Abstract:
PROBLEM TO BE SOLVED: To provide a method for economically and efficiently producing a high-purity aromatic carboxylic acid dianhydride having an ester group.SOLUTION: The method for producing the aromatic carboxylic acid dianhydride having the ester group by reacting acid chloride of trimellitic anhydride with an aromatic dihydroxy compound in the presence of a base uses acetonitrile as a reaction solvent. As a result, water-washing operation for removing by-produced hydrochloride becomes unnecessary, and a treating operation for returning a hydrolyzed product to the original becomes also unnecessary. Consequently, an impurity inhibiting the high purification is not formed. The aromatic carboxylic acid dianhydride free from such the impurity is suitable as a polymerization raw material because the impurity becomes an inhibiting factor for the polymerization reaction when using the aromatic carboxylic acid dianhydride as the polymerization raw material.
Abstract:
PROBLEM TO BE SOLVED: To provide an epoxy (meth)acrylate resin which provides a cured product, excellent in developability in a dilute alkali aqueous solution and excellent in photo curability, flexibility and bending property, and to provide a curable resin composition containing the same resin and the cured product thereof.SOLUTION: A reaction product (c) of dicarboxylic acids (a) and an unsaturated-group containing mono-epoxy compound (b) is reacted with diols (d) and diisocyanates (e) to provide a reaction product (f), which is further reacted with a bifunctional epoxy compound (g), an unsaturated-group containing monocarboxylic acid (h) and a polybasic acid anhydride (i) to provide the epoxy (meth)acrylate resin. The curable composition containing the same resin and the cured product thereof are provided.
Abstract:
PROBLEM TO BE SOLVED: To provide a method for producing high-purity bis(3-nitro-4-hydroxyphenyl) represented by formula (1) wherein X represents CH 2 or CHCH 3 , at a high yield. SOLUTION: The method includes nitrating bis(4-hydroxyphenyl)methane or bis(4-hydroxyphenyl)ethane with nitric acid in an aromatic hydrocarbon solvent. COPYRIGHT: (C)2010,JPO&INPIT
Abstract:
PROBLEM TO BE SOLVED: To provide a method for efficiently producing a polyisoxazole compound in high yield by using a polyfunctional chloro-oxime as starting material, generating a polyfunctional nitrile oxide in the system, and then conducting a cyclopolyaddition between the polyfunctional nitrile oxide and a polyfunctional unsaturated monomer, while enabling side reactions to be suppressed. SOLUTION: The method for producing a polyisoxazole having in the main chain an isoxazole skeleton and/or isoxazoline skeleton includes a step of conducting a reaction between a polyfunctional unsaturated monomer having in the molecule two or more carbon-carbon unsaturated bonds and a polyfunctional chloro-oxime having in the molecule two or more (hydroxyimino)chloromethyl groups in the presence of a base. COPYRIGHT: (C)2010,JPO&INPIT
Abstract:
PROBLEM TO BE SOLVED: To provide a trifunctional nitrile oxide having three nitrile oxide groups in the molecule and exhibiting relatively good stability, and to provide a method for producing the same. SOLUTION: The trifunctional nitrile oxide is represented by general formula (1), and a method for producing the trifunctional nitrile oxide, comprising preparing the trifunctional nitrile oxide from the corresponding triformyl compound through an oxime compound. In the general formula (1), R groups are preferably each independently H, an alkyl group or an alkoxy group. COPYRIGHT: (C)2010,JPO&INPIT
Abstract:
PROBLEM TO BE SOLVED: To provide an air separator capable of responding to a situation where oxygen demand is largely fluctuated from 0% to 100% or vice versa. SOLUTION: The air separator includes a fractionating tower for performing cryogenic liquefaction/separation of material air taken in from outside by using a difference of a boiling point to manufacture liquid oxygen and nitrogen gas and a liquid oxygen storage tank 3 for storing the liquid oxygen manufactured by the fractionating tower. The air separator is further provided with a heat exchanger 17 for liquefying the nitrogen gas manufactured by the fractionating tower and a liquid oxygen supply pump 4 for taking out the liquid oxygen stored in the liquid oxygen storage tank 3 and supplying the liquid oxygen to the heat exchanger 17 as a refrigerant. In accordance with the demand for oxygen gas, the liquid oxygen stored within the liquid oxygen storage tank 3 is supplied to the heat exchanger 17 and made to perform heat exchange with the nitrogen gas within the heat exchanger 17. Liquid nitrogen is generated by liquefying the nitrogen gas by cold heat of the liquid oxygen, and a necessary amount of oxygen gas is generated by vaporizing the liquid oxygen by warm heat of the nitrogen gas. COPYRIGHT: (C)2010,JPO&INPIT