公开(公告)号：US20110213192A1

公开(公告)日：2011-09-01

申请号：US12994162

申请日：2009-06-04

Applicant: Laurent Levy ,  Agnes Pottier ,  Annabelle Rouet ,  Julie Marill ,  Corinne Devaux ,  Matthieu Germain

Inventor： Laurent Levy ,  Agnes Pottier ,  Annabelle Rouet ,  Julie Marill ,  Corinne Devaux ,  Matthieu Germain

IPC: A61N5/00 ,  A61K9/14 ,  A61K33/24

CPC classification number: A61K41/0038 ,  B82Y5/00 ,  Y10S977/904

Abstract: The present application relates to novel excitable particles which can be used in the health sector. It more particularly relates to particles which can generate electrons and/or high energy photon when excited by ionizing radiations such as X- Rays, γ-Rays, radioactive isotope and/or electron beams, and to the uses thereof in health, in particular in human health. The inventive particles are made of an inorganic material comprising oxygen, in particular an oxide, said material having an adequate density, and can be activated in vitro, ex vivo, or in vivo, by controllable external excitation, in order to disturb, alter or destroy target cells, tissues or organs. The invention also relates to methods for the production of said particles, and to pharmaceutical or medical device compositions containing same.

Abstract translation: 本申请涉及可用于健康部门的新型可兴奋颗粒。 更具体地说，涉及当通过诸如X-射线，γ-射线，放射性同位素和/或电子束的电离辐射激发时可以产生电子和/或高能光子的颗粒，以及其在健康中的用途，特别是在 人类健康。 本发明的颗粒由包含氧，特别是氧化物的无机材料制成，所述材料具有足够的密度，并且可以通过可控外部激发在体外，离体或体内活化，以便干扰，改变或 破坏靶细胞，组织或器官。 本发明还涉及生产所述颗粒的方法以及含有该颗粒的药物或医疗装置组合物。

公开(公告)号：US20090173383A1

公开(公告)日：2009-07-09

申请号：US12406760

申请日：2009-03-18

Applicant: Luc Brohan ,  Hari Sutrisno ,  Yves Piffard ,  Maria Teresa Caldes-Rouillon ,  Olivier Joubert ,  Eric Puzenat ,  Annabelle Rouet

Inventor： Luc Brohan ,  Hari Sutrisno ,  Yves Piffard ,  Maria Teresa Caldes-Rouillon ,  Olivier Joubert ,  Eric Puzenat ,  Annabelle Rouet

IPC: H01L31/0216 ,  H01B1/02

CPC classification number: B82Y30/00 ,  C01G23/0536 ,  C01P2002/76 ,  C01P2004/10 ,  C01P2004/64 ,  C01P2006/60

Abstract: The invention relates to a titanium oxide-based polymer composition. The inventive composition comprises a TiOx(OH)y(H2O)z(x+y−+z=3) titanium oxide-based polymer in the form of a gel or sol. Said polymer, which has a one-dimensional (1D) structure, is made from concentrically-wound fibers having a periodicity which is deduced from the spacing between said fibers, of between 3.5 Å and 4 Å. Each fiber comprises TiO6octahedrons and each TiO6octahedron shares two opposite edges with two adjacent octahedrons (2.times.292 Å) in order to form infinite chains which develop along the axis of a fiber. According to the invention, two adjacent chains form double lines as a result of the shared edges (2.times.3.27 Å). The inventive polymer is suitable for use as a photosensitive element in a photovoltaic cell, such as a sunscreen for a window.

Abstract translation: 本发明涉及一种基于氧化钛的聚合物组合物。 本发明的组合物包含凝胶或溶胶形式的TiO x（OH）y（H 2 O）z（x + y + z = 3）氧化钛基聚合物。 具有一维（1D）结构的所述聚合物由具有介于3.5和4之间的从所述纤维之间的间隔推断的周期性的同心缠绕的纤维制成。 每个纤维包括TiO 6八面体，并且每个TiO 6八面体共享两个相对的边缘和两个相邻的八面体（2.282），以形成沿着纤维轴发展的无限链。 根据本发明，作为共享边缘的结果，两个相邻的链形成双线（2/3.27埃）。 本发明的聚合物适合用作光伏电池中的光敏元件，例如用于窗户的防晒剂。

公开(公告)号：US20070041890A1

公开(公告)日：2007-02-22

申请号：US10555926

申请日：2004-04-29

Applicant: Lue Brohan ,  Hari Sutrisno ,  Eric Puzenat ,  Annabelle Rouet ,  Helene Terrisse

Inventor： Lue Brohan ,  Hari Sutrisno ,  Eric Puzenat ,  Annabelle Rouet ,  Helene Terrisse

IPC: C01G23/00

CPC classification number: B01J35/004 ,  B01J27/135 ,  B82Y30/00 ,  C01G23/02 ,  C01G23/0536 ,  C01P2002/76 ,  C01P2002/77 ,  C01P2002/85 ,  C01P2004/03 ,  C01P2004/64

Abstract: The invention relates to a titanium aquo-oxo chloride and to a method for its preparation. The compound is in the form of crystals and has the following composition by weight: 26.91% Ti; 21.36% Cl; and 4.41% H, which corresponds to the formula [Ti8O12(H2O)24]Cl8.HCl.7H2O. The method of preparation consists in hydrolyzing TiOCl2 either in an atmosphere whose moisture content is maintained between 50 and 60%, or by an alkali metal carbonate A2CO3, in order to obtain a titanium aquo-oxo chloride. The compound is useful as a semiconductor element of a photovoltaic cell or as a photocatalyst in air or water purification treatments.

Abstract translation: 本发明涉及一种钛 - 含氧氯化钛及其制备方法。 该化合物为晶体形式，重量百分比如下：26.91％Ti; 21.36％Cl; 和4.41％H，其对应于式[Ti 8 O 12（H 2 O）24] C 8 H 12，HCl 7 H 2 O。 制备方法包括在水分含量保持在50至60％的气氛中或通过碱金属碳酸盐A 2 N 2 CO 2水解TiOCl 2， 3 N，以获得钛 - 氧代氯化钛。 该化合物在空气或水净化处理中可用作光伏电池的半导体元件或光催化剂。

公开(公告)号：US07858064B2

公开(公告)日：2010-12-28

申请号：US10555926

申请日：2004-04-29

Applicant: Luc Brohan ,  Hari Sutrisno ,  Eric Puzenat ,  Annabelle Rouet ,  Hélène Terrisse

Inventor： Luc Brohan ,  Hari Sutrisno ,  Eric Puzenat ,  Annabelle Rouet ,  Hélène Terrisse

IPC: C01G23/00

CPC classification number: B01J35/004 ,  B01J27/135 ,  B82Y30/00 ,  C01G23/02 ,  C01G23/0536 ,  C01P2002/76 ,  C01P2002/77 ,  C01P2002/85 ,  C01P2004/03 ,  C01P2004/64

Abstract: The invention relates to a titanium aquo-oxo chloride and to a method for its preparation. The compound is in the form of crystals and has the following composition by weight: 26.91% Ti; 21.36% Cl; and 4.41% H, which corresponds to the formula [Ti8O12(H2O)24]Cl8.HCl.7H2O. The method of preparation consists in hydrolyzing TiOCl2 either in an atmosphere whose moisture content is maintained between 50 and 60%, or by an alkali metal carbonate A2CO3, in order to obtain a titanium aquo-oxo chloride. The compound is useful as a semiconductor element of a photovoltaic cell or as a photocatalyst in air or water purification treatments.

Abstract translation: 本发明涉及一种钛 - 含氧氯化钛及其制备方法。 该化合物为晶体形式，重量百分比如下：26.91％Ti; 21.36％Cl; 和4.41％H，其对应于式[Ti8O12（H2O）24] Cl8·HCl·7H2O。 制备方法包括在水分含量保持在50至60％的气氛中或通过碱金属碳酸盐A2CO3水解TiOCl 2，以获得钛 - 氧代氯化钛。 该化合物在空气或水净化处理中可用作光伏电池的半导体元件或光催化剂。

公开(公告)号：US07723610B2

公开(公告)日：2010-05-25

申请号：US12406760

申请日：2009-03-18

Applicant: Luc Brohan ,  Hari Sutrisno ,  Yves Piffard ,  Maria Teresa Caldes-Rouillon ,  Olivier Joubert ,  Eric Puzenat ,  Annabelle Rouet

Inventor： Luc Brohan ,  Hari Sutrisno ,  Yves Piffard ,  Maria Teresa Caldes-Rouillon ,  Olivier Joubert ,  Eric Puzenat ,  Annabelle Rouet

IPC: C01G25/02 ,  C01G27/02 ,  C04B35/00 ,  H01L35/00 ,  H01B1/02 ,  H01M6/30

CPC classification number: B82Y30/00 ,  C01G23/0536 ,  C01P2002/76 ,  C01P2004/10 ,  C01P2004/64 ,  C01P2006/60

Abstract: The invention relates to a titanium oxide-based polymer composition. The inventive composition comprises a TiOx(OH)y(H2O)z(x+y−+z=3) titanium oxide-based polymer in the form of a gel or sol. Said polymer, which has a one-dimensional (1D) structure, is made from concentrically-wound fibers having a periodicity which is deduced from the spacing between said fibers, of between 3.5 Å and 4 Å. Each fiber comprises TiO6octahedrons and each TiO6octahedron shares two opposite edges with two adjacent octahedrons (2.times.2.92 Å) in order to form infinite chains which develop along the axis of a fiber. According to the invention, two adjacent chains form double lines as a result of the shared edges (2.times.3.27 Å). The inventive polymer is suitable for use as a photosensitive element in a photovoltaic cell, such as a sunscreen for a window.

Abstract translation: 本发明涉及一种基于氧化钛的聚合物组合物。 本发明的组合物包含凝胶或溶胶形式的TiO x（OH）y（H 2 O）z（x + y + z = 3）氧化钛基聚合物。 具有一维（1D）结构的所述聚合物由具有介于3.5和4之间的从所述纤维之间的间隔推断的周期性的同心缠绕的纤维制成。 每个纤维包括TiO 6八面体，并且每个TiO 6八面体共享两个相对的边缘，其中两个相邻的八面体（2. 2.92埃）以形成沿着纤维轴发展的无限链。 根据本发明，作为共享边缘的结果，两个相邻的链形成双线（2/3.27埃）。 本发明的聚合物适合用作光伏电池中的光敏元件，例如用于窗户的防晒剂。

公开(公告)号：US08845507B2

公开(公告)日：2014-09-30

申请号：US12994162

申请日：2009-06-04

Applicant: Laurent Levy ,  Agnes Pottier ,  Annabelle Rouet ,  Julie Marill ,  Corinne Devaux ,  Matthieu Germain

Inventor： Laurent Levy ,  Agnes Pottier ,  Annabelle Rouet ,  Julie Marill ,  Corinne Devaux ,  Matthieu Germain

IPC: A61N5/00 ,  B82Y5/00 ,  A61K41/00

CPC classification number: A61K41/0038 ,  B82Y5/00 ,  Y10S977/904

Abstract: The present application relates to novel excitable particles which can be used in the health sector. It more particularly relates to particles which can generate electrons and/or high energy photon when excited by ionizing radiations such as X-Rays, γ-Rays, radioactive isotope and/or electron beams, and to the uses thereof in health, in particular in human health. The inventive particles are made of an inorganic material comprising oxygen, in particular an oxide, said material having an adequate density, and can be activated in vitro, ex vivo, or in vivo, by controllable external excitation, in order to disturb, alter or destroy target cells, tissues or organs. The invention also relates to methods for the production of said particles, and to pharmaceutical or medical device compositions containing same.

Abstract translation: 本申请涉及可用于健康部门的新型可兴奋颗粒。 更具体地说，涉及当通过诸如X射线，γ射线，放射性同位素和/或电子束的电离辐射激发时可以产生电子和/或高能光子的颗粒，以及其在健康中的用途，特别是在 人类健康。 本发明的颗粒由包含氧，特别是氧化物的无机材料制成，所述材料具有足够的密度，并且可以通过可控外部激发在体外，离体或体内活化，以便干扰，改变或 破坏靶细胞，组织或器官。 本发明还涉及生产所述颗粒的方法以及含有该颗粒的药物或医疗装置组合物。

公开(公告)号：US07524482B2

公开(公告)日：2009-04-28

申请号：US10502399

申请日：2003-01-14

Applicant: Luc Brohan ,  Hari Sutrisno ,  Yves Piffard ,  Maria Teresa Caldes-Rouillon ,  Olivier Joubert ,  Eric Puzenat ,  Annabelle Rouet

Inventor： Luc Brohan ,  Hari Sutrisno ,  Yves Piffard ,  Maria Teresa Caldes-Rouillon ,  Olivier Joubert ,  Eric Puzenat ,  Annabelle Rouet

IPC: C01G25/02 ,  C01G27/02 ,  C04B35/00

CPC classification number: B82Y30/00 ,  C01G23/0536 ,  C01P2002/76 ,  C01P2004/10 ,  C01P2004/64 ,  C01P2006/60

Abstract: The invention relates to a titanium oxide-based polymer composition. The inventive composition comprises a TiOx(OH)y(H2O)z (x+y+z=3) titanium oxide-based polymer in the form of a gel or sol. Said polymer, which has a one-dimensional (1D) structure, is made from concentrically-wound fibers having a periodicity which is deduced from the spacing between said fibers, of between 3.5 Å and 4 Å. Each fiber comprises TiO6octahedrons and each TiO6octahedron shares two opposite edges with two adjacent octahedrons (2×2.92 Å) in order to form infinite chains which develop along the axis of a fiber. According to the invention, two adjacent chains form double lines as a result of the shared edges (2×3.27 Å). The inventive polymer is suitable for use as a photosensitive element in a photovoltaic cell, such as a sunscreen for a window.

Abstract translation: 本发明涉及一种基于氧化钛的聚合物组合物。 本发明的组合物包含凝胶或溶胶形式的TiO x（OH）y（H 2 O）z（x + y + z = 3）氧化钛基聚合物。 具有一维（1D）结构的所述聚合物由具有介于3.5和4之间的从所述纤维之间的间隔推断的周期性的同心缠绕的纤维制成。 每个纤维包括TiO 6八面体，并且每个TiO 6八面体共享两个相对的边缘和两个相邻的八面体（2x2.92埃），以便形成沿着纤维轴发展的无限链。 根据本发明，由于共享边缘（2x3.27），两个相邻的链形成双线。 本发明的聚合物适合用作光伏电池中的光敏元件，例如用于窗户的防晒剂。

公开(公告)号：US20050163702A1

公开(公告)日：2005-07-28

申请号：US10502399

申请日：2003-01-14

Applicant: Luc Brohan ,  Hari Sutrisno ,  Yves Piffard ,  Maria Caldes-Rouillon ,  Olivier Joubert ,  Eric Puzenat ,  Annabelle Rouet

Inventor： Luc Brohan ,  Hari Sutrisno ,  Yves Piffard ,  Maria Caldes-Rouillon ,  Olivier Joubert ,  Eric Puzenat ,  Annabelle Rouet

IPC: C01G23/04 ,  B01J13/00 ,  C01G23/053 ,  H01L31/04 ,  H01M14/00

CPC classification number: B82Y30/00 ,  C01G23/0536 ,  C01P2002/76 ,  C01P2004/10 ,  C01P2004/64 ,  C01P2006/60

Abstract: The invention relates to a titanium oxide-based polymer composition. The inventive composition comprises a TiOx(OH)y(H2O)z(x+y+z=3) titanium oxide-based polymer in the form of a gel or sol. Said polymer, which has a one-dimensional (1D) structure, is made from concentrically-wound fibers having a periodicity which is deduced from the spacing between said fibers, of between 3.5 Å and 4 Å. Each fiber comprises TiO6octahedrons and each TiO6octahedron shares two opposite edges with two adjacent octahedrons (2×2.92 Å) in order to form infinite chains which develop along the axis of a fiber. According to the invention, two adjacent chains form double lines as a result of the shared edges (2×3.27 Å). The inventive polymer is suitable for use as a photosensitive element in a photovoltaic cell, such as a sunscreen for a window.

Abstract translation: 本发明涉及一种基于氧化钛的聚合物组合物。 本发明的组合物包含（x + y +）（x + y + z） z = 3）凝胶或溶胶形式的氧化钛基聚合物。 具有一维（1D）结构的所述聚合物由具有介于3.5和4之间的从所述纤维之间的间隔推断的周期性的同心缠绕的纤维制成。 每个纤维包括TiO 6八面体，并且每个TiO 2六面体共享两个相邻的边缘和两个相邻的八面体（2x2.92），以形成沿轴线发展的无限链 的纤维。 根据本发明，由于共享边缘（2x3.27），两个相邻的链形成双线。 本发明的聚合物适合用作光伏电池中的光敏元件，例如用于窗户的防晒剂。