公开(公告)号：JP2005272404A

公开(公告)日：2005-10-06

申请号：JP2004090794

申请日：2004-03-26

Applicant: Takasago Internatl Corp ,  高砂香料工業株式会社

Inventor： SAWAKI TOMOYA ,  KENMOCHI HIROYUKI ,  HORI YASUSHI

IPC: C07C67/08 ,  C07C69/54

Abstract: PROBLEM TO BE SOLVED: To provide a method for producing a 2-alkyl-2-adamantyl (meth)acrylate having excellent physical properties such as excellent dry etching resistance in a semiconductor production process and useful as a semiconductor resist material in high pyrity and yield.
SOLUTION: The 2-alkyl-2-adamantyl (meth)acrylate expressed by general formula (2) (R
1 is a 1-3C alkyl; and R
2 is acryloyl group or methacryloyl group) is produced by reacting a 2-alkyl-2-adamantanol expressed by general formula (1) with an alkyl magnesium halide or a phenyl magnesium halide and then reacting with a (meth)acryloylation agent.
COPYRIGHT: (C)2006,JPO&NCIPI

Abstract translation: 要解决的问题：提供一种在半导体制造方法中制备具有优异的物理性能如耐腐蚀性优异的（甲基）丙烯酸2-金刚烷基酯的方法，并且可用作高半导体抗蚀剂材料 优惠和收益。 解决方案：由通式（2）表示的（甲基）丙烯酸-2-烷基-2-金刚烷基酯（R 1 SP 1）是1-3C烷基; R SP SP 2 >丙烯酰基或甲基丙烯酰基）是通过使由通式（1）表示的2-烷基-2-金刚烷醇与烷基卤化镁或苯基卤化镁反应，然后与（甲基）丙烯酰化剂反应制备的。 版权所有（C）2006，JPO＆NCIPI

公开(公告)号：JP2004331508A

公开(公告)日：2004-11-25

申请号：JP2003124840

申请日：2003-04-30

Applicant: Takasago Internatl Corp ,  高砂香料工業株式会社

Inventor： NAKAYAMA YUJI ,  IWATA TAKESHI ,  MATSUSHIMA YOSHIMASA ,  HORI YASUSHI

IPC: C07D213/30 ,  C07C251/24 ,  C07D239/48 ,  C07F15/00

CPC classification number: C07D239/48 ,  C07C251/24 ,  C07F15/0093

Abstract: PROBLEM TO BE SOLVED: To provide a platinum complex useful as a material, etc., for a light-emitting element of an organic EL element and having excellent thermal stability, emission characteristics and luminous efficiency. SOLUTION: The platinum complex is represented by general formula (1) (wherein, rings A, B and C denote each independently an aromatic ring which may have a substituent or an aromatic heterocyclic ring which may have a substituent; Xs denote each an oxygen atom or a sulfur atom; R 1 and R 2 denote each independently a hydrogen atom or a substituent; and the R 1 and the ring B and the R 2 and the ring B may each be bound to form a condensed ring) or general formula (2) (wherein, rings D, E, F and G denote each independently an aromatic ring which may have a substituent or an aromatic heterocyclic ring which may have a substituent; the ring E and the ring F denote each independently a nitrogen-containing aromatic heterocyclic ring which may have a substituent; and the ring E and the ring F may mutually be bound to form a condensed ring). COPYRIGHT: (C)2005,JPO&NCIPI

公开(公告)号：JP2011063519A

公开(公告)日：2011-03-31

申请号：JP2009213029

申请日：2009-09-15

Applicant: Chiba Univ ,  Takasago Internatl Corp ,  国立大学法人 千葉大学 ,  高砂香料工業株式会社

Inventor： SATO TOMOJI ,  OISHI YUSUKE ,  ISHIZAKI TAKERO ,  HORI YASUSHI

IPC: C07C29/60 ,  B01J21/06 ,  C07B61/00 ,  C07C33/025

CPC classification number: Y02P20/52

Abstract: PROBLEM TO BE SOLVED: To provide a method for simply and smoothly producing an 8-12C ω-alkene-1-ol having high purity in high yield by using an 8-12C α, ω-alkanediol as a raw material.
SOLUTION: The method for producing the 8-12C ω-alkene-1-ol includes subjecting the 8-12C α,ω-alkanediol to dehydration reaction under a reduced pressure by using monoclinic zirconium oxide as a catalyst.
COPYRIGHT: (C)2011,JPO&INPIT

Abstract translation: 要解决的问题：提供一种通过使用8-12Cα，ω-链烷二醇作为原料，以高产率简单平稳地制备高纯度的8-12Cω-烯-1-醇的方法。 解决方案：制备8-12Cω-烯-1-醇的方法包括通过使用单斜晶氧化锆作为催化剂，使8-12Cα，ω-链烷二醇在减压下进行脱水反应。 版权所有（C）2011，JPO＆INPIT

公开(公告)号：JP2004315465A

公开(公告)日：2004-11-11

申请号：JP2003114111

申请日：2003-04-18

Applicant: Takasago Internatl Corp ,  高砂香料工業株式会社

Inventor： NAKAMURA JUNJI ,  YAMADA SHINYA ,  KENMOCHI HIROYUKI ,  HORI YASUSHI

IPC: C07D307/00 ,  C08F20/28

Abstract: PROBLEM TO BE SOLVED: To provide a new monomer compound having a lactone structure and giving a polymer having improved properties as a resist material, etc.
SOLUTION: The compound is expressed by general formula (1) (one of R
1 and R
2 is methyl and the other is isopropyl; one of R
3 and R
4 is H and the other is hydroxy, acryloyloxy or methacryloyloxy; R
5 and R
6 are each independently H or an alkyl; X is (R
7 )(R
8 )C-C(R
9 )(R
10 ); and R
7 , R
8 , R
9 and R
10 are each independently H or an alkyl).
COPYRIGHT: (C)2005,JPO&NCIPI

Abstract translation: 要解决的问题：提供具有内酯结构的新型单体化合物，并提供具有改进性能的聚合物作为抗蚀剂材料等。溶液：该化合物由通式（1）表示（1 R 1 和R 2 是甲基，另一个是异丙基; R 3和R 4中的一个是H 另一个是羟基，丙烯酰氧基或甲基丙烯酰氧基; R 5和R 6共同独立地是H或烷基; X是（R SP 7） （R 8 ）CC（R 9 ）（R 10 ）; R R 4，R 10和R 10各自独立地为H或烷基。 版权所有（C）2005，JPO＆NCIPI

公开(公告)号：JP2004155676A

公开(公告)日：2004-06-03

申请号：JP2002320703

申请日：2002-11-05

Applicant: Japan Science & Technology Agency ,  Takasago Internatl Corp ,  独立行政法人 科学技術振興機構 ,  高砂香料工業株式会社

Inventor： TOKUNAGA MAKOTO ,  HORI YASUSHI

IPC: C07C29/10 ,  C07B61/00 ,  C07C33/22 ,  C07C35/30 ,  C07C45/42 ,  C07C49/403 ,  C07C49/437 ,  C07C51/09 ,  C07C53/08 ,  C07C57/44 ,  C07C63/06 ,  C07C65/24

Abstract: PROBLEM TO BE SOLVED: To provide a method for simply hydrolyzing an alkenyl ester compound or cleaving an alkenyl ether compound in good production efficiency without using an acidic compound and an alkaline compound and without needing such a buffer solution or nutrients as used in an enzymatic reaction or in a reaction using a microorganism, and thereby to provide a method for producing the corresponding carboxylic acid or alcohol and the corresponding ketone or aldehyde at low costs.
SOLUTION: This method for producing an oxygen-containing compound is characterized by reacting an alkenyl ester compound or an alkenyl ether compound with water in the presence of the compound of a metal belonging to the groups 2 to 13 in the periodic table, preferably the compound of a transition metal belonging to the group 8 to 11 in the periodic table, more preferably the complex of a transition metal belonging to the group 9 or 10 to produce the corresponding carboxylic acid or alcohol and the corresponding ketone or aldehyde in high yields.
COPYRIGHT: (C)2004,JPO

公开(公告)号：JP2012115726A

公开(公告)日：2012-06-21

申请号：JP2010265555

申请日：2010-11-29

Applicant: Takasago Internatl Corp ,  高砂香料工業株式会社

Inventor： YAMADA SHINYA ,  MAEDA HIRONORI ,  HORI YASUSHI

IPC: B01J31/28 ,  C07B53/00 ,  C07B61/00 ,  C07C45/62 ,  C07C47/21

CPC classification number: B01J31/04 ,  B01J21/12 ,  B01J23/40 ,  B01J23/44 ,  B01J23/74 ,  B01J23/755 ,  B01J27/053 ,  B01J29/068 ,  B01J29/072 ,  B01J31/062 ,  B01J31/1616 ,  B01J31/2217 ,  B01J31/26 ,  B01J2231/645 ,  B01J2531/0275 ,  B01J2531/821 ,  B01J2531/822 ,  B01J2531/824 ,  B01J2531/827 ,  B01J2531/828 ,  B01J2531/847 ,  C07B53/00 ,  C07B2200/07 ,  C07C45/62 ,  Y02P20/588 ,  C07C47/21

Abstract: PROBLEM TO BE SOLVED: To provide a catalyst for producing optically-active aldehydes or ketones being optically-active carbonyl compounds by selectively asymmetrically hydrogenating α, β-unsaturated carbonyl compounds, particularly a catalyst insoluble in a reaction mixture for obtaining an optically-active citronellal useful as a perfume by selectively asymmetrically hydrogenating citral, geranial or neral; and also to provide a method for producing corresponding optically-active carbonyl compounds.SOLUTION: The invention relates to a catalyst for asymmetrically hydrogenating α, β-unsaturated carbonyl compounds, which contains: the powder of at least one metal selected from group 8-10 metals in the periodic table, or a metal-supported material in which at least one metal selected from group 8-10 metals is supported by a carrier; an optically-active peptide compound; and an acid, and also relates to a method for producing optically-active carbonyl compounds using the catalyst.

Abstract translation: 要解决的问题：提供一种用于通过选择性不对称氢化α，β-不饱和羰基化合物，特别是不溶于反应混合物中的催化剂以获得光学活性的羰基化合物来提供用于制备光学活性的醛或酮的催化剂， 活性香茅醛通过选择性不对称氢化柠檬醛，香叶酸或香草来用作香料; 并且还提供了制备相应的光学活性羰基化合物的方法。 解决方案：本发明涉及用于不对称氢化α，β-不饱和羰基化合物的催化剂，其包含：选自周期表中第8-10族金属中的至少一种金属的粉末或金属负载材料 其中选自第8-10族金属中的至少一种金属由载体支撑; 光学活性肽化合物; 和酸，还涉及使用该催化剂制备光学活性羰基化合物的方法。 版权所有（C）2012，JPO＆INPIT

公开(公告)号：JP2011246366A

公开(公告)日：2011-12-08

申请号：JP2010119457

申请日：2010-05-25

Applicant: Takasago Internatl Corp ,  高砂香料工業株式会社

Inventor： ITO HISANORI ,  FUJIWARA MITSUHIKO ,  HORI YASUSHI

IPC: C07F5/06 ,  B01J31/14 ,  C07B61/00 ,  C07C29/38 ,  C07C35/17 ,  C07C39/04 ,  C07C39/14

CPC classification number: C07F5/066 ,  B01J31/143 ,  B01J2231/52 ,  C07B2200/07 ,  C07C29/56 ,  C07C2601/14 ,  C07C35/17

Abstract: PROBLEM TO BE SOLVED: To provide a catalyst for obtaining isopulegol of high diastereoselectivity by highly selective cyclization of citronellal.SOLUTION: The present invention relates to an organoaluminum compound obtained by reacting at least one organoaluminumoxy compound selected from the group consisting of chain aluminoxanes, cyclic aluminoxanes and bis(dialkylaluminumoxy)alkylboranes, with at least one hydroxy compound selected from the group consisting of diarylphenols, bis(diarylphenol) compounds, biaryldiols, dimethanols and silanols.

Abstract translation: 待解决的问题：提供通过香茅醛高度选择性环化获得高非对映选择性的异ule g的催化剂。 解决方案：本发明涉及通过使至少一种选自链铝氧烷，环铝氧烷和双（二烷基铝氧基）烷基硼烷的有机铝氧化合物与至少一种选自以下的羟基化合物反应获得的有机铝化合物： 的二芳基酚，双（二芳基苯酚）化合物，二芳基二醇，二乙醇和硅烷醇。 版权所有（C）2012，JPO＆INPIT

公开(公告)号：JP2005247745A

公开(公告)日：2005-09-15

申请号：JP2004060051

申请日：2004-03-04

Applicant: Takasago Internatl Corp ,  高砂香料工業株式会社

Inventor： SAWAKI TOMOYA ,  NAKAMURA JUNJI ,  HORI YASUSHI ,  NUMAZAWA SHIGEYOSHI

IPC: C07C69/54 ,  C07C67/08 ,  C07C67/14 ,  C07F1/02 ,  C07F3/02

Abstract: PROBLEM TO BE SOLVED: To provide a new monomer having a cyclohexane structure replaced with a plurality of alkyl groups and capable of providing a polymer such as a resist material responsive to high energy beam, excellent in sensitivity, resolution property and etching resistance and useful for fine processing with electron beam and far-ultraviolet light and to provide a method for producing the monomer. SOLUTION: The (meth)acrylate is represented by general formula (1) (wherein R 1 , R 2 and R 3 may be same or different and they are each an alkyl group; R 4 is a hydrogen atom or a methyl group). The method for producing the compound comprises using a metal or a metal compound. COPYRIGHT: (C)2005,JPO&NCIPI

Abstract translation: 要解决的问题：提供具有被多个烷基取代的环己烷结构的新型单体，并能够提供对高能束响应的聚合物如抗蚀剂材料，灵敏度，分辨率和耐蚀刻性优异 并且可用于用电子束和远紫外光的精细加工，并提供制备单体的方法。 解决方案：（甲基）丙烯酸酯由通式（1）表示（其中R 1 ，R 2 和R 3 相同或不同，它们各自为烷基; R 4为氢原子或甲基。 制备该化合物的方法包括使用金属或金属化合物。 版权所有（C）2005，JPO＆NCIPI

公开(公告)号：JP2005169363A

公开(公告)日：2005-06-30

申请号：JP2003417188

申请日：2003-12-15

Applicant: Takasago Internatl Corp ,  高砂香料工業株式会社

Inventor： HORI YASUSHI ,  NAKAMURA JUNJI ,  SAWAKI TOMOYA ,  TANAKA SHIGERU

IPC: B01J23/30 ,  B01J27/053 ,  B01J27/188 ,  B01J31/02 ,  C07D301/12 ,  C07D303/14 ,  C07D495/08

CPC classification number: B01J23/30 ,  B01J27/053 ,  B01J27/188 ,  B01J31/0239 ,  B01J2231/72 ,  C07D301/12 ,  C07D303/14 ,  C07D495/08

Abstract: PROBLEM TO BE SOLVED: To provide an inexpensive, versatile and catalytically active new multicomponent oxidation catalyst which can be effectively used, for example, for epoxidation reaction of olefins or the like, and a method for producing an epoxy body by hydrogen peroxide oxidation of an olefin using it as the catalyst.
SOLUTION: The multicomponent oxidation catalyst comprises a tungsten compound, a quaternary ammonium salt, phosphoric acids and/or boric acids, and a hydrogen sulfate. And the method for producing an epoxy compound is characterized by the hydrogen peroxide oxidation of the olefins in the presence of the multicomponent oxidation catalyst. The epoxy compound produced by the method is useful as an intermediate of an agricultural chemical or a medicine or the like, or a raw material or the like of various polymers.
COPYRIGHT: (C)2005,JPO&NCIPI

Abstract translation: 要解决的问题：提供廉价，通用和催化活性的新型多组分氧化催化剂，其可以有效地用于例如烯烃等的环氧化反应，以及通过过氧化氢生产环氧树脂的方法 使用其作为催化剂氧化烯烃。 解决方案：多组分氧化催化剂包含钨化合物，季铵盐，磷酸和/或硼酸以及硫酸氢盐。 环氧化合物的制造方法的特征在于在多组分氧化催化剂存在下，烯烃的过氧化氢氧化。 通过该方法制备的环氧化合物可用作农药或药物等的中间体或各种聚合物的原料等。 版权所有（C）2005，JPO＆NCIPI

公开(公告)号：JP2005041841A

公开(公告)日：2005-02-17

申请号：JP2003279613

申请日：2003-07-25

Applicant: Takasago Internatl Corp ,  高砂香料工業株式会社

Inventor： SAWAKI TOMOYA ,  KENMOCHI HIROYUKI ,  HORI YASUSHI

IPC: C07D307/93 ,  C07D307/00

CPC classification number: C07D307/00

Abstract: PROBLEM TO BE SOLVED: To provide a new monomer compound having a lactone structure and capable of providing a polymer having excellent characteristics as a resist material or the like.
SOLUTION: The compound is represented by general formula [1] (wherein R
1 and R
2 are each independently an alkyl group; R
3 and R
4 are each independently a hydrogen atom or an alkyl group; R
5 is a hydrogen atom, an acryloyl group or a methacryloyl group; X is a methylene group which may be substituted with an alkyl group or an ethylene group which may be substituted with the alkyl group). The present invention provides a compound having a lactone structure and providing a polymer having excellent characteristics, especially as a resist material and an alcohol substance having a lactone structure useful as the raw material or the like.
COPYRIGHT: (C)2005,JPO&NCIPI

Abstract translation: 要解决的问题：提供具有内酯结构并能够提供具有优异特性的聚合物作为抗蚀剂材料等的新单体化合物。 解决方案：该化合物由通式[1]（其中R 1和R 2各自独立地是烷基）表示; R 3 = SP>和R“SP 4”各自独立地为氢原子或烷基; R 5为氢原子，丙烯酰基或甲基丙烯酰基; X为亚甲基 其可以被可被烷基取代的烷基或亚乙基取代）。 本发明提供具有内酯结构并提供具有优异特性的聚合物的化合物，特别是作为抗蚀剂材料和具有用作原料等的内酯结构的醇物质。 版权所有（C）2005，JPO＆NCIPI