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    Optically active naphthalene derivative, process for preparation thereof, liquid crystal composition containing the same as effective component, and liquid crystal element using the same
    6.
    发明公开
    Optically active naphthalene derivative, process for preparation thereof, liquid crystal composition containing the same as effective component, and liquid crystal element using the same 失效
    光学活性的萘衍生物，其制备方法，涉及萘衍生物作为含有液晶组合物和使用该组合物的液晶显示器的活性成分。

    公开(公告)号：EP0416946A2

    公开(公告)日：1991-03-13

    申请号：EP90309841.6

    申请日：1990-09-07

    申请人： SUMITOMO CHEMICAL COMPANY, LIMITED

    发明人： Toda, Shoji ,  Higashii, Takayuki ,  Kurimoto, Isao ,  Minai, Masayoshi ,  Sekine, Chizu ,  Tani, Takeshi ,  Fujisawa, Koichi

    IPC分类号： C07C69/616 ,  C09K19/32 ,  C07C43/164 ,  C07C39/14 ,  C07C33/28 ,  C07C49/788 ,  G02F1/13

    CPC分类号： C09K19/322 ,  C07C33/18 ,  C07C43/1782 ,  C07C43/2055 ,  C07C43/23 ,  C07C45/59 ,  C07C45/673 ,  C07C45/71 ,  C07C65/24 ,  C07C69/017 ,  C07C69/76 ,  C07C69/92 ,  C07C49/215 ,  C07C49/84

    摘要： Disclosed herein are a novel optically active naphthalene derivative, a process of the preparation thereof a ferroelectric liquid crystal composition containing the same and a liquid crystal element using the composition.
    The above optically active naphthalene derivatives including optically active naphthylcarboxylic acid derivative, hydroxynaphthalene derivative, alkoxynaphthylalkanol derivative and alkylnaphthylalkanol derivative have the following structural formula:
    wherein R' denotes an alkyl group of 3-20 carbon atoms, R 2 denotes an alkyl group of 1-20 carbon atoms optionally substituted with halogen atom(s) or an alkoxyalkyl group of 2-20 carbon atoms optionally substituted with halogen atom(s), X denotes -COO- or -OCO-, k, t and m denotes 0 or 1 respectively, n denotes an integer of 0-6, p denotes 0 or 1, and an asterisk indicates an asymmetric carbon atom, proviso when k is 0, t and m are not 1 at the same time, when k is 1, m is 1, and when n is 0 and m is 1, X is -COO-.
    These optically active naphthalene derivatives are useful as a ferroelectric liquid crystal material or its component having a sufficient spontaneous polarization and by which a high speed response is possible and which further exhibits a ferroelectric liquid crystal phase in a temperature region around room temperature.

    摘要翻译： 公开是一种新颖的光学活性的萘衍生物，其制备铁电液晶组合物含有相同和使用该组合物的液晶元件的方法。 上述光学活性的萘衍生物，包括旋光活性naphthylcarboxylic酸衍生物，羟基衍生物，alkoxynaphthylalkanol衍生物和衍生物alkylnaphthylalkanol具有以下结构式： worin - [R <1>表示在烷基3-20个碳原子的，R <2> 表示在烷基有卤原子（一个或多个），或在用卤素原子（一个或多个）中，X表示-COO-或-OCO-，K，L任选被取代的2-20个碳原子的烷氧基烷基任选被取代的1-20个碳原子的 并且m分别表示0或1，n表示至0-6整数，p表示0或1，以及星号表示不对称碳原子，前提条件当k为0，l和m不为1的同时，当 k是1，m是1，当n是0且m是1，X是-COO-。 这些光学活性的萘衍生物是作为铁电液晶材料或具有自发极化的充其成分和通过该高速响应是可能的，并且其进一步展品在室温附近的温度区域中的铁电液晶相是有用的。

    Novel tri-phenyl alkane and alkene derivatives and their preparation and use
    7.
    发明公开
    Novel tri-phenyl alkane and alkene derivatives and their preparation and use 失效
    三苯基烷烃 -alkenderivate，ihre Herstellung und Verwendung。

    公开(公告)号：EP0095875A2

    公开(公告)日：1983-12-07

    申请号：EP83302912.7

    申请日：1983-05-20

    申请人： Farmos Group Ltd.

    发明人： Toivola, Reijo Juhani ,  Karjalainen, Ario Johannes ,  Kurkela, Kauko Oiva Antero ,  Soderwall, Marja-Liisa ,  Kangas, Lauri Veikko Matti ,  Blanco, Guillermo Luis ,  Sundquist, Hannu Kalervo

    IPC分类号： C07C33/26 ,  C07C33/28 ,  C07C39/14 ,  C07C39/15 ,  A61K31/34 ,  C07C39/17 ,  C07C43/23 ,  C07C69/157 ,  C07C69/78 ,  C07C93/06 ,  C07C143/68

    CPC分类号： C07D295/088 ,  C07C29/095 ,  C07C29/10 ,  C07C29/1285 ,  C07C33/26 ,  C07C33/28 ,  C07C39/12 ,  C07C39/21 ,  C07C39/367 ,  C07C39/373 ,  C07C43/1782 ,  C07C43/225 ,  C07C43/23 ,  C07C69/157 ,  C07C69/16 ,  C07C69/78 ,  C07C309/00 ,  C07D307/06 ,  C07D307/12 ,  C07D307/14 ,  C07D309/04 ,  C07D309/12

    摘要： The invention provides novel compounds of the formula:
    and
    wherein m is 1 or 2, R 6 and R 7 , which can be the same or different are H or an alkyl group of 1 to 4 carbon atoms, or
    wherein n is 0 to 4, R 1 and R 2 , which can be the same or different are H, OH, alkoxy of 1 to 4 carbon atoms, benzyloxy or methoxymethoxy; R 3 is H, OH, halogen, alkoxy of 1 to 4 carbon atoms, benzyloxy, methoxymethoxy, 2,3-dihydroxypropoxy or
    can form an N-containing three-, four-, five- or six-membered heterocyclic ring; R 4 is OH, F, Cl, Br, I, mesyloxy, tosyloxy, formyloxy, alkylcarbonyloxy of 1 to 4 carbon atoms or CH 2 R 4 is replaced by CHO; R 5 is H or OH; or R 4 and R 5 together form an -0- bridge between the carbon atoms to which they are attached, and their non-toxic pharmaceutically acceptable salts and esters and mixtures thereof. Processes for the preparation of these compounds are described, and also novel pharmaceutical compositions containing them. These compounds exhibit valuable pharmacological properties as estrogenic, anti-estrogenic, and progestanic agents. They are also effective against oestrogen-dependent tumours. Certain compounds are useful as chemical intermediates for the preparation of pharmacologically active compounds of the invention.

    摘要翻译： 本发明提供下式的新型化合物：其中m为1或2，R6和R7可相同或不同，为H或1至4个碳原子的烷基，或其中n 是0至4，可以相同或不同的R 1和R 2是H，OH，1至4个碳原子的烷氧基，苄氧基或甲氧基甲氧基; R3是H，OH，卤素，1-4个碳原子的烷氧基，苄氧基，甲氧基甲氧基，2,3-二羟基丙氧基或可以形成含N的三，四，五或六元杂环; R4是OH，F，Cl，Br，I，甲磺酰氧基，甲苯磺酰氧基，甲酰氧基，1至4个碳原子的烷基羰氧基或CH 2 R 4被CHO取代; R5是H或OH; 或R4和R5一起在它们所连接的碳原子之间形成-O-桥，以及它们的无毒的药学上可接受的盐和酯及其混合物。 本发明描述了制备这些化合物的方法，以及含有它们的新型药物组合物。 这些化合物显示出有价值的药理学性质，如雌激素，抗雌激素和孕激素。 它们也有效抵抗雌激素依赖性肿瘤。 某些化合物可用作制备本发明的药理活性化合物的化学中间体。