Process for the production of trimellitic acid
    5.
    发明公开
    Process for the production of trimellitic acid 有权
    Verfahren zur Herstellung vonTrimellitsäure

    公开(公告)号:EP1728778A1

    公开(公告)日:2006-12-06

    申请号:EP05425324.0

    申请日:2005-05-13

    Applicant: LONZA S.P.A.

    CPC classification number: C07C51/265 C07C63/307

    Abstract: Trimellitic acid is produced by oxidation of pseudocumene in acetic acid at temperatures between 130 and 240 °C in the presence of a catalyst composition containing cobalt, manganese and bromine. The process comprises the stages of
    (i) simultaneously feeding pseudocumene and air or an oxygen-containing gas into a solution containing acetic acid and the catalyst composition, at an addition rate resulting in an oxygen concentration in the off-gas of less than 8 vol%, and at a temperature and a pressure sufficient to result in 5 to 25 mol% of the total amount of oxygen required to oxidize the pseudocumene to trimellitic acid being consumed, and
    (ii) feeding air or an oxygen-containing gas into the reaction mixture obtained in stage (i) until essentially all of the pseudocumene has been consumed and a molar yield of trimellitic acid of at least 90% has been obtained.
    There is no supplementation of catalyst after stage (i).

    Abstract translation: 在含有钴,锰和溴的催化剂组合物的存在下,在130-240℃的温度下,在乙酸中氧化假枯烯来制备偏苯三酸。 该方法包括以下阶段:(i)同时将假阳离子和空气或含氧气体同时地加入到含有乙酸和催化剂组合物的溶液中,加入速率导致废气中的氧浓度小于8vol %,并且在足以导致将假枯烯氧化成偏苯三酸被消耗所需的氧的总量的5至25mol%的温度和压力下,和(ii)将空气或含氧气体进料到反应中 在步骤(i)中获得的混合物直到基本上所有的假枯烯已被消耗,并且已经获得至少90%的偏苯三酸的摩尔收率。 在阶段(i)之后没有催化剂的补充。

    METHOD OF PRODUCING TRIMELLITIC ACID
    6.
    发明公开
    METHOD OF PRODUCING TRIMELLITIC ACID 审中-公开
    用于生产偏苯三

    公开(公告)号:EP1551787A4

    公开(公告)日:2006-07-05

    申请号:EP03700610

    申请日:2003-01-07

    CPC classification number: C07C51/265 C07C63/307

    Abstract: Disclosed is a method of producing trimellitic acid through the liquid-phase oxidation of pseudocumene in acetic acid. The oxidation comprises a) conducting a first oxidation using an initial oxidizing catalytic system at 120-200¡É for 5-20 min in an oxidizing reactor, said initial oxidizing catalytic system comprising at least three compounds selected from the group consisting of cobalt compound, manganese compound, zirconium compound and bromine compound; b) conducting a second oxidation in situ at 160-220¡É for 30-60 min under addition of an additional catalytic system, said additional catalytic system comprising at least two compounds selected from the group consisting of cobalt compound, manganese compound, zirconium compound, and bromine compound; and c) completing the oxidation of pseudocumene at a temperature from 180 to 230¡É for a time from 5 to 20 min without the addition of catalysts into the reactor. The pressure is adjusted in the range from 100 to 450 psig over the steps a), b) and c).

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