摘要:
To provide a curable composition which has favorable insulating property and liquid repellency, and from which a cured film having liquid repellency capable of being sufficiently converted to be liquid-philic even by irradiation with ultraviolet light having a wavelength of at least 300 nm, can be formed; an article having a cured film obtained by curing the curable composition and its production process. A cured film is formed by using a curable composition comprising a polymer having units (u1) based on a compound represented by the following formula (m1):
wherein R 1 = a hydrogen atom, a methyl group or the like; R 2 = a bivalent organic group or the like; Cf= a C 1-20 fluoroalkyl group or the like, X=O, S, N or NH; m= 1 to 2; n= 0 to 4; k= 0 to 1; and Z= a (meth)acryloyl group or the like.
摘要翻译:提供一种具有良好的绝缘性和疏液性的固化性组合物,并从其中能够充分转化即使通过用具有至少300纳米的波长的紫外线照射是亲液的固化具有膜疏液性,可以是 形成的; 到制品具有固化膜获得通过固化可固化组合物及其生产方法。 一种固化膜,通过使用可固化组合物,其包括基于由下述式(M1)表示的化合物的聚合物具有单元(U1)形成的:worin,R 1 =氢原子,甲基等; R 2 =的二价有机基团等; CF = C 1-20的氟烷基等,X = O,S,N或NH; M = 1至2; n = 0至4; k = 0至1; 和Z =(甲基)丙烯酰基等。
摘要:
A kind of ketoxime ester compound used as photoinitiator, especially a kind of ketoxime ester photoinitiator used as the photocuring material, wherein said ketoxime ester photoinitiator has following general formula (I): wherein R 1 is formula (II), n is the integer of 1ˆ¼4, m is the integer of 1ˆ¼6; R 2 is C1-8 alkyl, phenyl, substituted phenyl, benzyl, or substituted benzyl; R 3 is diphenylthioether group, substituted diphenylthioether group, carbazyl group or substituted carbazyl. The ketoxime ester photoinitiator solves the problems that the existing ketoxime ester photoinitiator such as OXE-1 has bad application performance and bad thermal stability.
摘要:
A kind of ketoxime ester compound used as photoinitiator, especially a kind of ketoxime ester photoinitiator used as the photocuring material, wherein said ketoxime ester photoinitiator has following general formula (I): wherein R 1 is formula (II), n is the integer of 1∼4, m is the integer of 1∼6; R 2 is C1-8 alkyl, phenyl, substituted phenyl, benzyl, or substituted benzyl; R 3 is diphenylthioether group, substituted diphenylthioether group, carbazyl group or substituted carbazyl. The ketoxime ester photoinitiator solves the problems that the existing ketoxime ester photoinitiator such as OXE-1 has bad application performance and bad thermal stability.
摘要翻译:一种用作光引发剂的酮肟酯化合物,特别是一种用作光固化材料的酮肟酯光引发剂,其中所述酮肟酯光引发剂具有以下通式(I):其中R 1为式(II),n为 1 = 4,m为1/6的整数; R 2是C 1-8烷基,苯基,取代的苯基,苄基或取代的苄基; R 3为二苯硫醚基,取代二苯硫醚基,咔唑基或取代咔唑基。 酮肟酯光引发剂解决了现有的酮肟酯光引发剂如OXE-1的应用性能差,热稳定性差的问题。
摘要:
Compounds of the formulae I, II, and III wherein R1 is for example hydrogen, C3-C8 cycloalkyl, C1-C12alkyl, phenyl unsubstituted or substituted; R2 and R2' for example are hydrogen, C1-C20alkyl, C3-C8cycloalkyl or phenyl, unsubstituted or substituted, or are (I) (I) or (I); Ar1 is for example phenyl, optionally substituted by e.g. (CO)R7, (I)(D), (I)(E) and/or(I)(F); Ar2 is for example phenylene, optionally substituted e.g. by (CO)R7, (D), (E)or (F); Ar3 is for example phenyl; M1,M2 and M3 are, for example, C1-C20alkylene; M4 is for example direct bond, -O-, -S-, -Y-(C1-C10alkylene)-Y'-, optionally substituted;Y and Y' are for example a direct bond or O; R7is for example hydrogen, C1-C20alkyl or phenyl, optionally substituted; R8, R9, R8'and R9' are for example hydrogen or C1-C12alkyl, exhibit an unexpectedly good performance in photopolymerization reactions.
摘要翻译:式I,II和III的化合物,其中R 1是例如氢,C 3 -C 8环烷基,C 1 C 12 -C 12烷基,未取代或取代的苯基; R 2和R 2是例如氢,C 1 -C 20烷基,C 1 -C 20烷基,C 1 -C 12烷基, 3个C 8环烷基或未取代或取代的苯基,或者Ar 1是例如苯基,任选地被例如 Ar 2是例如亚苯基,任选被取代的例如亚苯基。 (CO)R 7,(D),(E)或(F); Ar 3是例如苯基; M 1,M 2和M 3是例如C 1 -C 20, / SUB>亚烷基; M 4是例如直接键合,-O - , - S - , - Y-(C 1 -C 10亚烷基)-Y ' - ,任选取代; Y和Y'例如是直接键或-O-; R 7是例如氢,C 1 -C 20烷基或任选被取代的苯基; R 8,R 9,R 8和R 9是例如氢或C 1 -C 8烷基, 1 -C 12烷基,在光聚合反应中表现出出乎意料的良好性能。
摘要:
A process for preparing indanylamine and aminotetralin derivatives from indanone or tetralone oximes by acylating the oximes with an organic anhydride, followed by catalytic hydrogenation in the presence of an organic anhydride with subsequent hydrolysis is described. The process is commercially feasible providing indanylamine and aminotetralin derivatives in high yield that are useful as intermediates in the production of therapeutically active compounds. Also described are novel intermediates, 1-indanone O-acetyl oximes and 1-tetralone O-acetyl oximes.
摘要:
Compounds of the formulae I, II, and III wherein R1 is for example hydrogen, C3-C8 cycloalkyl, C1-C12alkyl, phenyl unsubstituted or substituted; R2 and R2' for example are hydrogen, C1-C20alkyl, C3-C8cycloalkyl or phenyl, unsubstituted or substituted, or are (I) (I) or (I); Ar1 is for example phenyl, optionally substituted by e.g. (CO)R7, (I)(D), (I)(E) and/or(I)(F); Ar2 is for example phenylene, optionally substituted e.g. by (CO)R7, (D), (E)or (F); Ar3 is for example phenyl; M1,M2 and M3 are, for example, C1-C20alkylene; M4 is for example direct bond, -O-, -S-, -Y-(C1-C10alkylene)-Y'-, optionally substituted;Y and Y' are for example a direct bond or O; R7is for example hydrogen, C1-C20alkyl or phenyl, optionally substituted; R8, R9, R8'and R9' are for example hydrogen or C1-C12alkyl, exhibit an unexpectedly good performance in photopolymerization reactions.