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公开(公告)号:JPH11279509A
公开(公告)日:1999-10-12
申请号:JP9857098
申请日:1998-03-25
Applicant: Aica Kogyo Co Ltd , アイカ工業株式会社
Inventor: ISOBE SATORU , ASAI DAIJIRO
IPC: C09J131/04 , C09J11/06 , C09J129/14
Abstract: PROBLEM TO BE SOLVED: To remove the limitation of work life and improve the initial bond strength, water resistance and heat resistance by blending glyoxal with a vinyl acetate resin-based emulsion of a specific composition.
SOLUTION: This adhesive has 0.05-10 pts.wt. of gloxyal based on 100 pts.wt. of the resin solid content of a vinyl acetate resin-based emulsion which contains an acetoacetylated polyvinyl alcohol (hereinafter referred to as AA-ed PVA). The acetoacetylated PVA preferably has 0.1-15 mol% of residual acetic acid groups, an average degree of polymerization of 500-2,600 and an acetoacetyl group content of 2-8 mol%. The amount of the acetoacetylated PVA used as a protective colloid is suitably 2-20 pts.wt. based on the resin solid content of the vinyl acetate resin-based emulsion. As the vinyl acetate resin-based emulsion, for example, polyvinyl acetate resin-based emulsions, ethylene-vinyl acetate copolymer emulsions, vinyl acetate-acrylate copolymer emulsions and the like can be used.
COPYRIGHT: (C)1999,JPOAbstract translation: 要解决的问题:通过将乙二醛与具体组成的乙酸乙烯酯树脂基乳液混合来消除工作寿命的限制并提高初始粘合强度,耐水性和耐热性。 解决方案:该粘合剂具有0.05-10重量份 基于100 pts.wt. 含有乙酰乙酰化聚乙烯醇(以下称为AA-ed PVA)的乙酸乙烯酯树脂系乳液的树脂固体成分。 乙酰乙酰化PVA优选具有残留乙酸基团的0.1-15mol%,平均聚合度为500-2,600,乙酰乙酰基含量为2-8mol%。 用作保护胶体的乙酰乙酰化PVA的量适宜为2-20重量份 基于乙酸乙烯酯树脂基乳液的树脂固体含量。 作为乙酸乙烯酯树脂基乳液,可以使用例如聚乙酸乙烯酯树脂类乳液,乙烯 - 乙酸乙烯酯共聚物乳液,乙酸乙烯酯 - 丙烯酸酯共聚物乳液等。
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公开(公告)号:JP2935907B2
公开(公告)日:1999-08-16
申请号:JP41920790
申请日:1990-12-14
Applicant: SUMITOMO BEEKURAITO KK
Inventor: SUGIURA MICHIO , KAWAI IKUO
IPC: H05K3/38 , C09J129/14 , C09J161/20 , C09J161/28 , C09J163/00 , C09J175/00 , C09J175/04
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公开(公告)号:JPH1171564A
公开(公告)日:1999-03-16
申请号:JP23341797
申请日:1997-08-29
Applicant: HITACHI CHEMICAL CO LTD
Inventor: HORIUCHI TAKESHI , KUMAKURA YOSHITOSHI , NANAUMI KEN
IPC: C08J3/24 , B32B15/08 , C09J129/14 , C09J161/28 , C09J163/00 , H05K3/38
Abstract: PROBLEM TO BE SOLVED: To obtain an adhesive composition capable of giving laminates excellent in tracking resistance and heat resistance and used for printed circuit boards by adding an aromatic sulfonic acid as a curing accelerator to an adhesive composition comprising a polyvinyl acetal resin, a melamine resin and an epoxy resin. SOLUTION: This adhesive composition comprises 100 pts.wt. of a polyvinyl acetal resin, 40-100 pts.wt. of a melamine resin, 5-70 pts.wt. of an epoxy resin, and an aromatic sulfonic acid such as p-toluene sulfonic acid as a curing accelerator in an amount of 0.1-2 pts.wt. per 100 pts.wt. of the total amount of the polyvinyl acetal resin, the melamine resin and the epoxy resin. The composition is coated as a varnish on a metal foil and subsequently dried to give the metal foil having the adhesive.
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公开(公告)号:JP2809714B2
公开(公告)日:1998-10-15
申请号:JP16276789
申请日:1989-06-27
IPC: H05K3/18 , C09J109/02 , C09J129/14 , C23C18/20 , H05K3/38
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公开(公告)号:JPH10509138A
公开(公告)日:1998-09-08
申请号:JP51460496
申请日:1995-09-28
IPC: C07D319/08 , C08G8/36 , C09D161/06 , C09D161/28 , C09J129/04 , C09J129/14 , C09J161/06 , C09J161/28 , C09J163/00 , C09J201/00
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公开(公告)号:JP2671277B2
公开(公告)日:1997-10-29
申请号:JP438389
申请日:1989-01-11
IPC: B32B15/08 , C09J129/14 , C09J161/20 , C09J161/28 , C09J163/00 , C09J175/00 , H05K3/38
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公开(公告)号:JPH09258023A
公开(公告)日:1997-10-03
申请号:JP6073496
申请日:1996-03-18
Applicant: SUMITOMO CHEMICAL CO
Inventor: MATSUMOTO KOJI , HAYASHI SHIGETOSHI , KURATA NOBUYUKI
IPC: G02B5/30 , C09J129/04 , C09J129/14 , G02B1/08
Abstract: PROBLEM TO BE SOLVED: To provide a polarizing plate having excellent adhesiveness between polarizing film and a protective film and wet heat resistance. SOLUTION: The adhesive layer of the polarizing plate formed by sticking the protective film on at least one surface of the polyvinyl alcohol (PVA) polarizing film via the PVA adhesive layer consists of a PVA adhesive contg. a water- soluble epoxy compd. The ratio of the water-soluble epoxy compd. and PVA resin in the adhesive is specified to (5 to 50)/100 (by the weight of the solid content), thereby, the polarizing plate having the excellent adhesiveness of the polarizing film and the protective film and the wet heat resistance is obtd.
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公开(公告)号:JPH09124734A
公开(公告)日:1997-05-13
申请号:JP28030495
申请日:1995-10-27
Applicant: SEKISUI CHEMICAL CO LTD
Inventor: MIYAKE YOSHITAKA , KAMIYAMA TAKASHI
IPC: C08F8/28 , C08F16/38 , C09J129/14
Abstract: PROBLEM TO BE SOLVED: To obtain a process for producing a polyvinyl acetal resin contg. little metallic ion derived from an acetalization stopper even when an alkali metal hydroxide and/or an alkaline earth metal hydroxide is used as the stopper. SOLUTION: This polyvinyl acetal resin is obtd. by the acetalization of a modified polyvinyl alcohol having at least one kind of hydrophilic group selected from among COOM, SO3 M, OSO3 M, PO(OM)2 , and P(=O)(R)(OM) with an aldehyde, subject to the condition that after an alkali metal hydroxide and/or an alkaline earth metal hydroxide is used as the acetalization stopper, the resultant polyacetal resin is washed with an acid.
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公开(公告)号:JP2602524B2
公开(公告)日:1997-04-23
申请号:JP6267388
申请日:1988-03-15
IPC: C08L29/14 , C08L61/04 , C08L61/06 , C08L61/20 , C09J129/14 , C09J161/06 , C09J161/20 , H05K3/38
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公开(公告)号:JPH08238713A
公开(公告)日:1996-09-17
申请号:JP4603595
申请日:1995-03-07
Applicant: HITACHI CHEMICAL CO LTD
Inventor: NARABE YOSHIYUKI , YANO MASABUMI , ISHIHARA HIDEKI
IPC: B32B7/12 , B32B15/08 , B32B15/20 , C09J129/14 , C09J161/20 , C09J161/28 , C09J163/00 , H05K3/38
Abstract: PURPOSE: To obtain a coppered laminated plate with excellent moisture-proofness and antisilver migration. CONSTITUTION: Forty to eighty pts.wt. of melamine resin and 10 to 24 pts.wt. of epoxy resin are blended based on 100 pts.wt. of polyvinyl butylal. In addition, a copper foil is integrated with a base layer through an adhesive layer of at most 100ppm of metal ionic concentration in the polyvinyl butylal.
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