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    PROCÉDÉ DE PRÉPARATION DE MÉTHYLMERCAPTAN
    6.
    发明公开
    PROCÉDÉ DE PRÉPARATION DE MÉTHYLMERCAPTAN 审中-公开
    PROCÉDÉDEPRÉPARATIONDEMÉTHYLMERCAPTAN

    公开(公告)号：EP3164381A1

    公开(公告)日：2017-05-10

    申请号：EP15736577.6

    申请日：2015-06-29

    申请人： Arkema France

    发明人： FREMY, Georges ,  BARRE, Patrice ,  RAYMOND, Jean-Michel

    IPC分类号： C07C319/02 ,  C07C319/24

    摘要： The present invention relates to a method for preparing methyl mercaptan, in batches or continuously, preferably continuously, said method including at least the following steps: a) reacting at least one hydrocarbon feedstock in the presence of hydrogen sulphide (H
    2 S) and optionally sulphur (S) such as to form carbon disulphide (CS
    2 ) and hydrogen (H
    2 ); b) reacting said carbon disulphide (CS
    2 ) by hydrogenation in the presence of said hydrogen (H2) obtained in step a) such as to form methyl mercaptan (CH
    3 SH), hydrogen sulphide (H
    2 S) and possibly hydrogen (H
    2 ); c) optionally recirculating said hydrogen sulphide (H
    2 S) formed during step b) to step a); and d) recovering the methyl mercaptan.

    摘要翻译： 本发明涉及分批或连续，优选连续地制备甲硫醇的方法，所述方法至少包括以下步骤：a）使至少一种烃原料在硫化氢（H 2 S）和任选的硫（ S）以形成二硫化碳（CS2）和氢气（H2）; b）通过在步骤a）中获得的所述氢（H 2）存在下氢化所述二硫化碳（CS 2）以形成甲硫醇（CH 3 SH），硫化氢（H 2 S）和可能​​的氢（H 2）; c）任选地将步骤b）中形成的所述硫化氢（H 2 S）再循环至步骤a）; 和d）回收甲硫醇。