PYRAZOLOPYRIMIDINES, INTERMEDIATES THEREOF AND PROCESSES FOR THE PREPARATION OF THEM
    2.
    发明公开
    PYRAZOLOPYRIMIDINES, INTERMEDIATES THEREOF AND PROCESSES FOR THE PREPARATION OF THEM 失效
    吡唑并嘧啶,其中间体及其制备方法

    公开(公告)号:EP0234514A3

    公开(公告)日:1988-10-19

    申请号:EP87102392

    申请日:1987-02-19

    CPC分类号: C07D487/04 C07D231/48

    摘要: Disclosed is a process for preparing a 3-hydroxy-7-­ mercaptopyrazolo[4,3-d]pyrimidine compound represented by the general formula (IX): wherein R¹ is a hydrogen atom, an alkyl group having l to 4 carbon atoms, a phenyl group or a substituted phenyl group, which comprises:
        from a pyrazole compound represented by the general formula (III): wherein R¹ is the same as defined above.
    Also disclosed are pyrazole compounds represented by the general formula (I): wherein:
        R¹ is a hydrogen atom, an alkyl group having l to 4 carbon atom, a phenyl group or a substituted phenyl group:
        X is a nitroso group, an amino group or (R²)₂NCH=N- ­ (wherein R² is an alkyl group having l to 3 carbon atoms): and
        Y is -C(O)NH₂ when R¹ is an alkyl group having l to 4 carbon atoms, a phenyl group or a substituted phenyl group and X is a nitroso group, or -C(O)NH₂ when R¹ is a hydrogen atom, an alkyl group having l to 4 carbon atoms, a phenyl group or a substituted phenyl group and X is an amino group, or CN or -C(S)NH₂ when R¹ is a hydrogen atom, an alkyl group having l to 4 carbon atoms, a phenyl group or a substituted phenyl group and X is (R²)₂NCH=N- (wherein R² is the same as defined above. The compounds serve as intermediate for preparing the compound of the formula (IX).

    Color photographic light-sensitive material
    5.
    发明公开
    Color photographic light-sensitive material 失效
    彩色照相感光材料

    公开(公告)号:EP0127162A3

    公开(公告)日:1987-02-25

    申请号:EP84106000

    申请日:1984-05-25

    摘要: A silver halide color photographic light-sensitive material comprising a support having coated thereon at least one silver halide emulsion layer, the color photographic light-sensitive material having at least one layer containing at least one 2-equivalent magenta coupler of the 5-pyrazolone type represented by the following general formula (I):
    wherein W represents a phenyl group substituted with at least one substituent selected from the group consisting of a halogen atom, an alkyl group, an alkoxy group, an alkoxycarbonyl group and a cyano group; Y represents an acylamino group or an anilino group; and Z represents a group capable of being released upon coupling, and at least one compound represented by the following general formula (II):
    wherein R' and R Z , which may be the same or different, each represents a hydrogen atom, an alkyl group or an aryl group, provided that both R' and R' do not represent hydrogen atoms atthe same time; Z' represents a methine group, a substituted methine group orthe group-N=; and Q represents an atomic group which contains a nitrogen atom, a sulfur atom or an oxygen atom and is necessary to form a 5-membered ora 6-membered heterocyclic ring together with the group-C=Z 1 -. The silver halide color photographic light-sensitive material can provide an excellent magenta color image without the occurrence of stain, even when the color photographic material is processed in a processing solution under the running condition.

    摘要翻译: 1,一种卤化银彩色摄影感光材料,它包括一个载有至少一层卤化银乳剂层的载体,该彩色摄影感光材料至少有一层含有至少一种5-吡唑啉酮型的2当量品红成色剂 (I)表示:其中W表示被至少一个选自卤素原子,烷基,烷氧基,烷氧基羰基和氰基的取代基取代的苯基; Y代表酰氨基或苯胺基; Z表示能够在偶联时释放的基团,以及至少一种由以下通式(II)表示的化合物:其中R'和RZ可以相同或不同,各自表示氢原子,烷基 或芳基,条件是R'和R'两者不同时代表氢原子; Z'表示次甲基,取代的次甲基或N = Q表示含有氮原子,硫原子或氧原子的原子团,并且与基团-C = Z1-一起形成5元或6元杂环所必需的基团。 卤化银彩色照相感光材料即使在彩色照相材料在运行条件下在处理液中处理时,也可以提供优异的品红色彩色图像而不会发生色斑。