公开(公告)号：JP2005272404A

公开(公告)日：2005-10-06

申请号：JP2004090794

申请日：2004-03-26

Applicant: Takasago Internatl Corp ,  高砂香料工業株式会社

Inventor： SAWAKI TOMOYA ,  KENMOCHI HIROYUKI ,  HORI YASUSHI

IPC: C07C67/08 ,  C07C69/54

Abstract: PROBLEM TO BE SOLVED: To provide a method for producing a 2-alkyl-2-adamantyl (meth)acrylate having excellent physical properties such as excellent dry etching resistance in a semiconductor production process and useful as a semiconductor resist material in high pyrity and yield.
SOLUTION: The 2-alkyl-2-adamantyl (meth)acrylate expressed by general formula (2) (R
1 is a 1-3C alkyl; and R
2 is acryloyl group or methacryloyl group) is produced by reacting a 2-alkyl-2-adamantanol expressed by general formula (1) with an alkyl magnesium halide or a phenyl magnesium halide and then reacting with a (meth)acryloylation agent.
COPYRIGHT: (C)2006,JPO&NCIPI

Abstract translation: 要解决的问题：提供一种在半导体制造方法中制备具有优异的物理性能如耐腐蚀性优异的（甲基）丙烯酸2-金刚烷基酯的方法，并且可用作高半导体抗蚀剂材料 优惠和收益。 解决方案：由通式（2）表示的（甲基）丙烯酸-2-烷基-2-金刚烷基酯（R 1 SP 1）是1-3C烷基; R SP SP 2 >丙烯酰基或甲基丙烯酰基）是通过使由通式（1）表示的2-烷基-2-金刚烷醇与烷基卤化镁或苯基卤化镁反应，然后与（甲基）丙烯酰化剂反应制备的。 版权所有（C）2006，JPO＆NCIPI

公开(公告)号：JP2008074714A

公开(公告)日：2008-04-03

申请号：JP2006252397

申请日：2006-09-19

Applicant: Takasago Internatl Corp ,  高砂香料工業株式会社

Inventor： KOBAYASHI TORU ,  KENMOCHI HIROYUKI

IPC: C07C211/54 ,  G03G5/06

Abstract: PROBLEM TO BE SOLVED: To provide such an electrophotographic photoreceptor that a charge transport material to be used therein has high mobility and the resulting film as photosensitive layer having the charge transport material is stable, thus attaining high sensitivity and low residual voltage and withstanding practical use.
SOLUTION: The electrophotographic photoreceptor is such that the photosensitive layer essentially having a charge generator and a charge transfer agent is formed on an electrically conductive substrate. In this electrophotographic photoreceptor, the charge transport material in the photosensitive layer is a compound represented by the general formula (1).
COPYRIGHT: (C)2008,JPO&INPIT

Abstract translation: 要解决的问题：为了提供这样的电子照相感光体，其中使用的电荷传输材料具有高迁移率，并且所得到的作为具有电荷传输材料的感光层的膜是稳定的，因此获得高灵敏度和低残留电压， 耐用实用。 解决方案：电子照相感光体使得基本上具有电荷发生器和电荷转移剂的感光层形成在导电基底上。 在这种电子照相感光体中，感光层中的电荷输送材料是由通式（1）表示的化合物。 版权所有（C）2008，JPO＆INPIT

公开(公告)号：JP2005023063A

公开(公告)日：2005-01-27

申请号：JP2004150218

申请日：2004-05-20

Applicant: Takasago Internatl Corp ,  高砂香料工業株式会社

Inventor： NAKAMURA JUNJI ,  NUMAZAWA SHIGEYOSHI ,  KENMOCHI HIROYUKI ,  HORI YASUSHI

IPC: C07D307/77 ,  C07D307/93

Abstract: PROBLEM TO BE SOLVED: To provide a new monomer compound having a lactone structure which gives a polymer having more excellent properties as a resist material or the like, and an alcohol having a lactone structure useful as a raw material therefor or the like.
SOLUTION: The compound is represented by general formula [1] (wherein either one of R
1 and R
2 is a hydrogen atom, an acryloyl group or a methacryloyl group and the other is an alkyl group; R
3 and R
4 are each independently a hydrogen atom or an alkyl group; R
5 and R
6 are each a hydrogen atom or form a methylene chain optionally substituted with an alkyl group; and R
7 and R
8 are each independently a hydrogen atom or a methyl group).
COPYRIGHT: (C)2005,JPO&NCIPI

Abstract translation: 要解决的问题：提供具有内酯结构的新型单体化合物，其赋予作为抗蚀剂材料等具有更优异性能的聚合物，以及具有可用作其原料的内酯结构等的醇 。 解决方案：该化合物由通式[1]表示（其中R 1和R 2中的任一个是氢原子，丙烯酰基或甲基丙烯酰基 基团，另一个是烷基; R 3和R 4彼此独立地是氢原子或烷基; R 5和R 4都是 各自为氢原子或形成任选被烷基取代的亚甲基链; R“SP”7和R“SP”8各自独立地为氢 原子或甲基）。 版权所有（C）2005，JPO＆NCIPI

公开(公告)号：JP2005041841A

公开(公告)日：2005-02-17

申请号：JP2003279613

申请日：2003-07-25

Applicant: Takasago Internatl Corp ,  高砂香料工業株式会社

Inventor： SAWAKI TOMOYA ,  KENMOCHI HIROYUKI ,  HORI YASUSHI

IPC: C07D307/93 ,  C07D307/00

CPC classification number: C07D307/00

Abstract: PROBLEM TO BE SOLVED: To provide a new monomer compound having a lactone structure and capable of providing a polymer having excellent characteristics as a resist material or the like.
SOLUTION: The compound is represented by general formula [1] (wherein R
1 and R
2 are each independently an alkyl group; R
3 and R
4 are each independently a hydrogen atom or an alkyl group; R
5 is a hydrogen atom, an acryloyl group or a methacryloyl group; X is a methylene group which may be substituted with an alkyl group or an ethylene group which may be substituted with the alkyl group). The present invention provides a compound having a lactone structure and providing a polymer having excellent characteristics, especially as a resist material and an alcohol substance having a lactone structure useful as the raw material or the like.
COPYRIGHT: (C)2005,JPO&NCIPI

Abstract translation: 要解决的问题：提供具有内酯结构并能够提供具有优异特性的聚合物作为抗蚀剂材料等的新单体化合物。 解决方案：该化合物由通式[1]（其中R 1和R 2各自独立地是烷基）表示; R 3 = SP>和R“SP 4”各自独立地为氢原子或烷基; R 5为氢原子，丙烯酰基或甲基丙烯酰基; X为亚甲基 其可以被可被烷基取代的烷基或亚乙基取代）。 本发明提供具有内酯结构并提供具有优异特性的聚合物的化合物，特别是作为抗蚀剂材料和具有用作原料等的内酯结构的醇物质。 版权所有（C）2005，JPO＆NCIPI

公开(公告)号：JP2004210745A

公开(公告)日：2004-07-29

申请号：JP2003002449

申请日：2003-01-08

Applicant: Takasago Internatl Corp ,  高砂香料工業株式会社

Inventor： KENMOCHI HIROYUKI ,  HORI YASUSHI ,  HASEGAWA YOSHIKI

IPC: C07D307/33 ,  C07C67/12 ,  C07C69/54

Abstract: PROBLEM TO BE SOLVED: To provide a safe method for producing a (meth)acrylic ester of a cyclic secondary or tertiary alcohol in good handling nature and workability as well as in a high yield.
SOLUTION: The (meth)acrylic ester of a cyclic secondary or tertiary alcohol is produced by reacting a mixed acid anhydride represented by the formula: CH
2 =C(R
1 )-CO-OA [wherein, R
1 is H or CH
3 ; A is represented by the formula: -CO-R
2 (wherein, R
2 is a t-butyl group, 2,3-dimethyl-2-butyl group, 2-methyl-2-pentyl group, 3-methl-3-pentyl group, 4-nitrophenyl group or 2,4,6-trichlorophenyl group)] and a cyclic secondary or tertiary alcohol-based compound selected from a metal alkoxide of a cycloaliphatic alcohol, a hydroxylactone and an alcohol containing a condensed cycloaliphatic lactone in which an alcoholic hydroxyl is linked to a carbon atom constituting an aliphatic ring.
COPYRIGHT: (C)2004,JPO&NCIPI

公开(公告)号：JP2004315465A

公开(公告)日：2004-11-11

申请号：JP2003114111

申请日：2003-04-18

Applicant: Takasago Internatl Corp ,  高砂香料工業株式会社

Inventor： NAKAMURA JUNJI ,  YAMADA SHINYA ,  KENMOCHI HIROYUKI ,  HORI YASUSHI

IPC: C07D307/00 ,  C08F20/28

Abstract: PROBLEM TO BE SOLVED: To provide a new monomer compound having a lactone structure and giving a polymer having improved properties as a resist material, etc.
SOLUTION: The compound is expressed by general formula (1) (one of R
1 and R
2 is methyl and the other is isopropyl; one of R
3 and R
4 is H and the other is hydroxy, acryloyloxy or methacryloyloxy; R
5 and R
6 are each independently H or an alkyl; X is (R
7 )(R
8 )C-C(R
9 )(R
10 ); and R
7 , R
8 , R
9 and R
10 are each independently H or an alkyl).
COPYRIGHT: (C)2005,JPO&NCIPI

Abstract translation: 要解决的问题：提供具有内酯结构的新型单体化合物，并提供具有改进性能的聚合物作为抗蚀剂材料等。溶液：该化合物由通式（1）表示（1 R 1 和R 2 是甲基，另一个是异丙基; R 3和R 4中的一个是H 另一个是羟基，丙烯酰氧基或甲基丙烯酰氧基; R 5和R 6共同独立地是H或烷基; X是（R SP 7） （R 8 ）CC（R 9 ）（R 10 ）; R R 4，R 10和R 10各自独立地为H或烷基。 版权所有（C）2005，JPO＆NCIPI