公开(公告)号：JP2005272404A

公开(公告)日：2005-10-06

申请号：JP2004090794

申请日：2004-03-26

Applicant: Takasago Internatl Corp ,  高砂香料工業株式会社

Inventor： SAWAKI TOMOYA ,  KENMOCHI HIROYUKI ,  HORI YASUSHI

IPC: C07C67/08 ,  C07C69/54

Abstract: PROBLEM TO BE SOLVED: To provide a method for producing a 2-alkyl-2-adamantyl (meth)acrylate having excellent physical properties such as excellent dry etching resistance in a semiconductor production process and useful as a semiconductor resist material in high pyrity and yield.
SOLUTION: The 2-alkyl-2-adamantyl (meth)acrylate expressed by general formula (2) (R
1 is a 1-3C alkyl; and R
2 is acryloyl group or methacryloyl group) is produced by reacting a 2-alkyl-2-adamantanol expressed by general formula (1) with an alkyl magnesium halide or a phenyl magnesium halide and then reacting with a (meth)acryloylation agent.
COPYRIGHT: (C)2006,JPO&NCIPI

Abstract translation: 要解决的问题：提供一种在半导体制造方法中制备具有优异的物理性能如耐腐蚀性优异的（甲基）丙烯酸2-金刚烷基酯的方法，并且可用作高半导体抗蚀剂材料 优惠和收益。 解决方案：由通式（2）表示的（甲基）丙烯酸-2-烷基-2-金刚烷基酯（R 1 SP 1）是1-3C烷基; R SP SP 2 >丙烯酰基或甲基丙烯酰基）是通过使由通式（1）表示的2-烷基-2-金刚烷醇与烷基卤化镁或苯基卤化镁反应，然后与（甲基）丙烯酰化剂反应制备的。 版权所有（C）2006，JPO＆NCIPI

公开(公告)号：JP2008110920A

公开(公告)日：2008-05-15

申请号：JP2006293124

申请日：2006-10-27

Applicant: Takasago Internatl Corp ,  高砂香料工業株式会社

Inventor： SAWAKI TOMOYA ,  SUZUKI KEN

IPC: C07F9/50 ,  B01J31/24 ,  C07B53/00 ,  C07B61/00 ,  C07C45/68 ,  C07C49/67 ,  C07C231/18 ,  C07C233/47 ,  C07F1/08 ,  C07F9/53 ,  C07F15/00 ,  C07F15/04

CPC classification number: Y02P20/52

Abstract: PROBLEM TO BE SOLVED: To provide an asymmetric synthesis catalyst having excellent performance as a catalyst for catalytic asymmetric synthesis reaction including chemical selectivity, enantio-selectivity, catalytic activity and the like, and a ligand therefor.
SOLUTION: The optically active phosphine compound is represented by formula (1) (wherein R
1 , R
4 and R
5 each represents a hydrogen atom, a (cyclo)alkyl group or the like; R
6 , R
7 , R
8 and R
9 each represents a (cyclo)alkyl group or the like; p+q and r+s are in the range of 0 to 5). Its use in an asymmetric synthesis reaction is disclosed.
COPYRIGHT: (C)2008,JPO&INPIT

Abstract translation: 要解决的问题：提供具有优异性能的不对称合成催化剂作为包括化学选择性，对映选择性，催化活性等的催化不对称合成反应的催化剂及其配体。 解决方案：光学活性膦化合物由式（1）表示（其中R 1，R 2，R 4和R 5各自表示 氢原子，（环）烷基等; R 6，R 7，R SP，R SP， / SP>各自表示（环）烷基等; p + q和r + s在0〜5的范围内）。 公开了其在不对称合成反应中的用途。 版权所有（C）2008，JPO＆INPIT

公开(公告)号：JP2005247745A

公开(公告)日：2005-09-15

申请号：JP2004060051

申请日：2004-03-04

Applicant: Takasago Internatl Corp ,  高砂香料工業株式会社

Inventor： SAWAKI TOMOYA ,  NAKAMURA JUNJI ,  HORI YASUSHI ,  NUMAZAWA SHIGEYOSHI

IPC: C07C69/54 ,  C07C67/08 ,  C07C67/14 ,  C07F1/02 ,  C07F3/02

Abstract: PROBLEM TO BE SOLVED: To provide a new monomer having a cyclohexane structure replaced with a plurality of alkyl groups and capable of providing a polymer such as a resist material responsive to high energy beam, excellent in sensitivity, resolution property and etching resistance and useful for fine processing with electron beam and far-ultraviolet light and to provide a method for producing the monomer. SOLUTION: The (meth)acrylate is represented by general formula (1) (wherein R 1 , R 2 and R 3 may be same or different and they are each an alkyl group; R 4 is a hydrogen atom or a methyl group). The method for producing the compound comprises using a metal or a metal compound. COPYRIGHT: (C)2005,JPO&NCIPI

Abstract translation: 要解决的问题：提供具有被多个烷基取代的环己烷结构的新型单体，并能够提供对高能束响应的聚合物如抗蚀剂材料，灵敏度，分辨率和耐蚀刻性优异 并且可用于用电子束和远紫外光的精细加工，并提供制备单体的方法。 解决方案：（甲基）丙烯酸酯由通式（1）表示（其中R 1 ，R 2 和R 3 相同或不同，它们各自为烷基; R 4为氢原子或甲基。 制备该化合物的方法包括使用金属或金属化合物。 版权所有（C）2005，JPO＆NCIPI

公开(公告)号：JP2005169363A

公开(公告)日：2005-06-30

申请号：JP2003417188

申请日：2003-12-15

Applicant: Takasago Internatl Corp ,  高砂香料工業株式会社

Inventor： HORI YASUSHI ,  NAKAMURA JUNJI ,  SAWAKI TOMOYA ,  TANAKA SHIGERU

IPC: B01J23/30 ,  B01J27/053 ,  B01J27/188 ,  B01J31/02 ,  C07D301/12 ,  C07D303/14 ,  C07D495/08

CPC classification number: B01J23/30 ,  B01J27/053 ,  B01J27/188 ,  B01J31/0239 ,  B01J2231/72 ,  C07D301/12 ,  C07D303/14 ,  C07D495/08

Abstract: PROBLEM TO BE SOLVED: To provide an inexpensive, versatile and catalytically active new multicomponent oxidation catalyst which can be effectively used, for example, for epoxidation reaction of olefins or the like, and a method for producing an epoxy body by hydrogen peroxide oxidation of an olefin using it as the catalyst.
SOLUTION: The multicomponent oxidation catalyst comprises a tungsten compound, a quaternary ammonium salt, phosphoric acids and/or boric acids, and a hydrogen sulfate. And the method for producing an epoxy compound is characterized by the hydrogen peroxide oxidation of the olefins in the presence of the multicomponent oxidation catalyst. The epoxy compound produced by the method is useful as an intermediate of an agricultural chemical or a medicine or the like, or a raw material or the like of various polymers.
COPYRIGHT: (C)2005,JPO&NCIPI

Abstract translation: 要解决的问题：提供廉价，通用和催化活性的新型多组分氧化催化剂，其可以有效地用于例如烯烃等的环氧化反应，以及通过过氧化氢生产环氧树脂的方法 使用其作为催化剂氧化烯烃。 解决方案：多组分氧化催化剂包含钨化合物，季铵盐，磷酸和/或硼酸以及硫酸氢盐。 环氧化合物的制造方法的特征在于在多组分氧化催化剂存在下，烯烃的过氧化氢氧化。 通过该方法制备的环氧化合物可用作农药或药物等的中间体或各种聚合物的原料等。 版权所有（C）2005，JPO＆NCIPI

公开(公告)号：JP2005041841A

公开(公告)日：2005-02-17

申请号：JP2003279613

申请日：2003-07-25

Applicant: Takasago Internatl Corp ,  高砂香料工業株式会社

Inventor： SAWAKI TOMOYA ,  KENMOCHI HIROYUKI ,  HORI YASUSHI

IPC: C07D307/93 ,  C07D307/00

CPC classification number: C07D307/00

Abstract: PROBLEM TO BE SOLVED: To provide a new monomer compound having a lactone structure and capable of providing a polymer having excellent characteristics as a resist material or the like.
SOLUTION: The compound is represented by general formula [1] (wherein R
1 and R
2 are each independently an alkyl group; R
3 and R
4 are each independently a hydrogen atom or an alkyl group; R
5 is a hydrogen atom, an acryloyl group or a methacryloyl group; X is a methylene group which may be substituted with an alkyl group or an ethylene group which may be substituted with the alkyl group). The present invention provides a compound having a lactone structure and providing a polymer having excellent characteristics, especially as a resist material and an alcohol substance having a lactone structure useful as the raw material or the like.
COPYRIGHT: (C)2005,JPO&NCIPI

Abstract translation: 要解决的问题：提供具有内酯结构并能够提供具有优异特性的聚合物作为抗蚀剂材料等的新单体化合物。 解决方案：该化合物由通式[1]（其中R 1和R 2各自独立地是烷基）表示; R 3 = SP>和R“SP 4”各自独立地为氢原子或烷基; R 5为氢原子，丙烯酰基或甲基丙烯酰基; X为亚甲基 其可以被可被烷基取代的烷基或亚乙基取代）。 本发明提供具有内酯结构并提供具有优异特性的聚合物的化合物，特别是作为抗蚀剂材料和具有用作原料等的内酯结构的醇物质。 版权所有（C）2005，JPO＆NCIPI