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    BIPYRIDYL COMPOUND
    6.
    发明公开
    BIPYRIDYL COMPOUND 有权
    BIPYRIDYLVERBINDUNG

    公开(公告)号：EP3101004A1

    公开(公告)日：2016-12-07

    申请号：EP15744067.8

    申请日：2015-01-29

    申请人： Japan Science and Technology Agency

    发明人： KUNINOBU, Yoichiro ,  KANAI, Motomu ,  IDA, Haruka ,  NISHI, Mitsumi

    IPC分类号： C07D213/53 ,  B01J31/22 ,  C07B61/00 ,  C07F5/04

    CPC分类号： C07D213/53 ,  B01J31/1815 ,  B01J31/22 ,  B01J2231/40 ,  B01J2231/4277 ,  B01J2531/827 ,  C07F15/0033

    摘要： There are provided a compound capable of being a novel ligand allowing regioselective borylation to be performed in the aromatic borylation reaction, and a catalyst using the same compound. There is provided a bipyridyl compound represented by a general formula (1):
    (wherein A represents a single bond, a vinylene group or an ethynylene group;
    X represents an oxygen atom or a sulfur atom;
    n pieces of R 1 may be the same or different, and R 1 represents a hydrogen atom, a halogen atom, an optionally substituted hydrocarbon group, an optionally substituted alkoxy group, an optionally substituted aryloxy group, an optionally substituted amino group, a cyano group, a nitro group, or an alkoxycarbonyl group, or two adjacent R 1 may form a saturated or unsaturated ring structure optionally containing a hetero atom together with the carbon atoms bonded to the two R 1 ;
    R 2 represents a hydrogen atom, an optionally substituted hydrocarbon group, an optionally substituted alkoxy group, or an optionally substituted aryloxy group;
    and
    n represents a number of 1 to 4).

    摘要翻译： 提供能够作为在芳族硼酸化反应中进行区域选择性硼酸化的新配体的化合物和使用相同化合物的催化剂。 提供由通式（1）表示的联吡啶基化合物：其中A表示单键，亚乙烯基或亚乙炔基; X表示氧原子或硫原子; n个R 1可以相同 或不同，R 1表示氢原子，卤素原子，任选取代的烃基，任选取代的烷氧基，任选取代的芳氧基，任选取代的氨基，氰基，硝基或烷氧基羰基 基团或两个相邻的R 1可以形成任选地含有杂原子和与两个R 1键合的碳原子的饱和或不饱和环结构; R 2表示氢原子，任选取代的烃基，任选取代的烷氧基 ，或任选取代的芳氧基; n表示1〜4的数）。