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1.发明公开
公开(公告)号：EP0158189A3
公开(公告)日：1986-01-22
申请号：EP85103330
申请日：1985-03-21
CPC分类号： C07C2/864 , C07C2523/02 , C07C2523/04 , C07C2527/232 , C07C2531/04 , C07C2601/10 , C07C13/15
摘要： An alkylation method of a cyclopentadiene derivative comprising the vapor-phase reaction of a cyclopentadiene derivative and an aliphatic lower alcohol in the presence of a specific heterogeneous basis catalyst.
摘要翻译： 环戊二烯衍生物的烷基化方法，包括环戊二烯衍生物和脂肪族低级醇在特殊非均相碱性催化剂存在下的气相反应。
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公开(公告)号：EP0148147A3
公开(公告)日：1985-09-25
申请号：EP84870181
申请日：1984-12-19
CPC分类号： C07C2/66 , C07C2/864 , C07C2529/035 , Y02P30/42 , C07C15/02
摘要： A process for the selective alkylation of monoalkylbenzene into dialkylbenzenes wherein the para isomer of the disubstituted product is present in a concentration greater than in a thermodynamic equilibrium is provided. The method comprises passing the monoalkylbenzene and an alkylating agent capable of methylation. ethylation or propylation through a reaction zone containing an unmodified crystalline silica catalyst of the silicalite type having the monoclinic symmetry.
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3.发明公开Para-selective and beta-selective crystallized glass zeolite alkylation catalyst 失效PARA选择性和BETA选择性结晶玻璃沸石烷基化催化剂
公开(公告)号：EP0126245A3
公开(公告)日：1985-09-18
申请号：EP84103503
申请日：1984-03-29
CPC分类号： C07C2/66 , B01J29/86 , C07C2/864 , C07C2529/86 , Y10S423/22 , C07C15/00
摘要： There are provided crystallized borosilicate glass zeolite catalysts which are para-selective in the alkylation of benzene and derivatives thereof and beta-selective in the alkylation of naphthalene and derivatives thereof. There is provided a process for the production of such catalysts wherein a borosilicate type glass is reacted with a zeolite synthesis template. There is also provided a selective alkylation process for the alkylation of benzene and its derivatives and of naphthalene and its derivatives wherein these are reacted with an alkylation agent in the presence of such catalyst.
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4.发明公开Silica-modified catalyst and use for selective production of para-dialkyl substituted benzenes 失效二氧化硅改性催化剂和用于选择性生产对二苯基取代的苯乙烯的用途
公开(公告)号：EP0128721A3
公开(公告)日：1986-09-24
申请号：EP84303751
申请日：1984-06-04
CPC分类号： C07C6/126 , B01J29/40 , B01J29/65 , B01J29/70 , B01J29/80 , B01J37/0219 , B01J37/082 , B01J37/086 , B01J2229/12 , B01J2229/32 , C07C2/66 , C07C2/861 , C07C2/864 , C07C2/865 , C07C2/868 , C07C6/123 , C07C2529/40 , C07C2529/65 , C07C2529/70 , Y02P20/52 , C07C15/02 , C07C15/08
摘要： The present invention relates to a method for preparing a zeolite composition comprising a crystalline zeolite having deposited thereon a coating of silica which extensively covers and resides substantially exclusively on the external surface thereof, and to the composition so prepared. The present invention also relates to a process for the selective conversion of aromatic hydrocarbon feedstocks to a product rich in para-dialkyl substituted benzenes over a catalyst composition comprising such a silica-modified zeolite composition.
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公开(公告)号：EP0154753A3
公开(公告)日：1986-01-02
申请号：EP84309097
申请日：1984-12-27
申请人： UOP INC.
发明人： Imai, Tamotsu
CPC分类号： C07C2/862 , C07C2521/04 , C07C2521/12 , C07C2523/06 , C07C2523/26 , C07C2523/72 , Y02P20/52 , C07C15/02
摘要： Alkylaromatic compounds are synthesized by reacting aromatic compounds with a mixture of carbon monoxide and hydrogen in the presence of a dual-fuction catalyst system comprising (1) a composite of oxides of copper, zinc and either aluminum or chromium and (2) an aluminosilicate in crystalline or amorphous form.
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公开(公告)号：EP0106158A3
公开(公告)日：1986-07-02
申请号：EP83109033
申请日：1983-09-13
发明人： Yang, Duck Joo
CPC分类号： C07C2/12 , B01J21/08 , B01J29/035 , B01J29/88 , B01J37/0217 , B01J2229/12 , B01J2229/32 , C07C2/864 , C07C2521/08 , C07C2529/035 , C07C2529/06 , Y02P20/52 , Y10S423/22 , C07C15/08
摘要： Process for coating crystalline silica polymorphs such as silicalites and zeolites with amorphous silica using alkali metal silicates as the source of silica.
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7.发明公开
公开(公告)号：EP0085342A3
公开(公告)日：1984-10-17
申请号：EP83100373
申请日：1983-01-18
CPC分类号： C07C2/864 , B01J29/06 , C01B39/02 , C07C1/20 , C07C5/222 , C07C5/2737 , C07C2521/12 , Y02P20/52 , C07C15/06 , C07C15/08
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公开(公告)号：EP0256228A3
公开(公告)日：1988-10-05
申请号：EP87107621
申请日：1987-05-25
CPC分类号： C07C2/864 , C07C2529/08 , C07C2529/60 , C07C2529/70 , C07C2601/10 , C07C13/15
摘要： A process for producing an alkylcyclopentadiene derivative comprises the vapor-phase reaction of a cyclopentadiene derivative and an aliphatic lower alcohol in the presence of a crystalline aluminosilicate catalyst containing an alkali metal.
摘要翻译： 制备烷基环戊二烯衍生物的方法包括环戊二烯衍生物和脂族低级醇在含有碱金属的结晶硅铝酸盐催化剂存在下的气相反应。
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9.发明公开
公开(公告)号：EP0174121A3
公开(公告)日：1988-01-07
申请号：EP85305825
申请日：1985-08-16
IPC分类号： C01B33/28 , C01B35/12 , C01B33/20 , C01G17/00 , C01G37/14 , C01G49/00 , B01J29/28 , B01J29/04 , C07C02/86 , C07C06/12 , C07C02/00
CPC分类号： B01J29/7026 , B01J29/40 , B01J29/70 , C01B39/48 , C07C2/00 , C07C2/66 , C07C2/864 , C07C4/06 , C07C6/08 , C07C6/123 , C07C2529/70 , Y02P20/52 , C07C15/02 , C07C15/08
摘要： A synthetic porous zeolite, identified as ZSM-57, a method for its preparation and use thereof in catalytic conversion of organic compounds are disclosed. The crystalline zeolite has a molar ratio of XO,: Y,O, of at least 4, wherein X represents silicon and/or germanium and Y represents aluminum, boron, chromium, iron and/or gallium and the characteristic X-ray diffraction shown in Table 1. The silica/alumina form of this crystalline material may be prepared with a directing agent in the form of a N,N,N,N'.N',N'-hexaethylpentane-diammonium compound.
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10.发明公开Method for promoting the activity and/or extending the life of cation-exchangeable layered clay catalysts in proton-catalysed reactions 失效用于促进活性和/或延长可交换层状催化剂在原子催化反应中的寿命的方法
公开(公告)号：EP0073141A3
公开(公告)日：1984-02-01
申请号：EP82304375
申请日：1982-08-19
发明人： Gregory, Reginald
CPC分类号： B01J21/16 , B01J29/049 , B01J2229/42 , C07C2/66 , C07C2/864 , C07C67/04 , C07C2521/16 , Y10S502/514 , C07C15/00 , C07C69/14
摘要： A method for promoting the activity and/or extending the life of a cation-exchangeable layered clay catalyst in reactions susceptible to catalysis by protons which method comprises the addition to the catalyst of water as the sole additive. The quantity of water employed is suitably up to 40°C. preferably up to 10% based on weight of reactants. The layered clay catalyst can be for example montmorillonite, bentonite or vermiculite. Suitable proton catalysed reactions include formation of esters, (eg by reaction of olefin and carboxylic acid), ethers, aldehydes, thioethers and alkylation and cracking reactions.
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