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    비어있는 킬레이트 사이트를 갖는 삼차원 금속-유기 구조체 및 이의 제조 방법
    83.
    发明公开
    비어있는 킬레이트 사이트를 갖는 삼차원 금속-유기 구조체 및 이의 제조 방법 无效
    含金属螯合物的3D金属有机骨架及其制备方法

    公开(公告)号：KR1020140004370A

    公开(公告)日：2014-01-13

    申请号：KR1020120071830

    申请日：2012-07-02

    Applicant: 성신여자대학교 산학협력단

    Inventor： 박성순 ,  정수현 ,  김영미 ,  김성진

    IPC: C07F15/00 ,  C01F17/00 ,  C07D213/00

    CPC classification number: C07F15/00 ,  G01N21/64 ,  G01N33/20

    Abstract: The present invention relates to a three-dimensional metal-organic structure containing empty chelating sites using a metal ion and an organic binding compound. More specifically, the invention relates to a structure having an empty chelate ligand using a samarium ion(III) of lanthanum origin and a 2,2'-bipyridine-5,5'-dicarboxylic acid organic binding compound, and a manufacturing method thereof, a storage method of gas and a method for detecting a metal ion using the structure.

    Abstract translation: 本发明涉及含有使用金属离子和有机结合化合物的空螯合位点的三维金属 - 有机结构。 更具体地说，本发明涉及使用镧原子的钐离子（III）和2,2'-联吡啶-5,5'-二羧酸有机结合化合物的具有空的螯合配体的结构及其制造方法， 气体的储存方法和使用该结构检测金属离子的方法。

    팔라듐과 리간드를 이용한 알릴벤젠 유도체의 제조방법
    86.
    发明公开
    팔라듐과 리간드를 이용한 알릴벤젠 유도체의 제조방법 失效
    使用PD和配体合成全甲苯衍生物

    公开(公告)号：KR1020100006456A

    公开(公告)日：2010-01-19

    申请号：KR1020080066689

    申请日：2008-07-09

    Applicant: 강원대학교산학협력단

    Inventor： 이필호 ,  서문동 ,  박용광

    IPC: C07C2/64 ,  C07C15/44 ,  C07D213/00

    CPC classification number: Y02P20/52

    Abstract: PURPOSE: A method for manufacturing allyl benzene derivatives is provided to be applied in the synthesis of various natural products, to prepare allyl benzene derivatives at high yield compared with a conventional allyl indium reaction, and to compensate toxicity of organic tin compound. CONSTITUTION: A method for manufacturing allyl benzene derivatives comprises the steps of: reacting an allyl derivative represented by chemical formula 2, indium halide represented by chemical formula 3, amine compound represented by chemical formula 4, in the indium, palladium catalyst, and ligand condition to prepare allyl indium represented by chemical formula 5; performing cross coupling reaction of the allyl indium with an allyl compound represented by chemical formula 6 to prepare an allyl benzene derivative represented by chemical formula 1.

    Abstract translation: 目的：提供一种制备烯丙基苯衍生物的方法，用于合成各种天然产物，与常规的烯丙基铟反应相比，以高产率制备烯丙基苯衍生物，并补偿有机锡化合物的毒性。 构成：制造烯丙基苯衍生物的方法包括以下步骤：使由化学式2表示的烯丙基衍生物，由化学式3表示的卤化铟，由化学式4表示的胺化合物反应在铟，钯催化剂和配体条件 制备由化学式5表示的烯丙基铟; 进行烯丙基铟与化学式6表示的烯丙基化合物的交叉偶联反应，制备由化学式1表示的烯丙基苯衍生物。

    부전하 부여성 하전 제어제, 정전하상 현상용 토너 및 하전 제어 방법
    87.
    发明公开
    부전하 부여성 하전 제어제, 정전하상 현상용 토너 및 하전 제어 방법 失效
    充电控制代理和相关技术

    公开(公告)号：KR1020070088566A

    公开(公告)日：2007-08-29

    申请号：KR1020077007761

    申请日：2006-03-22

    Applicant: 오리엔트 가가쿠 고교 가부시키가이샤

    Inventor： 구로다가즈요시 ,  야스마츠마사시

    IPC: G03G9/097 ,  C07D213/00

    CPC classification number: G03G9/09733 ,  C07D213/68 ,  C07D213/79 ,  C07D213/81 ,  C07D213/82 ,  C07D215/06 ,  C07D215/233 ,  C07D309/38 ,  C07D311/10 ,  C07D311/22 ,  C07D311/42 ,  G03G9/09758

    Abstract: [PROBLEMS] To provide a charge control agent, which has a practical level of negative charge imparting properties, is colorless and a light color and can be used in a color toner, can realize good stability against an environmental change of electrostatic charges generated by electrification of resin powder such as toner, has excellent storage stability and durability, and has high safety, and a method for charge control of resin powder using the charge control agent, and a toner. [MEANS FOR SOLVING PROBLEMS] A charge control agent comprising a compound represented by the following formula as an active component: formula (1) wherein X: an oxygen atom or N-H; and R1 to R4: a hydrogen atom, a carboxyl group, a substituted or unsubstituted aminocarbonyl group, a substituted or unsubstituted aminocarbonylmethyl group, an alkoxycarbonyl group, an alkyl group, a substituted or unsubstituted phenyl group, or a group that, together with any of other group selected from R1 to R4, forms a substituted or unsubstituted saturated or unsaturated ring, and a method for charge control of resin powder using the charge control agent, and a toner.

    Abstract translation: 为了提供一种电荷控制剂，具有实际的负电荷赋予特性，是无色和浅色，可以用于彩色调色剂中，可以实现良好的稳定性，抵抗由带电产生的静电电荷的环境变化 的树脂粉末，例如调色剂，具有优异的储存稳定性和耐久性，并且具有高安全性，以及使用电荷控制剂对树脂粉末进行充电控制的方法和调色剂。 解决问题的方法电荷控制剂包含下式表示的化合物作为活性成分：式（1）其中X：氧原子或N-H; R 1〜R 4为氢原子，羧基，取代或未取代的氨基羰基，取代或未取代的氨基羰基甲基，烷氧基羰基，烷基，取代或未取代的苯基， 的选自R1至R4的其它基团，形成取代或未取代的饱和或不饱和环，以及使用电荷控制剂的树脂粉末的电荷控制方法和调色剂。

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