  HOLLOBAUGH DUSTIN O ,  FU QI ,  BREEN MICHAEL

IPC分类号： B01J29/89 ,  B01D53/94 ,  B01J29/06 ,  B01J29/16 ,  B01J29/20 ,  B01J37/02

CPC分类号： B01J37/0215 ,  B01D53/9418 ,  B01D53/9436 ,  B01D2251/2062 ,  B01D2251/2067 ,  B01D2255/104 ,  B01D2255/2063 ,  B01D2255/2065 ,  B01D2255/20707 ,  B01D2255/20715 ,  B01D2255/20723 ,  B01D2255/2073 ,  B01D2255/20738 ,  B01D2255/20746 ,  B01D2255/20753 ,  B01D2255/20761 ,  B01D2255/50 ,  B01D2255/911 ,  B01J29/763 ,  B01J29/89 ,  B01J35/002 ,  B01J35/04 ,  B01J37/0246 ,  B01J2229/183 ,  B01J2229/186

摘要： Described is a selective catalytic reduction catalyst comprising a zeolitic framework material of silicon and aluminum atoms, wherein a fraction of the silicon atoms are isomorphously substituted with a tetravalent metal. The catalyst can include a promoter metal such that the catalyst effectively promotes the reaction of ammonia with nitrogen oxides to form nitrogen and H20 selectively over a temperature range of 150 to 650 °C. In another aspect, described is a selective catalytic reduction composite comprising an SCR catalyst material and an ammonia storage material comprising a transition metal having an oxidation state of IV. The SCR catalyst material promotes the reaction of ammonia with nitrogen oxides to form nitrogen and H20 selectively over a temperature range of 150 °C to 600 °C, and the SCR catalyst material is effective to store ammonia at temperatures of 400 °C and above. A method for selectively reducing nitrogen oxides, and a method for simultaneously selectively reducing nitrogen oxide and storing ammonia are also described. Additionally, an exhaust gas treatment system is also described.

公开(公告)号：EP3157671A1

公开(公告)日：2017-04-26

申请号：EP15808974.8

申请日：2015-06-17

申请人： BASF Corporation

发明人： YANG, Xiaofan ,  HOCHMUTH, John K. ,  XUE, Wen-Mei ,  WANG, Xiaoming ,  CAUDLE, Matthew Tyler ,  MOINI, Ahmad ,  HOLLOBAUGH, Dustin O. ,  FU, Qi ,  BREEN, Michael

IPC分类号： B01J29/06 ,  B01J29/16 ,  B01J29/20

CPC分类号： B01J37/0215 ,  B01D53/9418 ,  B01D53/9436 ,  B01D2251/2062 ,  B01D2251/2067 ,  B01D2255/104 ,  B01D2255/2063 ,  B01D2255/2065 ,  B01D2255/20707 ,  B01D2255/20715 ,  B01D2255/20723 ,  B01D2255/2073 ,  B01D2255/20738 ,  B01D2255/20746 ,  B01D2255/20753 ,  B01D2255/20761 ,  B01D2255/50 ,  B01D2255/911 ,  B01J29/763 ,  B01J29/89 ,  B01J35/0006 ,  B01J35/002 ,  B01J35/023 ,  B01J35/04 ,  B01J37/0246 ,  B01J2229/183 ,  B01J2229/186

摘要： Described is a selective catalytic reduction catalyst comprising a zeolitic framework material of silicon and aluminum atoms, wherein a fraction of the silicon atoms are isomorphously substituted with a tetravalent metal. The catalyst can include a promoter metal such that the catalyst effectively promotes the reaction of ammonia with nitrogen oxides to form nitrogen and H20 selectively over a temperature range of 150 to 650 °C. In another aspect, described is a selective catalytic reduction composite comprising an SCR catalyst material and an ammonia storage material comprising a transition metal having an oxidation state of IV. The SCR catalyst material promotes the reaction of ammonia with nitrogen oxides to form nitrogen and H20 selectively over a temperature range of 150 °C to 600 °C, and the SCR catalyst material is effective to store ammonia at temperatures of 400 °C and above. A method for selectively reducing nitrogen oxides, and a method for simultaneously selectively reducing nitrogen oxide and storing ammonia are also described. Additionally, an exhaust gas treatment system is also described.

摘要翻译： 描述了一种选择性催化还原催化剂，其包含硅和铝原子的沸石骨架材料，其中一部分硅原子被四价金属同晶取代。 催化剂可以包括助催化剂金属，使得催化剂有效地促进氨与氮氧化物的反应，以在150至650℃的温度范围内选择性地形成氮气和H 2 O. 另一方面，描述了选择性催化还原复合物，其包含SCR催化剂材料和包含具有IV氧化态的过渡金属的氨储存材料。 SCR催化剂材料促进氨与氮氧化物的反应以在150℃至600℃的温度范围内选择性地形成氮气和H 2 O，并且SCR催化剂材料在400℃以上的温度下有效地存储氨。 还描述了选择性还原氮氧化物的方法，以及同时选择性还原氮氧化物和储存氨的方法。 另外，还描述了排气处理系统。

公开(公告)号：EP1027930A1

公开(公告)日：2000-08-16

申请号：EP98941804.1

申请日：1998-09-09

申请人： TOYOTA JIDOSHA KABUSHIKI KAISHA

发明人： TAKAHASHI, Hiroaki ,  TAKADA, Toshihiro ,  KURACHI, Saeko

IPC分类号： B01J29/064 ,  B01J29/10 ,  B01J29/20 ,  B01J29/42 ,  B01J29/66 ,  B01D53/94 ,  F01N3/08

CPC分类号： B01D53/945 ,  B01D53/9418 ,  B01D2255/1021 ,  B01D2255/2022 ,  B01D2255/2025 ,  B01D2255/2042 ,  B01D2255/2047 ,  B01D2255/50 ,  B01D2255/912 ,  B01J29/068 ,  B01J29/084 ,  B01J29/18 ,  B01J29/22 ,  B01J29/40 ,  B01J29/44 ,  B01J29/65 ,  B01J29/67 ,  B01J29/80 ,  B01J35/04 ,  B01J37/0246 ,  B01J37/0248 ,  F01N3/0814 ,  F01N3/0835 ,  F01N3/0842 ,  F01N3/206 ,  Y02T10/22

摘要： It is arranged such that a first zeolite loaded with a catalyst metal and a second zeolite unloaded with a catalyst metal are mixed.
By actively adsorbing HC onto the second zeolite, it is possible to inhibit the catalyst metal loaded on the first zeolite from being poisoned by HC, and to sufficiently adsorb HC. Accordingly, since the HC adsorbing capability is improved, and since the HC poisoning of the catalyst metal is suppressed, the NO x purifying capability is enhanced and the durability is also upgraded.

摘要翻译： 将负载有催化剂金属的第一沸石和未载有催化剂金属的第二沸石混合。 通过积极地将HC吸附到第二沸石上，可以抑制负载在第一沸石上的催化剂金属被HC中毒并充分吸附HC。 因此，由于HC吸附能力提高，并且由于催化剂金属的HC中毒被抑制，所以NO x净化能力提高，耐久性也得到提高。

公开(公告)号：EP0614692A1

公开(公告)日：1994-09-14

申请号：EP94201396.2

申请日：1991-05-02

申请人： SAKAI CHEMICAL INDUSTRY CO., LTD.,

发明人： Yoshimoto, Masafumi ,  Nakatsuji, Tadao ,  Shimizu, Hiromitsu

IPC分类号： B01D53/36 ,  B01J29/20

CPC分类号： B01J21/066 ,  B01D53/9418 ,  B01D2251/208 ,  B01D2255/1021 ,  B01D2255/1023 ,  B01D2255/1026 ,  B01D2255/2063 ,  B01D2255/207 ,  B01J21/063 ,  B01J23/38 ,  B01J29/068

摘要： A catalyst for denitrizing of nitrogen oxides in the presence of a hydrocarbon as a reducing agent, which comprises:

(A) a substituted zeolite having the general formula



        M¹ A M² B [(A10₂) x (Si0₂) Y ]·Z H₂0



in which M¹ represents alkali metal, alkaline earth metal or hydrogen ion; M² is at least one metal ion selected from Ti⁴⁺, Zr⁴⁺ and Sn⁴⁺; n₁A +n₂B = X wherein n₁ is a valence of the ion M¹ and n₂ is a valence of ion M²; and Y/Z≧ 5 ; the M² ion being contained in an amount of 0.1-20% by weight based on the zeolite; and either
(B) at least one metal or oxide of metal selected from Pd, Pt, Ru, Rh and Ag supported on the substituted zeolite in an amount of 0.1-10% by weight based on the zeolite, or
(C) at least one oxide of metal selected from V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Nb, Mo and W in an amount of 0.1-20% by weight based on the zeolite.

摘要翻译： 在烃作为还原剂存在下脱氮氮氧化物的催化剂，其包括：（A）具有通式M 1 AM 2 B [（A 102）x（SiO 2）Y]的取代沸石， .ZH 2 O其中M 1表示碱金属，碱土金属或氢离子; M 2是选自Ti 4+，Zr 4+和Sn 4+中的至少一种金属离子。 n1A + n2B = X其中n1是离子M 1的化合价，n2是离子M 2的化合价; 和Y / Z> = 5; 相对于沸石，M 2离子的含量为0.1-20重量％; 和（B）至少一种选自负载在取代的沸石上的Pd，Pt，Ru，Rh和Ag的金属或金属的金属，其量为0.1-10重量％，或者（C）至少 选自V，Cr，Mn，Fe，Co，Ni，Cu，Zn，Nb，Mo和W的金属的一种氧化物的量为0.1-20重量％。

公开(公告)号：EP0363253B1

公开(公告)日：1992-04-22

申请号：EP89402635.0

申请日：1989-09-26

申请人： INSTITUT FRANCAIS DU PETROLE

发明人： Travers, Christine ,  Raatz, Francis ,  Marcilly, Christian ,  Ribeiro Ramoa, Fernando ,  Gomes Ribeiro, Maria Filipa

IPC分类号： B01J29/20 ,  C10G45/64 ,  C07C5/27

CPC分类号： C10G45/64 ,  B01J29/20 ,  B01J29/22 ,  B01J35/002 ,  B01J2229/16 ,  B01J2229/37 ,  B01J2229/40 ,  B01J2229/42 ,  C07C5/2724 ,  C07C15/067

公开(公告)号：EP0100115A2

公开(公告)日：1984-02-08

申请号：EP83201009.4

申请日：1983-07-05

申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V.

发明人： van Erp, Willibrord Adelbert ,  van de Griend, Jacob Adrianus ,  Maxwell, Ian Ernest ,  Nanne, Johannes Martinus

IPC分类号： C01B33/28 ,  B01J29/20 ,  C10G45/64

CPC分类号： C10G45/64 ,  B01J29/70 ,  C01B33/2876

摘要： Hydrocarbon oils, in particular lubricating oils, transformer oils, kerosines or gas oils, are hydrodewaxed over a composite crystalline aluminium silicate as catalyst, which has been prepared from a pyridine-containing base mixture.

摘要翻译： 烃油，特别是润滑油，变压器油，煤油或瓦斯油，加氢脱蜡是在复合晶状硅酸铝作为催化剂，其已经从含吡啶基的混合物制备。

公开(公告)号：EP2225032A1

公开(公告)日：2010-09-08

申请号：EP08863255.9

申请日：2008-12-16

申请人： BP Chemicals Limited

发明人： BECKER, Edo, Johann ,  DITZEL, Evert, Jan ,  KAISER, Harry ,  MORRIS, George, Ernest ,  ROBERTS, Mark, Stephen ,  SCHUNK, Stephan, Andreas ,  SMIT, Martin ,  SUNLEY, John, Glenn

IPC分类号： B01J29/06 ,  B01J29/20 ,  B01J29/90 ,  B01J29/50 ,  B01J29/65 ,  B01J29/86 ,  B01J29/87 ,  B01J29/88 ,  C07C51/12 ,  C07C67/37

CPC分类号： B01J29/06 ,  B01J29/20 ,  B01J29/50 ,  B01J29/65 ,  B01J29/86 ,  B01J29/87 ,  B01J29/88 ,  B01J29/90 ,  C07C51/12 ,  C07C67/37 ,  Y02P20/584 ,  C07C53/08 ,  C07C69/14

摘要： A method for the regeneration of a zeolite catalyst effective for the carbonylation of methanol or dimethyl ether or dimethyl carbonate with carbon monoxide to produce at least one of acetic acid and methyl acetate wherein said method comprises contacting the zeolite catalyst with a regeneration gas selected from hydrogen or a mixture of hydrogen and carbon monoxide and wherein the catalyst is maintained at a temperature in the range 250 to 600 °C.

摘要翻译： 一种在羰基化工艺中原位再生沸石催化剂以通过在沸石催化剂存在下使甲醇，二甲基乙基或碳酸二甲酯与一氧化碳接触来生产乙酸甲酯和乙酸中的至少一种的方法，停止 催化剂与反应物接触，用选自氢气或氢气和一氧化碳的混合物的再生气体在250-600℃的温度下再生催化剂，终止氢气再生步骤，并恢复催化剂与 反应物和一氧化碳。