公开(公告)号：US08147959B2

公开(公告)日：2012-04-03

申请号：US12335846

申请日：2008-12-16

Applicant: Akio Nakashima ,  Atsushi Sasada

Inventor： Akio Nakashima ,  Atsushi Sasada

IPC: B32B5/16

CPC classification number: C09K9/00 ,  Y10T428/24997 ,  Y10T428/249986 ,  Y10T428/2982 ,  Y10T428/2989 ,  Y10T428/2991 ,  Y10T428/2998

Abstract: A color-change laminate in which a color tone derived from a porous layer is visually perceived in a dry state and a metallic lustrous property is visually perceived in a liquid-absorbed state of the porous layer caused by water application is excellent in luminance and which satisfies both of changing properties and decorative properties in the dry state and in the liquid-absorbed state. A color-change laminate includes a support having a metallic lustrous property and a porous layer provided on the surface of the support. The porous layer includes a low-refractive-index pigment and a transparent metallic lustrous pigment formed by coating a transparent core material with a metal oxide and/or a transparent metallic lustrous pigment having a color-flopping property all fixed onto a binder resin in a dispersed state and is different in transparency in a liquid-absorbed state and in a liquid-unabsorbed state.

Abstract translation: 其中由多孔层产生的色调在干燥状态下视觉上感觉到并且由水施加引起的多孔层的液体吸收状态下视觉上感觉到金属光泽性的变色层压板的亮度优异， 满足干燥状态和液体吸收状态下的变化特性和装饰性能。 变色层压板包括具有金属光泽性质的支撑体和设置在支撑体表面上的多孔层。 多孔层包括低折射率颜料和透明金属光泽颜料，该透明金属光泽颜料通过将透明芯材与金属氧化物和/或透明金属光泽颜料进行涂覆而形成，所述透明金属光泽颜料全部固定在粘合剂树脂上 分散状态，并且在液体吸收状态和液体未吸收状态下的透明度不同。

公开(公告)号：US20100248585A1

公开(公告)日：2010-09-30

申请号：US12161395

申请日：2007-01-29

Applicant: Akio Nakashima

Inventor： Akio Nakashima

IPC: A63H13/15 ,  A63H33/22

CPC classification number: B44F1/06 ,  A63H33/22 ,  B44D2/002

Abstract: An drawing toy 1 having a excellent performance in play to which water is applied to form images such as letters or characters, and patterns or designs, which are perceivable as images having brilliance is constituted of an drawable member 2 having a light-transmitting support 3 and provided on the surface thereof a porous layer 4 in which a low refractive index pigment has been made dispersedly fixed to a binder resin and which comes different in transparency between a liquid-absorbed condition and a liquid-non-absorbed condition, and a light source 5 which irradiates the back surface of the drawable member with light. A drawing toy set is constituted of the drawing toy 1 and a water-applying implement 15.

Abstract translation: 具有优良性能的绘图玩具1由具有透光支撑件3的可抽出构件2构成，该玩具1具有用于形成诸如字母或字符的图像的优异性能，以及可感知为具有光亮度的图像的图案或设计 并且在其表面上设置多孔层4，其中低折射率颜料已经分散地固定在粘合剂树脂上，并且在液体吸收状态和液体不吸收状态之间的透明度不同，并且光 光源5照射可拉伸部件的背面。 绘图玩具组由绘图玩具1和施水工具15构成。

公开(公告)号：US07753680B2

公开(公告)日：2010-07-13

申请号：US11706386

申请日：2007-02-15

Applicant: Akio Nakashima

Inventor： Akio Nakashima

IPC: G09B11/00

CPC classification number: B44D2/00 ,  B43L1/00

Abstract: To provide: a water-discoloring drawing toy which, when a writing utensil or applicator for water adhesion is applied thereto, produces a multicolor image and which eliminates the monotonous production of monochromatic images in a related-art technique and is rich in unexpectedness and changes; and a water-discoloring drawing toy set including this drawing toy.A water-discoloring drawing toy 1 having such a constitution that a drawing made by applying a writing utensil or applicator for water adhesion produces a multicolor image, the drawing toy comprising: a substrate; many non-discoloring images differing in color tone and adjoining each other disposed on the substrate so that at least two color tones per 100 cm2 can be visually recognized in the part having the non-discoloring images; and a porous layer for preventing the non-discoloring images from being seen in the ordinary state, the porous layer being disposed over the non-discoloring images and comprising a binder resin and a low-refractive-index pigment fixed therein in a dispersed state, the porous layer having a difference in transparency between a liquid-impregnated state and an unimpregnated state. Also provided is a water-discoloring drawing toy set which comprises the water-discoloring drawing toy 1 and a writing utensil 3 or applicator for water adhesion.

Abstract translation: 提供：一种褪色绘画玩具，当将用于水粘附的书写用具或涂布器施加到其上时，产生多色图像，并且消除了相关技术中单色图像的单调生成，并且具有丰富的意外和变化 ; 和一个包括这个绘画玩具的水褪色绘画玩具组。 具有这样一种构造的水褪色绘画玩具1，其中通过应用用于水粘附的书写用具或涂抹器制成的图形产生多色图像，所述绘图玩具包括：衬底; 许多色调不同的非变色图像彼此相邻设置在基板上，使得在具有非变色图像的部分中可以视觉识别每100cm 2的至少两个色调; 以及用于防止在普通状态下看不到不变色图像的多孔层，所述多孔层设置在所述非变色图像上并且以分散状态包含粘合剂树脂和固定在其中的低折射率颜料， 多孔层在液体浸渍状态和未浸渍状态之间的透明度差异。 还提供了一种水褪色绘画玩具组，其包括水褪色绘画玩具1和书写用具3或用于水粘附的涂抹器。

公开(公告)号：US20100111817A1

公开(公告)日：2010-05-06

申请号：US12596293

申请日：2008-04-18

Applicant: Noboru Taniguchi ,  Shuzo Tokumitsu ,  Tomohiro Kuroha ,  Kenichi Tokuhiro ,  Akio Nakashima ,  Keita Kobayashi ,  Shinji Nakahara

Inventor： Noboru Taniguchi ,  Shuzo Tokumitsu ,  Tomohiro Kuroha ,  Kenichi Tokuhiro ,  Akio Nakashima ,  Keita Kobayashi ,  Shinji Nakahara

IPC: C01B11/24 ,  C01G23/04

CPC classification number: A61L9/18 ,  B01J21/063 ,  B01J27/135 ,  B01J35/004 ,  B01J35/1019 ,  B01J37/26 ,  C01G23/00 ,  C01G23/047 ,  C01P2002/54 ,  C01P2006/12

Abstract: A titanium oxide photocatalyst that is capable of improving a decomposition rate, and a method for producing the same are provided. The titanium oxide photocatalyst of the present invention is a titanium oxide photocatalyst containing at least an anatase-type titanium oxide and fluorine, wherein a content of the fluorine is 2.5 wt % to 3.5 wt %, and 90 wt % or more of the fluorine is chemically bonded to the anatase-type titanium oxide.

Abstract translation: 提供能够提高分解率的氧化钛光催化剂及其制造方法。 本发明的氧化钛光催化剂是至少含有锐钛矿型氧化钛和氟的氧化钛光催化剂，其中氟的含量为2.5〜3.5重量％，氟的90重量％以上为 化学键合到锐钛矿型氧化钛。

公开(公告)号：US20090155498A1

公开(公告)日：2009-06-18

申请号：US12335846

申请日：2008-12-16

Applicant: Akio NAKASHIMA ,  Atsushi SASADA

Inventor： Akio NAKASHIMA ,  Atsushi SASADA

IPC: B44F1/10

CPC classification number: C09K9/00 ,  Y10T428/24997 ,  Y10T428/249986 ,  Y10T428/2982 ,  Y10T428/2989 ,  Y10T428/2991 ,  Y10T428/2998

Abstract: A color-change laminate in which a color tone derived from a porous layer is visually perceived in a dry state and a metallic lustrous property is visually perceived in a liquid-absorbed state of the porous layer caused by water application is excellent in luminance and which satisfies both of changing properties and decorative properties in the dry state and in the liquid-absorbed state. A color-change laminate includes a support having a metallic lustrous property and a porous layer provided on the surface of the support. The porous layer includes a low-refractive-index pigment and a transparent metallic lustrous pigment formed by coating a transparent core material with a metal oxide and/or a transparent metallic lustrous pigment having a color-flopping property all fixed onto a binder resin in a dispersed state and is different in transparency in a liquid-absorbed state and in a liquid-unabsorbed state.

Abstract translation: 其中由多孔层产生的色调在干燥状态下视觉上感觉到并且由水施加引起的多孔层的液体吸收状态下视觉上感觉到金属光泽性的变色层压板的亮度优异， 满足干燥状态和液体吸收状态下的变化特性和装饰性能。 变色层压板包括具有金属光泽性质的支撑体和设置在支撑体表面上的多孔层。 多孔层包括低折射率颜料和透明金属光泽颜料，该透明金属光泽颜料通过将透明芯材与金属氧化物和/或透明金属光泽颜料进行涂覆而形成，所述透明金属光泽颜料全部固定在粘合剂树脂上 分散状态，并且在液体吸收状态和液体未吸收状态下的透明度不同。

公开(公告)号：US20090071370A1

公开(公告)日：2009-03-19

申请号：US12270100

申请日：2008-11-13

Applicant: Akio Nakashima

Inventor： Akio Nakashima

IPC: C09D103/02 ,  C09D1/00 ,  C09D105/00 ,  B32B5/18 ,  A63H3/00 ,  C09D191/00 ,  C09D101/00

CPC classification number: C09D5/29 ,  B44D2/002 ,  B44D7/00 ,  Y10T428/249953 ,  Y10T428/249987

Abstract: In a liquid composition for metachromatic members which is to be applied to a metachromatic member having a support and provided thereon a porous layer formed by fixing therein a low refractive index pigment in a disperse state together with a binder resin, the liquid composition has a liquid medium and dissolved and/or dispersed therein a solid matter having a refractive index of from 1.3 to 1.8. Also disclosed is a metachromatic member set having this liquid composition and a metachromatic member. The liquid composition for metachromatic members satisfies permanent preservability of images, having superior density retention and shape retention of images formed in the metachromatic member and being suitable for uses in which impressions of hands, feet and the like are taken and preserved or in which written images or stamped images are preserved.

Abstract translation: 在用于异染色构件的液体组合物中，所述液体组合物应用于具有支撑体的异色构件，并且在其上设置有通过在粘合剂树脂中固定分散状态的低折射率颜料而形成的多孔层，所述液体组合物具有液体 中和溶解和/或分散在其中的具有1.3至1.8的折射率的固体物质。 还公开了具有该液体组合物和异染色构件的异染色构件。 用于异染色构件的液体组合物满足图像的永久保存性，具有优异的密度保持性和在异色构件中形成的图像的形状保持性，并且适用于拍摄和保存手，脚等的印象或其中写入图像 或压印图像被保留。

公开(公告)号：US20080015317A1

公开(公告)日：2008-01-17

申请号：US11776732

申请日：2007-07-12

Applicant: Akio NAKASHIMA

Inventor： Akio NAKASHIMA

IPC: C08F2/00

CPC classification number: D21H19/44 ,  D06N3/0063 ,  D06N3/10 ,  D06N2201/02 ,  D06N2201/042 ,  D06N2209/0807 ,  D06N2209/128 ,  D21H21/28 ,  D21H27/20 ,  Y10T428/24802 ,  Y10T428/24934 ,  Y10T428/249986 ,  Y10T442/277 ,  Y10T442/2861 ,  Y10T442/698

Abstract: To provide a relatively lightweight wall adhering material comprising a non-woven fabric or a water-resistant paper, having a specific coating weight as a substrate and provided thereon a specific amount of a porous layer, a water-discoloring wall adhering material which has excellent convenience at the time of production and use, promptly forms clear image to perceive, is difficult to fall down when adhered to a wall, and has high commercial value, and a water-discoloring wall adhering material set using the same.A water-discoloring wall adhering material 1 comprising a non-woven fabric 2 or a water-resistant paper, having a coating weight of from 40 to 150 g/m2 and provided on the surface thereof a porous layer 3 in an amount of from 5 to 50 g/m2, the porous layer comprising a binder resin and a low-refractive-index pigment dispersed in the binder resin and firmly fixed thereto, and the water-discoloring wall adhering material 1 having a gross weight of from 50 to 200 g/m2, and a water-discoloring wall adhering material set comprising the water-discoloring wall adhering material and a wall fixture or a tool for water adhesion, or a water-discoloring wall adhering material set comprising the water-discoloring wall adhering material, a wall fixture and a tool for water adhesion.

Abstract translation: 为了提供一种相对轻质的壁粘合材料，其包含具有特定涂层重量作为基底并在其上设置特定量的多孔层的无纺织物或防水纸，其具有优异的水变褪色壁附着材料 在生产和使用时方便，及时形成清晰的图像，粘附在墙上时难以落下，具有很高的商业价值，以及使用该墙壁的水变色墙壁附着材料。 一种包含无纺织物2或防水纸的脱水壁粘合材料1，其涂层重量为40-150g / m 2，并在其表面上提供多孔 层3的含量为5至50g / m 2，多孔层包含分散在粘合剂树脂中的粘合剂树脂和低折射率颜料并牢固地固定在其上，并且水 - 具有50至200g / m 2的总重量的脱色壁粘合材料1和包含水变色墙附着材料的水变色墙附着材料和壁装置或 或用于水粘附的工具，或包含水变色墙附着材料的水变色墙附着材料组，壁装置和用于水粘附的工具。

公开(公告)号：US5858914A

公开(公告)日：1999-01-12

申请号：US668818

申请日：1996-06-24

Applicant: Yutaka Shibahashi ,  Katsuyuki Fujita ,  Akio Nakashima

Inventor： Yutaka Shibahashi ,  Katsuyuki Fujita ,  Akio Nakashima

IPC: A43B23/24 ,  A63F3/06 ,  B44F1/10 ,  B41M5/34

CPC classification number: A43B3/24 ,  A43B1/0036 ,  A43B23/24 ,  A43B3/0078 ,  B44F1/10 ,  A63F3/0685

Abstract: A footwear has a thermochromic coloring color-memory layer having a large hysteresis on a color-density-to-temperature curve so as to show interchangeability between a first color phase and a second color phase different from the first color phase, and a coloring tool for forming a desired image on the footwear.

Abstract translation: 一种鞋类具有在色密度 - 温度曲线上具有大的迟滞的热致变色着色色记忆层，以便显示第一色相和不同于第一色相的第二色相之间的互换性，以及着色工具 用于在鞋上形成期望的图像。

公开(公告)号：US3979641A

公开(公告)日：1976-09-07

申请号：US474025

申请日：1974-05-28

Applicant: Yoshihiro Arakawa ,  Akio Nakashima ,  Shunji Iwabuchi ,  Kenji Ando

Inventor： Yoshihiro Arakawa ,  Akio Nakashima ,  Shunji Iwabuchi ,  Kenji Ando

IPC: H04N3/16 ,  H03K4/69 ,  H01J29/70

CPC classification number: H03K4/696

Abstract: A vertical deflection output circuitry for a television receiver wherein two transistors are connected in single ended and push-pull relation, and the output junction point of the two transistors is connected, to a D.C. power source for supplying a higher voltage than that of a power source for the vertical deflection output circuitry, through a switch which is turned off during the vertical scan period and turned on during the vertical retrace period.

Abstract translation: 一种用于电视接收机的垂直偏转输出电路，其中两个晶体管以单端和推挽关系连接，并且两个晶体管的输出连接点连接到用于提供比功率更高的电压的DC电源 通过在垂直扫描周期期间关闭并在垂直回扫期间接通的开关，垂直偏转输出电路的源极。

公开(公告)号：US3950672A

公开(公告)日：1976-04-13

申请号：US477987

申请日：1974-06-10

Applicant: Hirokazu Fukaya ,  Kenji Andou ,  Akio Nakashima

Inventor： Hirokazu Fukaya ,  Kenji Andou ,  Akio Nakashima

IPC: H04N3/16 ,  H04N3/24 ,  H01J29/70 ,  H01J29/72

CPC classification number: H04N3/24

Abstract: A vertical sweep circuit includes a first transistor supplied with a sawtooth voltage. A voltage drop is developed across a resistor by a vertical sweep current for producing a first voltage across a first load. A second transistor is supplied with the first voltage for producing a second voltage across a second load, and a pair of push-pull connected transistors are supplied with the second voltage for producing the sweep current. An additional transistor of the same conductivity type as the second transistor is included in the circuit. Responsive to the first voltage, the additional transistor produces voltage pulses at a point of connection thereto of an additional load, which is greater than the second load to make the second and additional transistors operate as a linear amplifier transistor and a switching transistor, respectively. Vertical blanking pulses are produced from the voltage pulses.